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Citation: Jia-Hui LIU, Dao-An SUN, Chun-Ying LI, Yong-Mei DU, Zhi-Xuan WANG, Jian LÜ. Effects of Promoters on Polycyclic Hydrocarbon JP-10 Steam Reforming for Hydrogen Production over Ni/γ-Al2O3 Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(12): 2412-2422. doi: 10.11862/CJIC.2022.217 shu

Effects of Promoters on Polycyclic Hydrocarbon JP-10 Steam Reforming for Hydrogen Production over Ni/γ-Al2O3 Catalysts

  • 1.

    State Key Laboratory of Fluorine & Nitrogen Chemical, Xi′an Modern Chemistry Research Institute, Xi′an 710065, China

  • 2.

    College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi′an 710021, China

Figures(10)

  • A series of 15%Ni-5%M/γ-Al2O3 catalysts (denoted as NMA, M=Na, Mg, Ce) modified by Alkali metal Na, alkaline-earth metal Mg, and rare earth metal Ce promoters were prepared by the incipient-wetness co-impregnation method. The texture and surface properties of the above catalysts were characterized and analyzed by XRD (X-ray diffraction), N2 adsorption-desorption, H2-TPR (H2-programmed temperature reduction), TEM (transmission electron microscope), NH3-TPD (NH3-programmed temperature desorption), TG (thermogravimetric), and Raman spectrum techniques. Effects of these promoters on the catalytic performance for steam reforming of JP-10 as a representative of polycyclic hydrocarbons were investigated in a micro-channel reactor (length: 300 mm, inner diameter: 4 mm, 304 stainless steel) wash-coated by catalyst slurry from 600 to 750 ℃ with the feeds of exo-tetrahydrodicyclopentadi-enew (JP-10) (0.5 mL·min-1) and deionized water (1.5 mL·min-1). The above catalyst slurry was prepared by fast ball-milling of catalyst powder, deionized water, 25% silica sol binder for 0.5 h, and the resulted catalyst loading was about 0.25 g. The results showed that all the promoters significantly improved the catalytic activity of Ni/γ -Al2O3 catalysts (denoted as NA) and carbon deposition resistance. Among them, the alkali metal promoter Na exhibited the best modification effect overall. It not only reduced the size of nickel grains and total acid amount, improved the dispersibility of nickel active components, and reduced property, but also inhibited the accumulation of nickel in the high-temperature reforming reaction to the maximum extent. Specifically, conversion of JP-10 and H2 selectivity of NNaA catalyst could reach 82.9% and 73.3%, respectively, and the carbon formation was as low as 0.53 mg·gfeed-1 under the reaction conditions of normal pressure, 750 ℃, steam/carbon (S/C) molar ratio of 2.4, and weight hourly space velocity (WHSV) of 472 h-1. After the reaction, most filamentous carbons were observed on catalysts NNaA, while carbon deposits on the other catalysts were mostly amorphous carbons.
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