Synthesis and Luminescence Properties of Li4SrCa(SiO4)2∶Eu3+ Red Phosphor
- Corresponding author: Zhi- Xiang GAO, zxgao@sxdtdx.edu.cn Cui-Feng TIAN, cftian_050@sxdtdx.edu.cn
Citation: Xia-Xia FAN, Zhi- Xiang GAO, Wen-Shan QU, Cui-Feng TIAN, Jian-Gang LI, Wei LI, Li-Juan DONG, Yun-Long SHI. Synthesis and Luminescence Properties of Li4SrCa(SiO4)2∶Eu3+ Red Phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(6): 1016-1022. doi: 10.11862/CJIC.2022.123
Lin C C, Liu R S. Advances in Phosphors for Light-Emitting Diodes[J]. J. Phys. Chem. Lett., 2011,2(11):1268-1277. doi: 10.1021/jz2002452
Mckittrick J, Shea-Rohwer L E. Review: Down Conversion Materials for Solid-State Lighting[J]. J. Am. Ceram. Soc., 2014,97(5):1327-1352. doi: 10.1111/jace.12943
Ye S, Xiao F, Pan Y X, Ma Y Y, Zhang Q Y. Phosphors in Phosphor-Converted White Light-Emitting Diodes: Recent Advances in Materials, Techniques and Properties[J]. Mater. Sci. Eng. R, 2010,71(1):1-34. doi: 10.1016/j.mser.2010.07.001
Bachmann V, Ronda C, Meijerink A. Temperature Quenching of Yellow Ce3+ Luminescence in YAG: Ce[J]. Chem. Mater., 2009,21(10):2077-2084. doi: 10.1021/cm8030768
Song X F, He H, Fu R L, Wang D L, Zhao X R, Pan Z W. Photoluminescent Properties of SrSi2O2N2: Eu2+ Phosphor: Concentration Related Quenching and Red Shift Behaviour[J]. J. Phys. D: Appl. Phys., 2009,42(6)065409. doi: 10.1088/0022-3727/42/6/065409
Kim K B, Kim Y I, Chun H G, Cho T Y, Jung J S, Kang J G. Structural and Optical Properties of BaMgAl10O17: Eu2+ Phosphor[J]. Chem. Mater., 2002,14(12):5045-5052. doi: 10.1021/cm020592f
Brgoch J, DenBaars S P, Seshadri R. Proxies from Ab Initio Calculations for Screening Efficient Ce3+ Phosphor Hosts[J]. J. Phys. Chem. C, 2013,117(35):17955-17959. doi: 10.1021/jp405858e
George N C, Birkel A, Brgoch J, Hong B C, Mikhailovsky A A, Page K, Llobet A, Seshadri R. Average and Local Structural Origins of the Optical Properties of the Nitride Phosphor La3-xCexSi6N11 (0 < x ≤ 3)[J]. Inorg. Chem., 2013,52(23):13730-13741. doi: 10.1021/ic402318k
Schmiechen S, Schneider H, Wagatha P, Hecht C, Schmidt P J, Schnick W. Toward New Phosphors for Application in Illumination-Grade White pc-LEDs: The Nitridomagnesosilicates Ca[Mg3SiN4]: Ce3+, Sr[Mg3SiN4]: Eu2+, and Eu[Mg3SiN4][J]. Chem. Mater., 2014,26(8):2712-2719. doi: 10.1021/cm500610v
Akella A, Keszler D A. The New Orthosilicate Li4SrCa(SiO4)2: Structure and Eu2+ Luminescence[J]. Inorg. Chem., 1995,34(6):1308-1310. doi: 10.1021/ic00110a005
Zhang J L, Zhang W L, Qiu Z X, Zhou W L, Yu L P, Li Z Q, Lian S X. Li4SrCa(SiO4)2: Ce3+, a Highly Efficient Near-UV and Blue Emitting ortho-Silicate Phosphor[J]. J. Alloys Compd., 2015,646:315-320. doi: 10.1016/j.jallcom.2015.05.280
Pekgozlu I, Erdogmus E, Yilmaz M. Synthesis and Photoluminescence Properties of Li4SrCa(SiO4)2: M (M: Pb2+ and Bi3+)[J]. J. Lumin., 2015,161:160-163. doi: 10.1016/j.jlumin.2015.01.009
Zhang J L, Zhang W L, He Y N, Zhou W L, Yu L P, Lian S X, Li Z Q, Gong M L. Site-Occupancy on the Luminescence Properties of a Single-Phase Li4SrCa(SiO4)2: Eu2+ Phosphor[J]. Ceram. Int., 2014,40(7):9831-9834. doi: 10.1016/j.ceramint.2014.02.073
Zhang X M, Li W L, Seo H J. Luminescence and Energy Transfer in Eu2+, Mn2+ Co-doped Li4SrCa(SiO4)2 for White Light-Emitting-Diodes[J]. Phys. Lett. A, 2009,373(38):3486-3489. doi: 10.1016/j.physleta.2009.07.052
Jin Y, Wang Y, Wang Y P. Tuning Luminescence and Excellent Thermal Stability of Gd4.67Si3O13: Bi3+ to Eu3+ with Energy Transfer from Bi3+ to Eu3+[J]. Ceram. Int., 2020,46(14):22927-22933. doi: 10.1016/j.ceramint.2020.06.066
Li W, Wang J, Zhang H R, Liu Y L, Lei B F, Zhuang J L, Cui J H, Peng M Y, Zhu Y. Tunable Emission Color and Mixed Valence State via the Modified Activator Site in the AlN-Doped Sr3SiO5: Eu Phosphor[J]. RSC Adv., 2016,6(39):33076-33082. doi: 10.1039/C6RA04387A
Singh S. Enhancement and Luminescence Properties of Eu3+, Sm3+ Co-doped KMgPO4 Phosphor with Variable Concentration of Eu3+ for w-LEDs[J]. Bull. Mater. Sci., 2021,44(1)22. doi: 10.1007/s12034-020-02314-0
Kang J S, Jeong Y K, Kang J G, Zhao L Y, Sohn Y, Pradhan D, Leung K T. Observation of Mediated Cascade Energy Transfer in Europium-Doped ZnO Nanowalls by 1, 10-Phenanthroline[J]. J. Phys. Chem. C, 2015,119(4):2142-2147. doi: 10.1021/jp5090795
Bezrkovnyi O S, Vorokhta M, Malecka M, Mista W, Kepinski L. NAP-XPS Study of Eu3+→Eu2+ and Ce4→Ce3+ Reduction in Au/Ce0.80Eu0.20O2 Catalyst[J]. Catal. Commun., 2020,135105875. doi: 10.1016/j.catcom.2019.105875
Blasse G. On the Eu3+ Fluorescence of Mixed Metal Oxides. Ⅳ. The Photoluminescent Efficiency of Eu3+-Activated Oxides[J]. J. Chem. Phys., 1966,45(7):2356-2360. doi: 10.1063/1.1727946
Dexter D L, Schulman J H. Theory of Concentration Quenching in Inorganic Phosphors[J]. J. Chem. Phys., 1954,22(6):1063-1070. doi: 10.1063/1.1740265
Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO3 for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C3N4/Ti3C2Tx Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C3N4 nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO2 reduction performance of Z-scheme Ag-Cu2O/BiVO4 photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO3)3 double-coating modification on the electrochemical properties of Li[Ni0.8Co0.15Al0.05]O2. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi0.90Co0.06Mn0.04O2 electrode by uniform Li3PO4 coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I2 interface modification engineering on the performance of all-inorganic CsPbBr3 perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO2 anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
Reference is standard card data of Li4SrCa(SiO4)2 (PDF No.83-0763)
Inset: lg(I/x) vs lg x plot for Eu3+ ion