Citation: Da-Ze NING, Hong-Guang SUN. Performance of the Inward Radial Hollow TiN Particles as Cathodes for Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(7): 1375-1381. doi: 10.11862/CJIC.2022.143 shu

Performance of the Inward Radial Hollow TiN Particles as Cathodes for Lithium-Sulfur Batteries

Da-Ze NING ,
Hong-Guang SUN ^,

School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266044, China

Corresponding author: Hong-Guang SUN, hgsun816@qust.edu.cn
Received Date: 18 March 2022
Revised Date: 17 May 2022

Figures(5)

The inward radially hollow structure TiN particles (IRHTiNs) was designed and synthesized by using the hard-template method and combined with sulfur (S) to prepare lithium-sulfur batteries (LSB) cathodes. Subsequently, the structure and composition of IRHTiNs and IRHTiNs/S composite cathodes were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). In the electrochemical test process, compared with the C cathodes, LSB using the IRHTiNs cathodes exhibited a high original specific capacity of 1 256 mAh·g^-1, the capacity fading rate was significantly reduced, and the LSB performance was significantly improved.
- lithium-sulfur battery,
- titanium nitride,
- nanoparticles,
- shuttle effect
1. [1]
  Shi H D, Ren X M, Lu J M, Dong C, Liu J, Yang Q H, Chen J, Wu Z S. Dual-Functional Atomic Zinc Decorated Hollow Carbon Nanoreactors for Kinetically Accelerated Polysulfides Conversion and Dendrite Free Lithium Sulfur Batteries[J]. Energy Storage Mater., 2020,10(39)2002271.
2. [2]
  Wang W P, Zhang J, Chou J, Yin Y X, You Y, Xin S, Guo Y G. Solidifying Cathode-Electrolyte Interface for Lithium-Sulfur Batteries[J]. Energy Storage Mater., 2021,11(2)2000791.
3. [3]
  Ding B, Wang J, Fan Z J, Chen S, Lin Q Y, Lu X J, Dou H, Nanjundan A K, Yushin G, Zhang X G, Yamauchi Y. Solid-State Lithium-Sulfur Batteries: Advances, Challenges and Perspectives[J]. Mater. Today, 2020,40:114-131. doi: 10.1016/j.mattod.2020.05.020
4. [4]
  Lim J, Pyun J, Char K. Recent Approaches for the Direct Use of Elemental Sulfur in the Synthesis and Processing of Advanced Materials[J]. Angew. Chem. Int. Ed., 2015,54(11):3249-3258. doi: 10.1002/anie.201409468
5. [5]
  Son Y, Lee J S, Son Y, Jang J H, Cho J. Recent Advances in Lithium Sulfide Cathode Materials and Their Use in Lithium Sulfur Batteries[J]. Adv. Energy Mater., 2015,5(16)1500110. doi: 10.1002/aenm.201500110
6. [6]
  Zhou L, Danilov D L, Eichel R A, Notten P H L. Host Materials Anchoring Polysulfides in Li-S Batteries Reviewed[J]. Adv. Energy Mater., 2020,11(15)2001304.
7. [7]
  Zheng M B, Chi Y, Hu Q, Tang H, Jiang X L, Zhang L, Zhang S T, Pang H, Xu Q. Carbon Nanotube-Based Materials for Lithium-Sulfur Batteries[J]. J. Mater. Chem. A, 2019,7(29):17204-17241. doi: 10.1039/C9TA05347F
8. [8]
  Zeng W D, Cheng M M C, Ng K Y S. Cathode Framework of Nanostructured Titanium Nitride/Graphene for Advanced Lithium-Sulfur Batteries[J]. ChemElectroChem, 2019,6(10):2796-2804. doi: 10.1002/celc.201900364
9. [9]
  Li H T, Li Y G, Zhang L. Designing Principles of Advanced Sulfur Cathodes toward Practical Lithium-Sulfur Batteries[J]. SusMat, 2022,2(1):34-64. doi: 10.1002/sus2.42
10. [10]
  Cui Z Q, Yao J, Mei T, Zhou S Y, Hou B F, Li J, Li J H, Wang J Y, Qian J W, Wang X B. Strong Lithium Polysulfides Chemical Trapping of TiC-TiO₂/S Composite for Long-Cycle Lithium-Sulfur Batteries[J]. Electrochim. Acta, 2019,298(1):43-51.
11. [11]
  Yang J H, Yang X F, Cheong J L, Zaghib K, Trudeau M L, Ying J Y. Nanoboxes with a Porous MnO Core and Amorphous TiO₂ Shell as a Mediator for Lithium-Sulfur Batteries[J]. J. Mater. Chem. A, 2021,9(8):4952-4961. doi: 10.1039/D0TA09700D
12. [12]
  Gao B, Li X X, Ding K, Huang C, Li Q W, Chu P K, Huo K. Recent Progress in Nanostructured Transition Metal Nitrides for Advanced Electrochemical Energy Storage[J]. J. Mater. Chem. A, 2019,7(1):14-37. doi: 10.1039/C8TA05760E
13. [13]
  Lim W G, Jo C S, Cho A, Hwang J, Kim S, Han J W, Lee J. Approaching Ultrastable High-Rate Li-S Batteries through Hierarchically Porous Titanium Nitride Synthesized by Multiscale Phase Separation[J]. Adv. Mater., 2019,31(3)1806547. doi: 10.1002/adma.201806547
14. [14]
  Wang Y K, Zhang R F, Pang Y C, Chen X, Lang J X, Xu J J, Xiao C H, Li H L, Xi K, Ding S J. Carbon@Titanium Nitride Dual Shell Nanospheres as Multi-functional Hosts for Lithium Sulfur Batteries[J]. Energy Storage Mater., 2019,16:228-235. doi: 10.1016/j.ensm.2018.05.019
15. [15]
  Li H X, Ma S, Li J W, Liu F Y, Zhou H H, Huang Z Y, Jiao S Q, Kuang Y. Altering the Reaction Mechanism to Eliminate the Shuttle Effect in Lithium-Sulfur Batteries[J]. Energy Storage Mater., 2020,26:203-212. doi: 10.1016/j.ensm.2020.01.002
16. [16]
  Polshettiwar V, Cha D, Zhang X, Basset J M. High-Surface-Area Silica Nanospheres (KCC-1) with a Fibrous Morphology[J]. Angew. Chem. Int. Ed., 2010,122(50):9846-9850. doi: 10.1002/ange.201003451
17. [17]
  Liang X, Garsuch A, Nazar L F. Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries[J]. Angew. Chem. Int. Ed., 2015,127(13):3979-3983. doi: 10.1002/ange.201410174
18. [18]
  Zhou S Y, Hu J Y, Liu S G, Lin J X, Cheng J, Mei T, Wang X B, Liao H G, Huang L, Sun S G. Biomimetic Micro Cell Cathode for High Performance Lithium-Sulfur Batteries[J]. Nano Energy, 2020,72104680. doi: 10.1016/j.nanoen.2020.104680
19. [19]
  Wu Q P, Yao Z G, Zhou X J, Xu J, Cao F H, Li C L. Built-In Catalysis in Confined Nanoreactors for High-Loading Li-S Batteries[J]. ACS Nano, 2020,14(3):3365-3377. doi: 10.1021/acsnano.9b09231
20. [20]
  Jin Z S, Lin T N, Jia H F, Liu B Q, Zhang Q, Li L, Zhang L Y, Su Z M, Wang C G. Expediting the Conversion of Li₂S₂ to Li₂S Enables High-Performance Li-S Batteries[J]. ACS Nano, 2021,15(4):7318-7327. doi: 10.1021/acsnano.1c00556
21. [21]
  Cai D, Liu B K, Zhu D H, Chen D, Lu M J, Cao J M, Wang Y H, Huang W H, Shao Y, Tu H, Han W. Ultrafine Co₃Se₄ Nanoparticles in Nitrogen-Doped 3D Carbon Matrix for High-Stable and Long-Cycle-Life Lithium Sulfur Batteries[J]. Adv. Energy Mater., 2020,10(19)1904273. doi: 10.1002/aenm.201904273
22. [22]
  Yang X F, Gao X J, Sun Q, Jand S P, Yu Y, Zhao Y, Li X, Adair K, Kuo L Y, Rohrer J, Liang J N, Lin X T, Banis M N, Hu Y F, Zhang H Z, Li X F, Li R Y, Zhang H M, Kaghazchi P, Sham T K, Sun X L. Promoting the Transformation of Li₂S₂ to Li₂S: Significantly Increasing Utilization of Active Materials for High-Sulfur-Loading Li-S Batteries[J]. Adv. Mater., 2019,31(25)1901220. doi: 10.1002/adma.201901220
1. [1]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
2. [2]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-0. doi: 10.1016/j.actphy.2025.100082
3. [3]
  Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247
4. [4]
  Tao Wang , Qin Dong , Cunpu Li , Zidong Wei . Sulfur Cathode Electrocatalysis in Lithium-Sulfur Batteries: A Comprehensive Understanding. Acta Physico-Chimica Sinica, 2024, 40(2): 2303061-0. doi: 10.3866/PKU.WHXB202303061
5. [5]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
6. [6]
  Yan'e LIU , Shengli JIA , Yifan JIANG , Qinghua ZHAO , Yi LI , Xinshu CHANG . MoO₃/cellulose derived carbon aerogel: Fabrication and performance as cathode for lithium-sulfur battery. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1565-1573. doi: 10.11862/CJIC.20250054
7. [7]
  Xiaoli CHEN , Zhihong LUO , Yuzhu XIONG , Aihua WANG , Xue CHEN , Jiaojing SHAO . Inhibitory effect of the interlayer of two-dimensional vermiculite on the polysulfide shuttle in lithium-sulfur batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1661-1671. doi: 10.11862/CJIC.20250075
8. [8]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
9. [9]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H₂O₂ synthesis via melamine-foam supported S-scheme Cd_0.5Zn_0.5In₂S₄/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093
10. [10]
  Zeyu Liu , Wenze Huang , Yang Xiao , Jundong Zhang , Weijin Kong , Peng Wu , Chenzi Zhao , Aibing Chen , Qiang Zhang . Nanocomposite Current Collectors for Anode-Free All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2305040-0. doi: 10.3866/PKU.WHXB202305040
11. [11]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
12. [12]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂ Nanosheets Improved the Buried Interface for Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-0. doi: 10.3866/PKU.WHXB202407025
13. [13]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
14. [14]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
15. [15]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . Surface Sulfur Species Influence Hydrogenation Performance of Palladium-Sulfur Nanosheets. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-0. doi: 10.3866/PKU.WHXB202309043
16. [16]
  Jian Li , Yu Zhang , Rongrong Yan , Kaiyuan Sun , Xiaoqing Liu , Zishang Liang , Yinan Jiao , Hui Bu , Xin Chen , Jinjin Zhao , Jianlin Shi . Highly Efficient, Targeted, and Traceable Perovskite Nanocrystals for Photoelectrocatalytic Oncotherapy. Acta Physico-Chimica Sinica, 2025, 41(5): 100042-0. doi: 10.1016/j.actphy.2024.100042
17. [17]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
18. [18]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
19. [19]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
20. [20]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . Optimizing interfacial electric fields in carbon nitride nanosheet/spherical conjugated polymer S-scheme heterojunction for hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-0. doi: 10.1016/j.actphy.2025.100095

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1563)
HTML views(218)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142