Citation: Yang-Zheng CAO, Wei PAN, Chuan-Jiang ZHOU, Jun-Yong ZHANG, Hao XU, Chun-Hua GONG, Hui-Ting XU, Run-Pu SHEN, Sui-Jun LIU, Jing-Li XIE. A Series of Metal-Organic Frameworks Based on Mixed Ligand Strategy: Synthesis, Structures, and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2143-2153. doi: 10.11862/CJIC.2022.229 shu

A Series of Metal-Organic Frameworks Based on Mixed Ligand Strategy: Synthesis, Structures, and Properties

Yang-Zheng CAO ^{1, 4} ,
Wei PAN ¹ ,
Chuan-Jiang ZHOU ¹ ,
Jun-Yong ZHANG ^1,, ,
Hao XU ¹ ,
Chun-Hua GONG ^2,, ,
Hui-Ting XU ³ ,
Run-Pu SHEN ³ ,
Sui-Jun LIU ⁴ ,
Jing-Li XIE ^4,,

1.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
2.
College of Advanced Materials Engineering, Jiaxing Nanhu University, Jiaxing, Zhejiang 314001, China
3.
Zhejiang Engineering Research Center of Fat - Soluble Vitamin, Shaoxing University, Shaoxing, Zhejiang 312000, China
4.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: Jun-Yong ZHANG, zhangjy@mail.zjxu.edu.cn Chun-Hua GONG, gongch@jxnhu.edu.cn Jing-Li XIE, jlxie@mail.zjxu.edu.cn
Received Date: 20 April 2022
Revised Date: 15 September 2022

Figures(9)

Taking advantage of a basic ligand (BPCH=2, 6 -bis(4-pyridyl methylidene)cyclohexanone) and three acid ligands (H₂TP=terephthalic acid, H₂IP=isophthalic acid, H₃TMA=1, 3, 5 - benzenetricarboxylic acid), seven metal - organic frameworks (MOFs) 1-7 have been achieved by using this acid - base mixed - ligand synthetic strategy. These complexes were characterized by single-crystal X-ray diffraction, IR spec- tra, powder X-ray diffraction, and thermogravimetric analysis. Diverse 3D structural characters of MOFs 1-3 or 2D structural characters of MOFs 4-7 have been observed. The fluorescence properties of these complexes have been explored, indicating that they had selectivity towards Fe³⁺ ions. Several complexes had shown certain performance for adsorbing dye molecules.
- metal-organic frameworks,
- mixed-ligand strategy,
- fluorescence,
- dye adsorption
1. [1]
  Oisaki K, Li Q, Furukawa H, Czaja A U, Yaghi O M. A Metal-Organic Framework with Covalently Bound Organometallic Complexes[J]. J. Am. Chem. Soc., 2010,132:9262-9264. doi: 10.1021/ja103016y
2. [2]
  Kitagawa S, Kitaura R, Noro S. Functional Porous Coordination Polymers[J]. Angew. Chem. Int. Ed., 2004,43:2334-2375. doi: 10.1002/anie.200300610
3. [3]
  Peng P, Li F F, Neti V S P K, Metta-Magana A J, Echegoyen L. Design, Synthesis, and X-ray Crystal Structure of a Fullerene-Linked Metal-Organic Framework[J]. Angew. Chem. Int. Ed., 2014,53:160-163. doi: 10.1002/anie.201306761
4. [4]
  Wang X N, Zhang P, Kirchon A, Li J L, Chen W M, Zhao Y M, Li B, Zhou H C. Crystallographic Visualization of Postsynthetic Nickel Clusters into Metal-Organic Framework[J]. J. Am. Chem. Soc., 2019,141:13654-13663. doi: 10.1021/jacs.9b06711
5. [5]
  Xiao J D, Jiang H L. Metal -Organic Frameworks for Photocatalysis and Photothermal Catalysis[J]. Acc. Chem. Res., 2019,52:356-366. doi: 10.1021/acs.accounts.8b00521
6. [6]
  Yoon M, Srirambalaji R, Kim K. Homochiral Metal-Organic Frameworks for Asymmetric Heterogeneous Catalysis[J]. Chem. Rev., 2012,112:1196-1231. doi: 10.1021/cr2003147
7. [7]
  Li H, Wang K C, Sun Y J, Lollar C T, Li J L, Zhou H C. Recent Advances in Gas Storage and Separation Using Metal-Organic Frameworks[J]. Mater. Today, 2018,21:108-121. doi: 10.1016/j.mattod.2017.07.006
8. [8]
  Li J, Jiang L, Chen S, Kirchon A, Li B, Li Y, Zhou H C. Metal-Organic Framework Containing Planar Metal-Binding Sites: Efficiently and Cost-Effectively Enhancing the Kinetic Separation of C₂H₂/C₂H₄[J]. J. Am. Chem. Soc., 2019,141:3807-3811. doi: 10.1021/jacs.8b13463
9. [9]
  Mi X N, Sheng D F, Yu Y, Wang Y H, Zhao L M, Lu J, Li Y W, Li D C, Dou J M, Duan J G, Wang S N. Tunable Light Emission and Multiresponsive Luminescent Sensitivities in Aqueous Solutions of Two Series of Lanthanide Metal-Organic Frameworks Based on Structurally Related Ligands[J]. ACS Appl. Mater. Interfaces, 2019,11:7914-7926. doi: 10.1021/acsami.8b18320
10. [10]
  Yang X G, Ma L F, Yan D P. Facile Synthesis of 1D Organic-Inorganic Perovskite Micro-belts with High Water Stability for Sens-ing and Photonic Applications[J]. Chem. Sci., 2019,10:4567-4572. doi: 10.1039/C9SC00162J
11. [11]
  Zhao F, Guo X Y, Dong Z P, Liu Z L, Wang Y Q. 3D Ln^Ⅲ-MOFs: Slow Magnetic Relaxation and Highly Sensitive Luminescence Detection of Fe³⁺ and Ketones[J]. Dalton Trans., 2018,47:8972-8982. doi: 10.1039/C8DT01034J
12. [12]
  Wang H Y, Ge J Y, Hua C, Jiao C Q, Wu Y, Leong C F, D'Alessandro D M, Liu T, Zuo J L. Photo-and Electronically Switchable Spin-Crossover Iron(Ⅱ) Metal-Organic Frameworks Based on a Tetrathia-fulvalene Ligand[J]. Angew. Chem. Int. Ed., 2017,56:5465-5470. doi: 10.1002/anie.201611824
13. [13]
  Coronado E, Espallargas G M. Dynamic Magnetic MOFs[J]. Chem. Soc. Rev., 2013,42:1525-1539. doi: 10.1039/C2CS35278H
14. [14]
  Lustig W P, Mukherjee S, Rudd N D, Desai A V, Li J, Ghosh S K. Metal-Organic Frameworks: Functional Luminescent and Photonic Materials for Sensing Applications[J]. Chem. Soc. Rev., 2017,46:3242-3285.
15. [15]
  Easun T L, Jia J, Calladine J A, Blackmore D L, Stapleton C S, Vuong K Q, Champness N R, George M W. Photochemistry in a 3D Metal-Organic Framework (MOF): Monitoring Intermediates and Reactivity of the fac -to-mer Photoisomerization of Re(diimine)(CO)₃Cl Incorporated in a MOF[J]. Inorg. Chem., 2014,53:2606-2612. doi: 10.1021/ic402955e
16. [16]
  Zou J Y, Li L, You S Y, Chen K H, Dong X N, Chen Y H, Cui J Z. A usf Zinc(Ⅱ) Metal -Organic Framework as a Highly Selective Luminescence Probe for Acetylacetone Detection and Its Postsynthetic Cation Exchange[J]. Cryst. Growth Des., 2018,18:3997-4003. doi: 10.1021/acs.cgd.8b00344
17. [17]
  Huang R W, Wei Y S, Dong X Y, Wu X H, Du C X, Zang S Q, Mak T C W. Hypersensitive Dual-Function Luminescence Switching of a Silver-Chalcogenolate Cluster -Based Metal -Organic Framework[J]. Nat. Chem., 2017,9:689-697. doi: 10.1038/nchem.2718
18. [18]
  Huang W, Hu G B, Yao L Y, Yang Y, Liang W B, Yuan R, Xiao D R. Matrix Coordination-Induced Electrochemiluminescence Enhancement of Tetraphenylethylene-Based Hafnium Metal-Organic Framework: An Electrochemiluminescence Chromophore for Ultrasensitive Electrochemiluminescence Sensor Construction[J]. Anal. Chem., 2020,92:3380-3387.
19. [19]
  Du M, Li C P, Liu C S, Fang S M. Design and Construction of Coordination Polymers with Mixed -Ligand Synthetic Strategy[J]. Coord. Chem. Rev., 2013,257:1282-1305.
20. [20]
  Yin Z, Zhou Y L, Zeng M H, Kurmoo M. The Concept of Mixed Organic Ligands in Metal-Organic Frameworks: Design, Tuning and Functions[J]. Dalton Trans., 2015,44:5258-5275.
21. [21]
  Bhattacharyya S, Maji T K. Multi-Dimensional Metal-Organic Frameworks Based on Mixed Linkers: Interplay between Structural Flexibility and Functionality[J]. Coord. Chem. Rev., 2022,469214645.
22. [22]
  Zhang Y J, Gao L L, Zhou W D, Wei X Q, Hu T P. Synthesis and Magnetic Properties of Two Mn-based Coordination Polymers Constructed by a Mixed-Ligand Strategy[J]. CrystEngComm, 2020,22:7123-7128.
23. [23]
  Yu G H, Yang C L, Zhao H L, Yu A X, Zhang G, Du D Y, Su Z M. Mixed-Linker Strategy for the Construction of Metal-Organic Framework Combined with Dyes toward Alcohol Detection[J]. Inorg. Chem., 2022,61:5318-5325.
24. [24]
  Sheldrick G M. Crystal Structure Refinement with SHELXL[J]. Acta Crystallogr. Sect. C, 2015,C71:3-8.
25. [25]
  Spek A L. PLATON SQUEEZE: A Tool for the Calculation of the Disordered Solvent Contribution to the Calculated Structure Factors[J]. Acta Crystallogr. Sect. C, 2015,C71:9-18.
26. [26]
  Zhao D, Liu X H, Zhao Y, Wang P, Liu Y, Azam M, Al-Resayes S I, Lu Y, Sun W Y. Luminescent Cd(Ⅱ)-Organic Frameworks with Chelating NH₂ Sites for Selective Detection of Fe(Ⅲ) and Antibiotics[J]. J. Mater. Chem. A, 2017,5:15797-15807.
27. [27]
  Wang Y, Xu P, Xie Q, Ma Q Q, Meng Y H, Wang Z W, Zhang S, Zhao X J, Chen J, Wang Z L. Cadmium(Ⅱ)-Triazole Framework as a Luminescent Probe for Ca²⁺ and Cyano Complexes[J]. Chem. Eur. J., 2016,22:10459-10474.
28. [28]
  Liu W L, Yu J H, Jiang J H, Yuan L M, Xu B, Liu Q A, Qu B T, Zhang G Q, Yan C G. Hydrothermal Syntheses, Structures and Luminescent Properties of Zn(Ⅱ) Coordination Polymers Assembled with Benzene-1, 2, 3-Tricarboxylic Acid Involving In Situ Ligand Reactions[J]. CrystEngComm, 2011,13:2764-2773.
29. [29]
  Xu H, Zeng X H, Pan W, Zhang J Y, Cao Y Z, Guo H Y, Xie J L. Structural Diversity of Metal-Organic Frameworks Based on a Chalcone Dicarboxylic Acid Ligand[J]. Dalton Trans., 2020,49:5783-5786.
30. [30]
  Pan W, Gong C H, Zeng X H, Hu C Y, Zhang Y, Zhu D R, Xu H, Guo H Y, Zhang J Y, Xie J L. Assembly of Porous Lanthanide Metal-Organic Frameworks Constructed by Chalcone Dicarboxylic Acid and Exploration of Their Properties[J]. Polyhedron, 2019,169:24-31.
31. [31]
  PAN W, MA C X, ZHOU C J, ZHANG L, ZHANG J Y, SHI Y B, XU H, ZHU D R, XIE J L. Synthesis and Characterization of Metal-Organic Framework Based on 2, 6-Bis(4-carboxybenzylidene)cyclo-hexanone[J]. Chinese J. Inorg. Chem., 2021,37(5):953-960.
32. [32]
  Zhang J Y, Gong C H, Zeng X H, Xie J L. Continuous Flow Chemistry: New Strategies for Preparative Inorganic Chemistry[J]. Coord. Chem. Rev., 2016,324:39-53.
33. [33]
  Zhang J Y, Chang S Q, Suryanto B H R, Gong C H, Zeng X H, Zhao C, Zeng Q D, Xie J L. Efficient Synthesis of Ir-Polyoxometalate Cluster Using a Continuous Flow Apparatus and STM Investigation of Its Coassembly Behavior on HOPG Surface[J]. Inorg. Chem., 2016,55:5585-5591.
34. [34]
  Gong C H, Zhang J Y, Zeng X H, Xie J L. Highly Effective Synthesis of a Cobalt(Ⅱ) Metal-Organic Coordination Polymer by Using Continuous Flow Chemistry[J]. Dalton Trans., 2017,46:25-28.
35. [35]
  Xie J L, Zhao D Y. Continuous-Flow Photochemistry: An Expanding Horizon of Sustainable Technology[J]. Chin. Chem. Lett., 2020,31:2395-2400.
1. [1]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
2. [2]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
3. [3]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
4. [4]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
5. [5]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
6. [6]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
7. [7]
  Ruowen Liang , Chao Zhang , Guiyang Yan . Enhancing CO2 cycloaddition through ligand functionalization: A case study of UiO-66 metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(2): 100211-100211. doi: 10.1016/j.cjsc.2023.100211
8. [8]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
9. [9]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
10. [10]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
11. [11]
  Jian Yang , Guang Yang , Zhijie Chen . Capturing carbon dioxide from air by using amine-functionalized metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(5): 100267-100267. doi: 10.1016/j.cjsc.2024.100267
12. [12]
  Longlong Geng , Huiling Liu , Wenfeng Zhou , Yong-Zheng Zhang , Hongliang Huang , Da-Shuai Zhang , Hui Hu , Chao Lv , Xiuling Zhang , Suijun Liu . Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics: A combined experimental and theoretical study. Chinese Chemical Letters, 2024, 35(8): 109120-. doi: 10.1016/j.cclet.2023.109120
13. [13]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
14. [14]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
15. [15]
  Xue-Zhi Wang , Yi-Tong Liu , Chuang-Wei Zhou , Bei Wang , Dong Luo , Mo Xie , Meng-Ying Sun , Yong-Liang Huang , Jie Luo , Yan Wu , Shuixing Zhang , Xiao-Ping Zhou , Dan Li . Amplified circularly polarized luminescence of chiral metal-organic frameworks via post-synthetic installing pillars. Chinese Chemical Letters, 2024, 35(10): 109380-. doi: 10.1016/j.cclet.2023.109380
16. [16]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
17. [17]
  Zheng Zhao , Ben Zhong Tang . An efficient strategy enabling solution processable thermally activated delayed fluorescence emitter with high horizontal dipole orientation. Chinese Journal of Structural Chemistry, 2024, 43(6): 100270-100270. doi: 10.1016/j.cjsc.2024.100270
18. [18]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
19. [19]
  Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO₃₋_x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753
20. [20]
  Junhua Wang , Xin Lian , Xichuan Cao , Qiao Zhao , Baiyan Li , Xian-He Bu . Dual polarization strategy to enhance CH₄ uptake in covalent organic frameworks for coal-bed methane purification. Chinese Chemical Letters, 2024, 35(8): 109180-. doi: 10.1016/j.cclet.2023.109180

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(586)
HTML views(86)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142