Citation: Chun-Hua BAI, Huan-Jian HOU, Xiao-Ning YANG, Guang-Hui LI. Fluorescence and Biomineralization Ability of Erbium-Doped Hydroxyapatite[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(11): 2154-2164. doi: 10.11862/CJIC.2022.224 shu

Fluorescence and Biomineralization Ability of Erbium-Doped Hydroxyapatite

1.
College of Mining and Coal, Inner Mongolia University of Science and Technology, Baotou, Inner Mongolia 014010, China
2.
Sinosteel Maanshan General Institute of Mining Research Co., Ltd., Ma′anshan, Anhui 243000, China

Corresponding author: Guang-Hui LI, ligh@imust.edu.cn
Received Date: 21 March 2022
Revised Date: 5 September 2022

Figures(11)

Erbium - doped hydroxyapatite (Er - HAP) particles were prepared by the co - precipitation method. The crystal structure, surface chemical composition, and fluorescent properties of Er-HAP particles were characterized by the methods of X- ray diffraction combined with Materials Studio, scanning electron microscopy-energy dispersive spectroscopy, X - ray photoelectron spectroscopy, and fluorescence spectroscopy. The results showed that Er³⁺ can competitively substitute for a Ca2+ site in the crystal lattice. Under the excitation of a 340 nm light source, Er-HAP particles emitted significant fluorescence at around 419 nm (purple), 458 nm (blue), 501 nm (green), and 535 nm (green), respectively. The four corresponding luminescence bands are attributed to ⁴F_3/2 → ⁴I_15/2, ⁴F_5/2 → ⁴I_15/2, ⁴F_7/2 →4I_15/2, and 4S_3/2 → 4I_15/2 transition states, respectively. Further, we evaluated the biomineralization ability by analyzing the formation of an interfacial layer after Er-HAP particles were immersed in simulated body fluid. When the dopant content (molar fraction) of Er³⁺ was 1%, it was observed that Er-HAP particles could form the mineralized layer with plate-like structures, and Er³⁺ incorporation affected the biomineralization ability, whereas the biomineralization rate and osteogenic performance significantly decreased with the increasing of the dopant content of Er³⁺. Therefore, the stronger biomineralization ability of Er-HAP particles might be exhibited while the Er dopant content was about 1%.
- Er³⁺ doped hydroxyapatite,
- biomineralization,
- photoluminescence
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