Citation: Chao HUANG, Kai-Teng WANG, Dong-Mei CHEN, Bi-Xue ZHU, Ji-Hong LU. Synthesis, Crystal Structures, Luminescence, and Vapor Adsorption Properties of 1D Mercury(Ⅱ) Coordination Polymers Based on Two Dipyridylamide Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2291-2298. doi: 10.11862/CJIC.2022.236 shu

Synthesis, Crystal Structures, Luminescence, and Vapor Adsorption Properties of 1D Mercury(Ⅱ) Coordination Polymers Based on Two Dipyridylamide Ligands

Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China

Corresponding author: Ji-Hong LU, lujhgzu@163.com
Received Date: 10 April 2022
Revised Date: 30 August 2022

Figures(8)

Two coordination polymers, {[Hg₂(L¹) (μ₂-I)₂I₂] ·2DMF·H₂O}_n (1) and {[Hg(L²)I₂] ·H₂O}_n (2), have been designed and synthesized from two dipyridylamide ligands (L¹ and L²) with mercury(Ⅱ) iodide, respectively. X-ray crystallographic analyses show that both the two complexes exist as 1D zig-zag chain structures but exhibit different configurations by slightly adjusted 3-and 4-pyridyl nitrogen atoms from the ligands. Each Hg(Ⅱ) center of the two complexes is four-coordinated with distorted tetrahedral geometry. In complex 1, the Hg(Ⅱ) center is coordinated by one 3-pyridyl nitrogen atom and three iodide anions in a 1∶2 molar ratio of L¹ and mercury iodide. In complex 2, the Hg(Ⅱ) center is coordinated by two 4-pyridyl nitrogen atoms and two iodide anions in a 1∶1 molar ratio of L² and mercury iodide. In addition, the thermal stabilities, luminescence properties, together with vapor adsorption properties of the two complexes were investigated.
- coordination polymer,
- dipyridylamide,
- crystal structure,
- one-dimensional,
- vapor adsorption
1. [1]
  Ovsyannikov A, Solovieva S, Antipin I, Ferlay S. Coordination Polymers Based on Calixarene Derivatives: Structures and Properties[J]. Coord. Chem. Rev., 2017,352:151-186. doi: 10.1016/j.ccr.2017.09.004
2. [2]
  Sun J K, Yang X D, Yang G Y, Zhang J. Bipyridinium Derivative-Based Coordination Polymers: From Synthesis to Materials Applications[J]. Coord. Chem. Rev., 2019,378:533-560. doi: 10.1016/j.ccr.2017.10.029
3. [3]
  Li N, Feng R, Zhu J, Chang Z, Bu X H. Conformation Versatility of Ligands in Coordination Polymers: From Structural Diversity to Properties and Applications[J]. Coord. Chem. Rev., 2018,375:558-586. doi: 10.1016/j.ccr.2018.05.016
4. [4]
  Liu J Q, Luo Z D, Pan Y, Singh A K, Trivedi M, Kumar A. Recent Developments in Luminescent Coordination Polymers: Designing Strategies, Sensing Application and Theoretical Evidences[J]. Coord. Chem. Rev., 2020,406213145. doi: 10.1016/j.ccr.2019.213145
5. [5]
  Tay H M, Kyratzis N, Thoonen S, Boer S A, Turner D R, Hua C. Synthetic Strategies towards Chiral Coordination Polymers[J]. Coord. Chem. Rev., 2021,435213763. doi: 10.1016/j.ccr.2020.213763
6. [6]
  Chen Y T, Ding Y, He S X, Huang C, Chen D M, Zhu B X. Synthesis, Crystal Structures and Vapor Adsorption Properties of Mercury(Ⅱ) Coordination Polymers Derived from Two Dipyridylamide Ligands[J]. Z. Anorg. Allg. Chem., 2021,647:623-628. doi: 10.1002/zaac.202000346
7. [7]
  Li J X, Qin Z B, Li Y H, Cui G H. Sonochemical Synthesis and Properties of Two New Nanostructured Silver Coordination Polymers[J]. Ultrason. Sonochem., 2018,48:127-135. doi: 10.1016/j.ultsonch.2018.05.016
8. [8]
  Zhang H, Liu G, Shi L, Liu H, Wang T, Ye J. Engineering Coordination Polymers for Photocatalysis[J]. Nano Energy, 2016,22:149-168. doi: 10.1016/j.nanoen.2016.01.029
9. [9]
  Rosa I M L, Costa M C S, Vitto B S, Amorim L, Correa C C, Pinheiro C B, Doriguetto A C. Influence of Synthetic Methods in the Structure and Dimensionality of Coordination Polymers[J]. Cryst. Growth Des., 2016,16:1606-1616. doi: 10.1021/acs.cgd.5b01716
10. [10]
  WANG L B, WANG J J, YUE E L, TANG L, WANG X, HOU X Y, ZHANG Y Q. Synthesis, Structure, Magnetic and Photocatalytic Properties of Nickel(Ⅱ) Coordination Polymer Based on 1-(3, 5-Dicar-boxybenzyl)-1H-pyrazole-3, 5-dicarboxylic Acid Ligand[J]. Chinese J. Inorg. Chem., 2021,37(4):744-750.
11. [11]
  Feng X, Guo N, Chen H, Wang H, Yue L, Chen X, Ng S W, Liu X, Ma L, Wang L. A Series of Anionic Host Coordination Polymers Based on Azoxybenzene Carboxylate: Structures, Luminescence and Magnetic Properties[J]. Dalton Trans., 2017,46:14192-14200. doi: 10.1039/C7DT02974H
12. [12]
  Fan L, Zhang Y, Liang J, Wang X, Lv H, Wang J, Zhao L, Zhang X. Structural Diversity, Magnetic Properties, and Luminescence Sensing of Five 3D Coordination Polymers Derived from Designed 3, 5-Di(2', 4'-dicarboxylphenyl)benozoic Acid[J]. CrystEngComm, 2018,20:4752-4762. doi: 10.1039/C8CE00877A
13. [13]
  Yang X G, Zhai Z M, Lu X M, Zhao Y, Chang X H, Ma L F. Room Temperature Phosphorescence of Mn(Ⅱ) and Zn(Ⅱ) Coordination Polymers for Photoelectron Response Applications[J]. Dalton Trans., 2019,48:10785-10789. doi: 10.1039/C9DT02178G
14. [14]
  YANG X Q, HE C Y, ZHANG Y H, MU X G, JIANG S. Synthesis, Crystal Structure and Properties of Mn(Ⅱ)/Co(Ⅱ) Coordination Polymers Based on 1, 4-Bis(imidazol-1-yl) benzene[J]. Chinese J. Inorg. Chem., 2021,37(8):1364-1374.
15. [15]
  Tzeng B C, Chang T Y, Wei S L, Sheu H S. Reversible Phase Transformation and Mechanochromic Luminescence of Zn^Ⅱ-Dipyridylamide-Based Coordination Frameworks[J]. Chem. Eur. J., 2012,18:5105-5112. doi: 10.1002/chem.201103405
16. [16]
  Liu G C, Li Y, Xiong Y, Liu X X, Li Q M, Zhang J W, Lin H Y, Li X W. Spacers-Directed Structural Diversity of Co(Ⅱ)/Zn(Ⅱ) Complexes Based on S-/O-Bridged Dipyridylamides: Electrochemical, Fluorescent Recognition Behavior and Photocatalytic Properties[J]. J. Coord. Chem., 2018,71:483-501. doi: 10.1080/00958972.2018.1438606
17. [17]
  Cardile S A, Burchell T J, Jennings M C, Puddephatt R J. Self-Assembly of Polymers through Dynamic Coordination Chemistry and Hydrogen Bonding: Polymers from Mercury (Ⅱ) Halides and Bis(amidopyridine) Ligands[J]. J. Inorg. Organomet. Polym. Mater., 2007,17:235-240. doi: 10.1007/s10904-006-9088-x
18. [18]
  Fletcher B E, Peach M J G, Evans N H. Rapidly Accessible"Click" Rotaxanes Utilizing a Single Amide Hydrogen Bond Templating Motif[J]. Org. Biomol. Chem., 2017,15:2797-2803. doi: 10.1039/C7OB00284J
19. [19]
  Han L, Zhang K, Ishida H, Froimowicz P. Study of the Effects of Intramolecular and Intermolecular Hydrogen-Bonding Systems on the Polymerization of Amide-Containing Benzoxazines[J]. Macromol. Chem. Phys., 2017,2181600562. doi: 10.1002/macp.201600562
20. [20]
  Henderson W R, Kumar A, Abboud K A, Castellano R K. Influence of Amide Connectivity on the Hydrogen-Bond-Directed Self-Assembly of [n. n]Paracyclophanes[J]. Chem. Eur. J., 2020,26:17588-17597. doi: 10.1002/chem.202003909
21. [21]
  Markad D, Mandal S K. An Exploration into the Amide-Pseudo Amide Hydrogen Bonding Synthon between a New Coformer with Two Primary Amide Groups and Theophylline[J]. CrystEngComm, 2017,19:7112-7124. doi: 10.1039/C7CE01666B
22. [22]
  Kaneko R, Wu G, Sugawa K, Otsuki J. Intermolecular Electronic Communication in Tetrathiafulvalene Derivatives with Hydrogen-Bonding Amide Units[J]. J. Org. Chem., 2018,7:897-901.
23. [23]
  Sheldrick G M. SHELXT-Integrated Space-Group and Crystal-Structure Determination[J]. Acta Crystallogr. Sect. A, 2015,A71:3-8.
24. [24]
  Dolomanov O V, Bourhis L J, Gildea R J, Howard J A K, Puschmann H. OLEX2: A Complete Structure Solution, Refinement and Analysis Program[J]. J. Appl. Cryst., 2009,42:339-341. doi: 10.1107/S0021889808042726
25. [25]
  Yang L, Powell D R, Houser R P. Structural Variation in Copper(Ⅰ) Complexes with Pyridylmethylamide Ligands: Structural Analysis with a New Four-Coordinate Geometry Index, τ₄[J]. Dalton Trans., 2007:955-964.
26. [26]
  Lin L Z, Zhong Q X, Hong J T, Chen H L, Chen W T. Syntheses, Structures, Photoluminescence and Semiconductor Properties of Two Novel Mercury-Lanthanide Complexes with a Three-Dimensional Open Framework[J]. Inorg. Chim. Acta, 2018,479:30-35. doi: 10.1016/j.ica.2018.04.039
27. [27]
  Heering C, Francis B, Nateghi B, Makhloufi G, Lüdeke S, Janiak C. Syntheses, Structures and Properties of Group 12 Element (Zn, Cd, Hg) Coordination Polymers with a Mixed-Functional Phosphonate-Biphenylcarboxylate Linker[J]. CrystEngComm, 2016,18:5209-5223. doi: 10.1039/C6CE00587J
28. [28]
  Bigdeli F, Hosseini-Monfared H, Morsali A, Mayer P. Synthesis of a New Hg(Ⅱ) Coordination Polymer: Ultrasonic-Assisted Synthesis and Mechanical Preparation of Nanostructure[J]. Ultrason. Sonochem., 2017,39:669-675. doi: 10.1016/j.ultsonch.2017.03.055
29. [29]
  Chhetri P M, Yang X K, Chen J D. Isostructural Hg(Ⅱ) Halide Coordination Polymers: A Comparison of Powder XRD, IR, Emission and Hirshfeld Surface Analysis[J]. J. Mol. Struct., 2021,1239130543. doi: 10.1016/j.molstruc.2021.130543
30. [30]
  Xu C, Li L, Wang Y, Guo Q, Wang X, Hou H, Fan Y. Three-Dimensional Cd(Ⅱ) Coordination Polymers Based on Semirigid Bis(methyl-benzimidazole) and Aromatic Polycarboxylates: Syntheses, Topological Structures and Photoluminescent Properties[J]. Cryst. Growth Des., 2011,11:4667-4675. doi: 10.1021/cg200961a
31. [31]
  Huang C, Yang J, Chen J L, Chen D M, Zhu B X. Synthesis and Crystal Structures of Metallomacrocyclic and Helical Hg(Ⅱ) Complexes with Two Bis(pyridylurea) Ligands[J]. Inorg. Chim. Acta, 2018,483:252-257. doi: 10.1016/j.ica.2018.08.020
32. [32]
  Huang C, Luo X, Zhai J, Chen Y, Chen D M, Zhu B X. [2+2] or[4+ 4] Metallamacrocycle: Synthesis and Crystal Structures of Hg(Ⅱ) Complexes Derived from Two Flexible Bis(pyridylurea) Ligands[J]. Polyhedron, 2019,165:111-115. doi: 10.1016/j.poly.2019.03.012
33. [33]
  Chen D M, Wu X F, Liu Y J, Huang C, Zhu B X. Synthesis, Crystal Structures and Vapor Adsorption Properties of Hg(Ⅱ) and Cd(Ⅱ) Coordination Polymers Derived from Two Hydrazone Schiff Base Ligands[J]. Inorg. Chim. Acta, 2019,494:181-186. doi: 10.1016/j.ica.2019.05.026
1. [1]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
4. [4]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
5. [5]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
6. [6]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
7. [7]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
8. [8]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
9. [9]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
10. [10]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
11. [11]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
12. [12]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
13. [13]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
14. [14]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
15. [15]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
16. [16]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
19. [19]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
20. [20]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(312)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142