Citation: Man‐Rong LIU, Ji‐Jiang WANG, Er‐Lin YUE, Long TANG, Xiao WANG, Xiang‐Yang HOU, Yu‐Qi ZHANG. Synthesis, Structure, Magnetic, and Fluorescent Sensing Properties of Cobalt(Ⅱ) Coordination Polymer Based on 1⁃(3, 5⁃Dicarboxybenzyl)⁃1H⁃pyrazole⁃3, 5⁃dicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1601-1608. doi: 10.11862/CJIC.2022.152 shu

Synthesis, Structure, Magnetic, and Fluorescent Sensing Properties of Cobalt(Ⅱ) Coordination Polymer Based on 1⁃(3, 5⁃Dicarboxybenzyl)⁃1H⁃pyrazole⁃3, 5⁃dicarboxylic Acid

Yan′an Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan′an University, Yan′an, Shaanxi 716000, China

Corresponding author: Ji‐Jiang WANG, yadxwjj@126.com Er‐Lin YUE, yueerlin@yau.edu.cn
Received Date: 15 January 2022
Revised Date: 18 April 2022

Figures(10)

A new coordination polymer (CP), [Co₅(L)₂(μ₃‐OH)₂(H₂O)₈]_n (1) (H₄L=1‐(3, 5‐dicarboxybenzyl)‐1H‐pyrazole‐3, 5‐dicarboxylic acid), was synthesized by hydrothermal method and characterized by single‐crystal X‐ray diffraction, elemental analyses, infrared spectroscopic analysis, and thermogravimetric analysis. The crystallographic analysis indicates that complex 1 crystallizes in the triclinic system with a space group of P1 and exhibits a 3D network structure. Each of the three Co(Ⅱ) ions in the molecule adopts a six‐coordinated pattern, forming a slightly twisted octahedral coordination configuration. The variable temperature magnetic susceptibility measurements indicate that there are antiferromagnetic interactions between the Co(Ⅱ) ions in complex 1. The fluorescence sensing experiments demonstrate that complex 1 exhibits fluorescent quenching to Hg²⁺ with high sensitivity and selectivity. Additionally, the Co(Ⅱ)‐CP sensor could be successfully used to assay the content of Hg²⁺ in Yanhe River water samples.
- coordination polymer,
- Co(Ⅱ),
- 1‐(3, 5‐dicarboxybenzyl)‐1H‐pyrazole‐3, 5‐dicarboxylic acid,
- magnetic property,
- fluorescent sensing,
- Hg²⁺
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