Citation: Han XU, Zhao-Rui PAN, Zhao-Peng QI, Jie SUN. Three Luminescent Zn-MOFs Based on V-Shaped Ligands for Fluorescence Sensing of 2, 4, 6-Trinitrophenol and Fe³⁺ in Aqueous Solution[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2479-2490. doi: 10.11862/CJIC.2022.238 shu

Three Luminescent Zn-MOFs Based on V-Shaped Ligands for Fluorescence Sensing of 2, 4, 6-Trinitrophenol and Fe³⁺ in Aqueous Solution

Han XU ¹ ,
Zhao-Rui PAN ^2,, ,
Zhao-Peng QI ¹ ,
Jie SUN ¹

1.
School of Chemistry and Chemical Engineering, Key Laboratory of Inorganic Functional Materials, Huangshan University, Huangshan, Anhui 245041, China
2.
School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: Zhao-Rui PAN, pzr_2006@163.com
Received Date: 27 April 2022
Revised Date: 1 September 2022

Figures(6)

Three Zn(Ⅱ)-based metal-organic frameworks with V-shaped ligands, namely {[Zn₂(BIDPS)₂(OBA)₂]·DMA}_n (1), {[Zn(BIDPT)(PA)]·DMF}_n (2), and {[Zn(BIDPS)(PA)(H₂O)₂]·2H₂O}_n (3) (BIDPS =4, 4'-bis(imidazol-l-yl)-phenyl sulphone, H₂OBA=4, 4'-oxybisbenzoic acid, H₂PA=pamoic acid, BIDPT=4, 4'-bis(imidazol-l-yl)diphenyl thioether), have been hydrothermally synthesized and characterized by single X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and powder X-ray diffraction. Compound 1 shows a two-fold 3D network with cds topology. Compound 2 is a 2D (4, 4) layer network and shows a 2D → 3D parallel-parallel polycatenation framework. Compound 3 exhibits an infinite chain, and such 1D chains are further interlinked into a 3D supramolecular structure via intermolecular and intramolecular hydrogen bonds. Compounds 1-3 could stably exist in aqueous solutions with pH=4-10. Compounds 1-3 demonstrated strong luminescence in aqueous solution, and fluorescence studies show that 1-3 could detect 2, 4, 6-trinitrophenol and Fe³⁺ with high sensitivity and selectivity by luminescent sensing.
- coordination polymer,
- crystal structure,
- hydrogen bonding,
- luminescence
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Three Luminescent Zn-MOFs Based on V-Shaped Ligands for Fluorescence Sensing of 2, 4, 6-Trinitrophenol and Fe3+ in Aqueous Solution

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通讯作者: 陈斌, bchen63@163.com

Three Luminescent Zn-MOFs Based on V-Shaped Ligands for Fluorescence Sensing of 2, 4, 6-Trinitrophenol and Fe³⁺ in Aqueous Solution