Citation: Fen-Fang LI, Jing HE. Synthesis, Structural and Magnetic Characterization of Fe(Ⅱ)/Co(Ⅱ)Isomorphous Complexes Based on a Dipyrazole-Containing Tetracarboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2259-2266. doi: 10.11862/CJIC.2022.226 shu

Synthesis, Structural and Magnetic Characterization of Fe(Ⅱ)/Co(Ⅱ)Isomorphous Complexes Based on a Dipyrazole-Containing Tetracarboxylate Ligand

Fen-Fang LI ^, ,
Jing HE

Department of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030600, China

Corresponding author: Fen-Fang LI, lffspring@126.com
Received Date: 14 March 2022
Revised Date: 16 September 2022

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We herein report the synthetic, structural, and magnetic studies on two 2D isomorphous complexes, {(NH₂(CH₃)₂)₂[M(L)]}_n (M=Fe (1), Co (2), H₄L=1, 1'-(1, 4-phenylenebis(methylene))bis(1H-pyrazole -3, 5-dicarboxylic acid)). From single crystal X-ray crystallography, it is found that the complexes crystallized in the same space group monoclinic P2₁ / n and have six - coordinate octahedron structures. The framework features anionic having a -2 charge, and the electroneutrality is achieved by the incorporation of the protonated dimethylamine by hydrolysis of DMF in the voids of the net. In the two polymers, each ligand bridges two metal(Ⅱ) ions through cheating N, O atoms of the pyrazole ring and monodentate O atoms of the same pyrazole ring, forming ⋯M-L-M-L⋯ chains and the 1D chains intersect to form an infinite 2D network which contains nearly square M₄L₄ units. Magnetic susceptibility measurements indicate the presence of antiferromagnetic properties in complexes 1 and 2.
- crystal structure,
- 1, 1'-(1, 4-phenylenebis(methylene))bis(1H-pyrazole-3, 5-dicarboxylic acid,
- Fe(Ⅱ) complex,
- Co(Ⅱ) complex,
- magnetic properties,
- coordination polymers
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