Citation: Bai-Tong NIU, Wang-Nan XIA, Zhao-Qin LAI, Hong-Xu GUO, Zhang-Xu CHEN. Solvent-Controlled Morphology of Ni-BTC and Ni-BDC Metal-Organic Frameworks for Supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1643-1654. doi: 10.11862/CJIC.2022.160 shu

Solvent-Controlled Morphology of Ni-BTC and Ni-BDC Metal-Organic Frameworks for Supercapacitors

1.
College of Chemistry, Chemical Engineering, and Environment, Minnan Normal University, Zhangzhou, Fujian 363000, China
2.
Fujian Provincial University Key Laboratory of Ecological Environment and Information Atlas, Putian University, Putian, Fujian 351100, China

Corresponding author: Hong-Xu GUO, guohx@mnnu.edu.cn
Received Date: 7 March 2022
Revised Date: 23 April 2022

Figures(13)

The performance of energy storage materials is substantially dependent on their nanostructures. Herein, Ni-1, 3, 5-benzenetricarboxylate (Ni-BTC) and Ni-1, 4-benzoate (Ni-BDC) metal-organic frameworks with different morphologies were controllably synthesized using a facile solvothermal method by simply adjusting the solvent, including Ni-BTC blocks, nanospheres, and double-pyramid structures and Ni-BDC nanosheets, nanoflowers and blocks structures, and their electrochemical performance as supercapacitors was thoroughly investigated. Moreover, our study showed that the supercapacitor performance of the electrode materials obtained for Ni-BTC and Ni-BDC electrodes in pure N, N-dimethylformamide (DMF) solvent was better than those prepared with pure ethanol (EtOH) and DMF/EtOH (50:50, V/V) as solvent.
- supercapacitor,
- morphology tuning,
- solvothermal method,
- metal-organic frameworks
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