Citation: Li-Zhou WU, Yi-Wei LI, Yi-Dan CHANG, Na YANG, Xin-Yu GE, Jun-Feng HUI, Bin LIU, Gang-Lin XUE. Syntheses, Structures, and Magnetic Properties of Sandwich-Type Tungstobismuthate Containing Manganese[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 2056-2064. doi: 10.11862/CJIC.2022.189 shu

Syntheses, Structures, and Magnetic Properties of Sandwich-Type Tungstobismuthate Containing Manganese

Li-Zhou WU ^{1, 2,,} ,
Yi-Wei LI ¹ ,
Yi-Dan CHANG ¹ ,
Na YANG ¹ ,
Xin-Yu GE ¹ ,
Jun-Feng HUI ^2,, ,
Bin LIU ^3,, ,
Gang-Lin XUE ³

1.
Department of Chemistry and Chemical Engineering, Research Centre of New Advanced Materials, Ankang Research Centre of Zn-Based Materials Science and Technology, Ankang University, Ankang, Shaanxi 725000, China
2.
School of Chemical Engineering, Northwest University, Xi′an 710069, China
3.
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi′an 710069, China

Corresponding author: Li-Zhou WU, akxywlz@163.com Jun-Feng HUI, huijunfeng@126.com Bin LIU, liubin@nwu.edu.cn
Received Date: 9 February 2022
Revised Date: 6 August 2022

Figures(8)

A new sandwich - type tungstobismuthate containing manganese (Ⅱ), Na₉H[(Mn(H₂O)₃)₂(Mn(H₂O)₂) (WO₂) (BiW₉O₃₃)₂]·30H₂O (1), has been synthesized in the aqueous solutions and structurally characterized by elemental analyses, UV-Vis spectroscopy, IR spectroscopy, powder X -ray diffraction, single-crystal X-ray diffraction and ther- mogravimetric analysis. Single crystal X-ray analysis shows that the polyanion of 1 is composed of two trivacant β-B-[BiW₉O₃₃]^9- Keggin fragments joined together by two [(Mn(H₂O)₂)_0.5(WO₂)_0.5]²⁺ moieties and two [Mn(H₂O)₃]²⁺ subunits located in the inner and outer positions, respectively. Magnetic measurements indicate that 1 exhibits the antiferro-magnetic couplings between Mn(Ⅱ) centers.
- polyoxometalates,
- sandwich-type,
- crystal structure,
- magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142