Citation: Dong-Bin CHEN, Jing-Ya DING, Guo-Lin ZHANG, Lan FAN, Lin SUN, Feng CHENG, Yong-Long LIU, Yi-Ke CHEN, Qi XU. Manganese Supported Nitrogen-Doped Graphene and Performance of Catalytic Decomposition High-Humidity Ozone[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 2072-2082. doi: 10.11862/CJIC.2022.203 shu

Manganese Supported Nitrogen-Doped Graphene and Performance of Catalytic Decomposition High-Humidity Ozone

Dong-Bin CHEN ¹ ,
Jing-Ya DING ¹ ,
Guo-Lin ZHANG ² ,
Lan FAN ³ ,
Lin SUN ⁴ ,
Feng CHENG ^4,, ,
Yong-Long LIU ¹ ,
Yi-Ke CHEN ¹ ,
Qi XU ^1,,

1.
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
2.
School of Mechanical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
3.
Yancheng Lanfeng Environmental Engineering Technology Co., Ltd., Yancheng 224051, China
4.
Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China

Corresponding author: Feng CHENG, chf@nju.edu.cn Qi XU, ycxqsteve@163.com
Received Date: 27 April 2022
Revised Date: 14 August 2022

Figures(12)

Nitrogen - doped graphene (NG) was synthesized by thermal annealing of graphene oxide (GO) using melamine as the nitrogen source, and NG-loaded manganese (Mn/NG) was prepared using the immersion precipitation method. At 80% relative humidity (RH) and an initial ozone concentration of 85.7 mg·m^-3, the decomposition rate of ozone remained above 80% after 24 h of reaction. Under the low RH environment, the catalytic activity can be restored to the initial state again. The nitrogen doping not only created structural defects for the catalyst, but also the lone pair electrons of nitrogen atoms increased the electron density of oxygen vacancies, reduced the adsorption energy of water molecules, and improved the moisture resistance of the catalyst.
- nitrogen-doped graphene,
- ozone decomposition,
- manganese
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