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Citation: Ming-Ming HAN, Ji-Wu HUANG, Xian-Wen WU, Shu-Quan LIANG, Jiang ZHOU. Electrolyte Modulation Strategies for Rechargeable Zn Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1451-1469. doi: 10.11862/CJIC.2022.130 shu

Electrolyte Modulation Strategies for Rechargeable Zn Batteries

  • 1.

    School of Materials Science and Engineering, Central South University, Changsha 410083, China

  • 2.

    School of Chemistry and Chemical Engineering, Jishou University, Jishou, Hunan 416000, China

  • Corresponding author: Jiang ZHOU, zhou_jiang@csu.edu.cn
  • Received Date: 5 January 2022
    Revised Date: 5 April 2022

Figures(10)

  • Large‐scale electrical energy storage (EES) technology with high safety, low cost, and high stability determines the future energy structure adjustment and smart grid construction. Rechargeable Zn batteries (RZBs) would be an ideal candidate for EES devices because of their intrinsic environment‐friendly and cost‐effective properties. Although substantial progress has been achieved in RZBs in the past several years, the state‐of‐art RZBs are plagued by severe side‐reactions like cathode materials dissolution, dendrites growth, Zn corrosion, and hydrogen evolution, which are associated with the active free water and hydrated Zn(OH)62+ ion in common aqueous solution. In this review, the electrolyte strategies including concentration, additives, and solvation structure modulation for improving Zn cycling performance are discussed in detail. This paper combines reviews and perspectives on electrolyte strategies, which would shed light on the development of high‐performance RZBs.
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