Citation: Xue-Dong WEI, Nan LIU, Shuang-Yan QIAO. Preparation and Oxygen Evolution Reaction Electrocatalytic Performance of NiMoO₄ Nanowires@ZnCo MOF(350) Core-Shell Structure Composites[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2308-2320. doi: 10.11862/CJIC.2022.231 shu

Preparation and Oxygen Evolution Reaction Electrocatalytic Performance of NiMoO₄ Nanowires@ZnCo MOF(350) Core-Shell Structure Composites

School of Chemistry & Material Science, Shanxi Normal University, Taiyuan 030031, China

Corresponding author: Xue-Dong WEI, weixd@sxnu.edu.cn
Received Date: 18 June 2022
Revised Date: 18 September 2022

Figures(9)

A novel NiMoO₄ NWs@ZnCo MOF (NWs=nanowires) was successfully synthesized by making a layer of ZnCo metal-organic framework (MOF) nanocrystals in situ grown on the NiMoO₄ NWs by liquid phase synthesis and then it was heat-treated at 350 ℃ (named NiMoO₄ NWs@ZnCo MOF(350)). It was found that the structure and morphology of the precursor were still well maintained after heat treatment, but a very small amount of Co₃O₄ phase appeared in ZnCo MOF, indicating that slight pyrolysis occurred. Chemical bonds C—O—Mo and a large number of oxygen vacancies generated at the phase heterointerfaces can become the source of active sites. The formation of a new Co₃O₄ phase also leads to a further increase in the heterophase interfaces. Furthermore, a little pyrolysis made the surface of the core-shell structure more coarse, loose, and porous, producing a higher specific surface area, faster ionic diffusion path, and better electrical conductivity. Therefore, according to the inert glassy carbon electrode test, the electrocatalyst exhibited a low overpotential of 360 mV at the current density of 10 mA·cm^-2 and maintained long-term catalytic stability of 30 000 s.
- metal-organic framework,
- nanomaterials,
- core-shell structure,
- oxygen evolution reaction,
- electrocatalysts
1. [1]
  Paul A, Upadhyay K K, Backovic G, Karmakar A, Ferreira L F V, Sljukic B, Montemor M F, da Silva M F C G, Pombeiro A J L. Versatility of Amide-Functionalized Co (Ⅱ) and Ni(Ⅱ) Coordination Polymers: From Thermochromic-Triggered Structural Transformations to Supercapacitors and Electrocatalysts for Water Splitting[J]. Inorg. Chem., 2020,59:16301-16318. doi: 10.1021/acs.inorgchem.0c02084
2. [2]
  Wang X Z, Liu S, Zhang H, Zhang S S, Meng G, Liu Q, Sun Z Y, Luo J, Liu X J. Polycrystalline SnS_x Nanofilm Enables CO₂ Electroreduction to Formate with High Current Density[J]. Chem. Commun., 2022,58:7654-7657. doi: 10.1039/D2CC01888H
3. [3]
  Meng G, Wei T R, Liu W J, Li W B, Zhang S S, Liu W X, Liu Q, Bao H H, Luo J, Liu X J. NiFe Layered Double Hydroxide Nanosheet Array for High-Efficiency Electrocatalytic Reduction of Nitric Oxide to Ammonia[J]. Chem. Commun., 2022,58:8097-8100. doi: 10.1039/D2CC02463B
4. [4]
  Li X F, Ma D D, Cao C S, Zou R Q, Xu Q, Wu X T, Zhu Q L. Inlaying Ultrathin Bimetallic MOF Nanosheets into 3D Ordered Macroporous Hydroxide for Superior Electrocatalytic Oxygen Evolution[J]. Small, 2019,151902218. doi: 10.1002/smll.201902218
5. [5]
  Chen X, Xu M Y, Li S, Li C C, Sun X C, Mu S C, Yu J. Ultrafine IrNi Bimetals Encapsulated in Zeolitic Imidazolate Frameworks-Derived Porous N-Doped Carbon for Boosting Oxygen Evolution in Both Alkaline and Acidic Electrolytes[J]. Adv. Mater. Interfaces, 2020,7202001145.
6. [6]
  Hou J R, Peng X Y, Sun J Q, Zhang S S, Liu Q, Wang X Z, Luo J, Liu X J. Accelerating Hydrazine-Assisted Hydrogen Production Kinetics with Mn Dopant Modulated CoS₂ Nanowire Arrays[J]. Inorg. Chem. Front., 2022,9:3047-3058.
7. [7]
  Li L F, Wang P T, Huang X Q, Young D J, Wang H F, Braunstein P, Lang J P. Large-Scale, Bottom-Up Synthesis of Binary Metal-Organic Framework Nanosheets for Efficient Water Oxidation[J]. Angew. Chem. Int. Ed., 2019,58:7051-7056.
8. [8]
  Yang M S, Liu Y F, Sun J Q, Zhang S S, Liu X J, Luo J. Integration of Partially Phosphatized Bimetal Centers into Trifunctional Catalyst for High-Performance Hydrogen Production and Flexible Zn-Air Battery[J]. Sci. China Mater., 2022,65:1176-1186. doi: 10.1007/s40843-021-1902-2
9. [9]
  Li L F, Shao P, Huang X Q, Lang J P. Nanoscale Trimetallic Metal-Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis[J]. Angew. Chem. Int. Ed., 2018,57:1888-1892. doi: 10.1002/anie.201711376
10. [10]
  Wu L L, Wang Q S, Li J, Long Y, Liu Y, Song S Y, Zhang H J. Co₉S₈ Nanoparticles-Embedded N/S-Codoped Carbon Nanofibers Derived from Metal-Organic Framework-Wrapped CdS Nanowires for Efficient Oxygen Evolution Reaction[J]. Small, 2018,141704035. doi: 10.1002/smll.201704035
11. [11]
  Xu Y Y, Deng P L, Chen G D, Chen Y X, Yan Y, Qi K, Liu H F, Xia B Y. 2D Nitrogen-Doped Carbon Nanotubes/Graphene Hybrid as Bifunctional Oxygen Electrocatalyst for Long-Life Rechargeable Zn-Air Batteries[J]. Adv. Funct. Mater., 2020,301906081. doi: 10.1002/adfm.201906081
12. [12]
  Bai Z Y, Heng J M, Zhang Q, Yang L, Chang F F. Rational Design of Dodecahedral MnCo₂O_4.5 Hollowed-Out Nanocages as Efficient Bifunctional Electrocatalysts for Oxygen Reduction and Evolution[J]. Adv. Energy Mater., 2018,81802390. doi: 10.1002/aenm.201802390
13. [13]
  Yu P, Wang L, Sun F F, Xie Y, Liu X, Ma J Y, Wang X W, Tian C G, Li J H, Fu H G. Co Nanoislands Rooted on Co-N-C Nanosheets as Efficient Oxygen Electrocatalyst for Zn-Air Batteries[J]. Adv. Mater., 2019,311901666.
14. [14]
  Amiinu I S, Pu Z H, Liu X B, Owusu K A, Monestel H G R, Boakye F O, Zhang H N, Mu S C. Multifunctional Mo-N/C@MoS₂ Electrocatalysts for HER, OER, ORR, and Zn-Air Batteries[J]. Adv. Funct. Mater., 2017,271702300. doi: 10.1002/adfm.201702300
15. [15]
  Chen Z L, Wu R B, Liu Y, Ha Y, Guo Y H, Sun D L, Liu M, Fang F. Ultrafine Co Nanoparticles Encapsulated in Carbon-Nanotubes-Grafted Graphene Sheets as Advanced Electrocatalysts for the Hydrogen Evolution Reaction[J]. Adv. Mater., 2018,301802011. doi: 10.1002/adma.201802011
16. [16]
  Wang X, Ma Z J, Chai L L, Xu L Q, Zhu Z Y, Hu Y, Qian J J, Huang S M. MOF Derived N-Doped Carbon Coated CoP Particle/Carbon Nanotube Composite For Efficient Oxygen Evolution Reaction[J]. Carbon, 2019,141:643-651.
17. [17]
  Wan J, Wu J B, Gao X, Li T Q, Hu Z M, Yu H M, Huang L. Structure Confined Porous Mo 2C for Efficient Hydrogen Evolution[J]. Adv. Funct. Mater., 2017,27(45)1703933. doi: 10.1002/adfm.201703933
18. [18]
  Sun L S, Wang C L, Sun Q J, Cheng Y, Wang L M. Self-Assembly of Hierarchical Ni-Mo-Polydopamine Microflowers and Their Conversion to a Ni-Mo₂C/C Composite for Water Splitting[J]. Chem. Eur. J., 2017,23:4644-4650. doi: 10.1002/chem.201605928
19. [19]
  Guo D, Zhang P, Zhang H M, Yu X Z, Zhu J, Li Q H, Wang T H. NiMoO₄ Nanowires Supported On Ni Foam as Novel Advanced Electrodes for Supercapacitors[J]. J. Mater. Chem. A, 2013,1:9024-9027. doi: 10.1039/c3ta11487b
20. [20]
  He D, Gao Y, Yao Y, Wu L, Zhang J, Huang Z H, Wang M X. Asymmetric Supercapacitors Based on Hierarchically Nanoporous Carbon and ZnCo₂O₄ from a Single Biometallic Metal Organic Frameworks (Zn/Co-MOF)[J]. Front. Chem., 2020,8719. doi: 10.3389/fchem.2020.00719
21. [21]
  Erarkc E, Kranan K D, Topu E. Three-Dimensional ZnCo-MOF Modified Graphene Sponge: Flexible Electrode Material for Symmetric Supercapacitor[J]. Energy Fuels, 2022,36:1735-1745. doi: 10.1021/acs.energyfuels.1c04183
22. [22]
  Dong B, Zhao X, Han G Q, Li X, Shang X, Liu Y R, Hu W H, Chai Y M, Zhao H, Liu C G. Two-Step Synthesis of Binary Ni-Fe Sulfides Supported on Nickel Foam as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction[J]. J. Mater. Chem. A, 2016,4:13499-13508. doi: 10.1039/C6TA03177C
23. [23]
  Li Y Q, Xu H B, Huang H Y, Wang C, Gao L G, Ma T L. One-Dimensional MoO₂-Co₂Mo₃O₈@C Nanorods: A Novel and Highly Efficient Oxygen Evolution Reaction Catalyst Derived from Metal-Organic Framework Composites[J]. Chem. Commun., 2018,54:2739-2742.
24. [24]
  Fu Y, Wang W J, Wang J W, Li X N, Shi R, Peng O, Chandrashekar B N, Liu K, Amini A, Cheng C. MOFs-Derived ZnCo-Fe Core-Shell Nanocages with Remarkable Oxygen Evolution Reaction Performance[J]. J. Mater. Chem. A, 2019,7:17299-17305.
25. [25]
  Sun J, Xue H, Guo N K, Song T S, Hao Y R, Sun J W, Zhang J W, Wang Q. Synergetic Metal Defect and Surface Chemical Reconstruction into NiCo₂S₄/ZnS Heterojunction to Achieve Outstanding Oxygen Evolution Performance[J]. Angew. Chem. Int. Ed., 2021,60:19435-19441.
26. [26]
  An L, Huang B L, Zhang Y, Wang R, Zhang N, Dai T Y, Xi P X, Yan C H. Interfacial Defect Engineering for Improved Portable Zinc-Air Batteries with a Broad Working Temperature[J]. Angew. Chem. Int. Ed., 2019,58:9459-9463.
27. [27]
  Shang C Q, Li M C, Wang Z Y, Wu S F, Lu Z G. Electrospun Nitrogen-Doped Carbon Nanofibers Encapsulating Cobalt Nanoparticles as Efficient Oxygen Reduction Reaction Catalysts[J]. ChemElectroChem, 2016,3:1437-1445.
28. [28]
  Li L J, Liu S Y, Manthiram A. Co₃O₄ Nanocrystals Coupled with O-and N-Doped Carbon Nanoweb as a Synergistic Catalyst for Hybrid Li-Air Batteries[J]. Nano Energy, 2015,12:852-860.
29. [29]
  Chen Z L, Wang S F, Zhang Z B, Zhou W L, Chen D J. Facile Synthesis of Co₃O₄/Co@N-Doped Carbon Nanotubes as Anode with Improved Cycling Stability for Li-Ion Batteries[J]. Electrochim. Acta, 2018,292:575-585.
30. [30]
  Kim Y, Noh Y, Han H, Bae J, Park S, Lee S, Yoon W, Kim Y K, Ahn H, Ham M H, Kim W B. Effect of N-Doped Carbon Layer on Co₃O₄ Nanowire-Graphene Composites as Anode Materials for Lithium Ion Batteries[J]. J. Phys. Chem. Solids, 2019,124:266-273.
31. [31]
  Lin Z Y, Waller G, Liu Y, Liu M L, Wong C P. Facile Synthesis of Nitrogen-Doped Graphene via Pyrolysis of Graphene Oxide and Urea, and Its Electrocatalytic Activity toward the Oxygen-Reduction Reaction[J]. Adv. Energy Mater., 2012,2:884-888.
32. [32]
  Wu Y H, Li Y W, Gao J G, Zhang Q C. Recent Advances in Vacancy Engineering of Metal-Organic Frameworks and Their Derivatives for Electrocatalysis[J]. SusMat, 2021,1:66-87.
33. [33]
  Chong S K, Sun L, Shu C Y, Guo S W, Liu Y N, Wang W, Liu H K. Chemical Bonding Boosts Nano-rose-like MoS2 Anchored on Reduced Graphene Oxide for Superior Potassium-Ion Storage[J]. Nano Energy, 2019,63103868.
34. [34]
  Zhou Y N, Wang F L, Dou S Y, Shi Z N, Dong B, Yu W L, Zhao H Y, Wang F G, Yu J F, Chai Y M. Motivating High-Valence Nb Doping by Fast Molten Salt Method for NiFe Hydroxides toward Efficient Oxygen Evolution Reaction[J]. Chem. Eng. J., 2022,427131643.
1. [1]
  Shaohua YANG , Na'na GAO , Yaqiong GONG . Metal-organic framework-templated construction of FeOOH@CoMoO₄/nickel foam heterostructure for enhanced oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2175-2185. doi: 10.11862/CJIC.20250218
2. [2]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
3. [3]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
4. [4]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
5. [5]
  Yifan LIU , Zhan ZHANG , Rongmei ZHU , Ziming QIU , Huan PANG . A three-dimensional flower-like Cu-based composite and its low-temperature calcination derivatives for efficient oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 979-990. doi: 10.11862/CJIC.20240008
6. [6]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
7. [7]
  Hongzhe GUO , Sen WANG , Lu YANG , Fucheng LIU , Jiongpeng ZHAO , Zhaoquan YAO . Highly selective acetylene capture by a pacs-type metal-organic framework constructed using metal-formate complexes as pore partition units. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2157-2164. doi: 10.11862/CJIC.20250179
8. [8]
  Xinnan XIE , Boyu ZHANG , Jianxun YANG , Yi ZHONG , Younis Osama , Jianxiao YANG , Xinchun YANG . Ultrafine platinum clusters achieved by metal-organic framework derived cobalt nanoparticle/porous carbon: Remarkable catalytic performance in dehydrogenation of ammonia borane. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2095-2102. doi: 10.11862/CJIC.20250025
9. [9]
  Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti₄L₆ cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
10. [10]
  Shanqing YANG , Lulu WANG , Qiang ZHANG , Jiajia LI , Yilong LI , Tongliang HU . A propane-selective metal-organic framework for inverse selective adsorption propane/propylene separation. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2138-2148. doi: 10.11862/CJIC.20250154
11. [11]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
12. [12]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
13. [13]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
14. [14]
  Min ZHU , Yuxin WANG , Xiao LI , Yaxu XU , Junwen ZHU , Zihao WANG , Yu ZHU , Xiaochen HUANG , Dan XU , Monsur Showkot Hossain Abul . Construction of AgVO₃/ZIF-8 composites for enhanced degradation of tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 994-1006. doi: 10.11862/CJIC.20240392
15. [15]
  Ri PENG , Yingxiang BAI , Yuxin XIE , Dunru ZHU . cis/trans-Octahedral configuration induced topologically different MOFs: Syntheses, structures, and Hirshfeld surface analyses. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1650-1660. doi: 10.11862/CJIC.20250143
16. [16]
  Bangdi GE , Xiaowei SONG , Zhiqiang LIANG . A bifunctional three-dimensional Eu-MOF fluorescent probe for highly sensitive detection of 2, 4, 6-trinitrophenol and tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2165-2174. doi: 10.11862/CJIC.20250190
17. [17]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
18. [18]
  Guoliang Gao , Guangzhen Zhao , Guang Zhu , Bowen Sun , Zixu Sun , Shunli Li , Ya-Qian Lan . Recent advancements in noble-metal electrocatalysts for alkaline hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(1): 109557-. doi: 10.1016/j.cclet.2024.109557
19. [19]
  Ruige ZHANG , Zhe ZHANG , He ZHENG , Zhan SHI . Recent advances of metal-organic frameworks for alkaline electrocatalytic oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2011-2028. doi: 10.11862/CJIC.20250185
20. [20]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(1597)
HTML views(272)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Oxygen Evolution Reaction Electrocatalytic Performance of NiMoO4 Nanowires@ZnCo MOF(350) Core-Shell Structure Composites

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Oxygen Evolution Reaction Electrocatalytic Performance of NiMoO₄ Nanowires@ZnCo MOF(350) Core-Shell Structure Composites