Anionic Modification of the Cu-Tb Single-Molecule Magnets Based on the Compartmental Schiff-Base Ligand
- Corresponding author: Xin-Yi WANG, wangxy66@nju.edu.cn
Citation: Wen-Jie JI, Cheng-Cai XIA, Xin-Yu ZHANG, Xin-Yi WANG. Anionic Modification of the Cu-Tb Single-Molecule Magnets Based on the Compartmental Schiff-Base Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(6): 1199-1208. doi: 10.11862/CJIC.2022.117
(a) Andoni Z L, Jose M S, Enrique C. Single-Molecule Magnets: From Mn12-ac to Dysprosium Metallocenes, a Travel in Time. Coord. Chem. Rev., 2021, 441: 3984-4020
(b)Shao D, Wang X Y. Development of Single-Molecule Magnets. Chin. J. Chem., 2020, 38: 1005-1018
Zhu Z, Guo M, Li X L, Tang J. Molecular Magnetism of Lanthanide: Advances and Perspectives[J]. Coord. Chem. Rev., 2019,378:350-364. doi: 10.1016/j.ccr.2017.10.030
Ding X L, Zhai Y Q, Han T, Chen W P, Ding Y S, Zheng Y Z. A Local D4h Symetric Dysprosiun(Ⅲ) Single-Molecule Magnet with an Energy Barrier Exceeding 2 000 K[J]. Chem. Eur. J., 2021,27:2623-2627. doi: 10.1002/chem.202003931
Guo F S, Day B M, Chen Y C, Tong M L, Mansikkamäki A, Layfield R A. Magnetic Hysteresis up to 80 Kelvin in a Dysprosium Metallocene Single Molecule Magnet[J]. Science, 2018,362:1400-1403. doi: 10.1126/science.aav0652
Goodwin C A P, Ortu F, Reta D, Chilton N F, Mills D P. Molecular Magnetic Hysteresis at 60 Kelvin in Dysprosocenium[J]. Nature, 2017,548:439-442. doi: 10.1038/nature23447
Alejandro C A, Yolimar G, Leonel L, Daniel A. High Performance Single-Molecule Magnets, Orbach or Raman Relaxation Suppression?[J]. InorgChem. Front., 2020,7:2478-2486.
Chen Y C, Liu J L, Ungur L, Li Q W, Wang L F, Ni Z P, Chibotaru L F, Chen X P, Tong M L. Symmetry-Supported Magnetic Blocking at 20 K in Pentagonal Bipyramidal Dy(Ⅲ) Single-Ion Magnets[J]. J. Am. Chem. Soc., 2016,138(8):2829-2837. doi: 10.1021/jacs.5b13584
Ungur L, Chibotaru L F. Magnetic Anisotropy in the Excited States of Low Symmetry Lanthanide Complexes[J]. Phys. Chem. Chem. Phys., 2011,13:20086-20090. doi: 10.1039/c1cp22689d
Gould C A, Mcclain K R, Reta D, Kragskow J G C, Marchiori D A, Lachman E, Choi E S, Analytis J G, Britt R D, Chilton N F, Harvey B G, Long J R. Ultrahard Magnetism from Mixed-Valence Dilanthanide Complexes with Metal-Metal Bonding[J]. Science, 2022,375:198-202. doi: 10.1126/science.abl5470
Jiang S D, Wang B W, Su G, Wang Z M, Gao S. A Mononuclear Dys- prosium Complex Featuring Single-Molecule Magnet Behavior[J]. Angew. Chem. Int. Ed., 2010,49:7448-7451. doi: 10.1002/anie.201004027
Demir S, Gonzalez M I, Darago L E, Evans W J, Long J R. Giant Coercivity and High Magnetic Blocking Temperatures for N23-Radical-Bridged Dilanthanide Complexes upon Ligand Dissociation[J]. Nat. Commun., 2017,82144. doi: 10.1038/s41467-017-01553-w
Dolinar B S, Alexandropoulos D I, Vignesh K R, James T A, Dunbar K R. Lanthanide Triangles Supported by Radical Bridging Ligands[J]. J. Am. Chem. Soc., 2018,140(3):908-911. doi: 10.1021/jacs.7b12495
Peng Y, Powell A K. What do 3d-4f Butterflies Tell Us?[J]. CoordChem. Rev., 2021,426214390.
Yang J W, Tian Y M, Tao J, Chen P, Li H F, Zhang Y Q, Yan P F, Sun W B. Modulation of the Coordination Environment around the Magnetic Easy Axis Leads to Significant Magnetic Relaxations in a Series of 3d-4f Schiff Complexes[J]. Inorg. Chem., 2018,57:8065-8077. doi: 10.1021/acs.inorgchem.8b00056
Wen H R, Hu J H, Yang K, Zhang J L, Liu S J, Liao J S, Liu C M. Family of Chiral ZnⅡ-LnⅢ (Ln=Dy and Tb) Heterometallic Complexes Derived from the Amine-Phenol Ligand Showing Multifunctional Properties[J]. Inorg. Chem., 2020,59:2811-2824. doi: 10.1021/acs.inorgchem.9b03164
Souvik M, Apran M, Sanjit K, Ashutosh G. The Role of 3d-4f Exchange Interaction in SMM Behavior and Magnetic Refrigeration of Carbonato Bridged Cu2Ⅱ Ln2Ⅲ (Ln=Dy, Tb, Gd) Complexes of an Unsymmetrical N2O4 Donor Ligand[J]. Dalton Trans., 2019,48:15170-15183. doi: 10.1039/C9DT02627D
Vignesh K R, Langly S K, Murray K S, Rajarman G. Quenching the Quantum Tunneling of Magnetization in Heterometallic Octanuclear TM4ⅡDy4Ⅲ (TM=Co and Cr) Single-Molecular Magnets by Modification of the Bridging Ligands and Enhancing the Magnetic Exchange Coupling[J]. Chem. Eur. J., 2017,23:1654-1666. doi: 10.1002/chem.201604835
Osa S, Kido T, Matsumoto N, Re N, Pochaba A, Mrozinski J. A Tetranuclear 3d-4f Single Molecule Magnet: [CuⅡLTbⅢ (hfac)2]2[J]. J. Am. Chem. Soc., 2004,126:420-421. doi: 10.1021/ja037365e
Liu C M, Zhang D Q, Hao X, Zhu D B. Assembly of Chiral 3d-4f Wheel-like Cluster Complexes with Achiral Ligands: Single-Molecule Magnetic Behavior and Magnetocaloric Effect[J]. Inorg. Chem. Front., 2020,7:3340-3351. doi: 10.1039/D0QI00632G
Wang Z X, Zhang X, Zhang Y Z, Li M X, Zhao H H, Andruh M, Dunbar K R. Single-Chain Magnetic Behavior in a Hetero-tri-spin Complex Mediated by Supramolecular Interactions with TCNQF·-Radicals[J]. Angew. Chem. Int. Ed., 2014,53:11567-11270. doi: 10.1002/anie.201407628
Vieru V, Pasatoiu T D, Ungur L, Suturina E, Madalan A M, Duhayon C, Sutter J P, Andruh M, ChibotaruL F. Synthesis, Crystal Struc-tures, Magnetic Properties, and Theoretical Investigation of a New Series of NiⅡ-LnⅢ-WⅤ Heterotrimetallics: Understanding the SMM Behavior of Mixed Polynuclear Complexes[J]. Inorg. Chem., 2016,55:12158-12171. doi: 10.1021/acs.inorgchem.6b01669
Huang X C, Zhou C, Wei H Y, Wang X Y. End-On Azido-Bridged 3d-4f Complexes Showing Single-Molecule Magnet Property[J]. Inorg. Chem., 2013,52:7314-7316. doi: 10.1021/ic400986y
Huang X C, Vieru V, Chibotaru L F, Wernsdorfer W, Jiang S D, Wang X Y. Determination of Magnetic Anisotropy in a Multinuclear TbⅢ-Based Single-Molecule Magnet[J]. Chem. Commun., 2015,51:10373-10376. doi: 10.1039/C5CC03089G
Bain G A, Berry J F. Diamagnetic Corrections and Pascal′s Con-stants[J]. J. Chem. Educ., 2008,85:532-536. doi: 10.1021/ed085p532
SAINT, Version 7.68A, Bruler AXS, Inc., Madison, WI, 2008.
Sheldrick G M. SHELXTL, Version 6.14, Bruker AXS, Inc., Madison, WI, 2000-2003.
Sheldrick G M. Recent Upgrade to the SHELXL Refinement Program is also Available[J]. Acta Crystallogr. Sect. C, 2015.
Lo W K, Wong W K, Wong W Y, Guo J P, Yeung K T, Cheng Y K, Yang X P, Jones R A. Heterobimetallic Zn(Ⅱ)-Ln(Ⅲ) Phenylene- Bridged Schiff Base Complexes, Computational Studies, and Evidence for Singlet Energy Transfer as the Main Pathway in the Sensitization of Near-Infrared Nd3+ Luminescence[J]. Inorg. Chem., 2006,45:9315-9325. doi: 10.1021/ic0610177
Chuan H L, Jian H J, Ping Y, Li M T, Xu L, Sheng X X, Xiu P, Xu T, Jin Q X, Yi Z, Ming A X, Qiang G L. Preparation, Structure, and Thermochemical Properties of a Copper((Ⅱ)) Schiff-Base Complex[J]. J. Therm. Anal. Calorim., 2015,119:1285-1292. doi: 10.1007/s10973-014-4232-2
Melby L R, Harder R J, Hertler W R, Mahler W, Benson R E, Mochel W E. Substituted Quinodimethans. Ⅱ. Anion-Radical Derivatives and Complexes of 7, 7, 8, 8-Tetracyanoquinodimethan[J]. J. Am. Chem. Soc., 1962,84:3374-3387.
Llunell M, Casanova D, Cirera J, Alemany P, Alvarez S. SHAPE, Version 2.1, University of Barcelona, Spain, 2013.
Ballesteros - Rivas M, Ota A, Reinheimer E, Prosvirin A, Valldes-Martinez J, Dunbar K R. Highly Conducting Coordination Polymers Based on Infinite M(4, 4'-bpy) Chains Flanked by Regular Stacks of Non-integer TCNQ Radicals[J]. Angew. Chem. Int. Ed., 2011,50:9703-9707. doi: 10.1002/anie.201101658
Kahn O. Molecular Magnetism. New York: VCH, 1993.
Costes J P, Dahan F, Dupuis A, Laurent J P. Nature of the Magnetic Interaction in the (Cu2+, Ln3+) Pairs: An Empirical Approach Based on the Comparison between Homologous (Cu2+, Ln3+) and (NiLS2+, Ln3+) Complexes[J]. Chem. Eur. J., 1998,4:1616-1620. doi: 10.1002/(SICI)1521-3765(19980904)4:9<1616::AID-CHEM1616>3.0.CO;2-A
Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO3. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
Shuyan ZHAO . Field-induced CoⅡ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
Chaochao Jin , Kai Li , Jiongpei Zhang , Zhihua Wang , Jiajing Tan . N,O-Bidentated difluoroboron complexes based on pyridine-ester enolates: Facile synthesis, post-complexation modification, optical properties, and applications. Chinese Chemical Letters, 2024, 35(9): 109532-. doi: 10.1016/j.cclet.2024.109532
Kun Zhang , Ni Dan , Dan-Dan Ren , Ruo-Yu Zhang , Xiaoyan Lu , Ya-Pan Wu , Li-Lei Zhang , Hong-Ru Fu , Dong-Sheng Li . A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(3): 100244-100244. doi: 10.1016/j.cjsc.2024.100244
Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd6(L)4]8+-type macrocyclic complexes for fluorescent sensing of HSO3-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
Wenbi Wu , Yinchu Dong , Haofan Liu , Xuebing Jiang , Li Li , Yi Zhang , Maling Gou . Modification of plasma protein for bioprinting via photopolymerization. Chinese Chemical Letters, 2024, 35(8): 109260-. doi: 10.1016/j.cclet.2023.109260
Lijun Mao , Shuo Li , Xin Zhang , Zhan-Ting Li , Da Ma . Cucurbit[n]uril-based nanostructure construction and modification. Chinese Chemical Letters, 2024, 35(8): 109363-. doi: 10.1016/j.cclet.2023.109363
Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
Chenghao Ge , Peng Wang , Pei Yuan , Tai Wu , Rongjun Zhao , Rong Huang , Lin Xie , Yong Hua . Tuning hot carrier transfer dynamics by perovskite surface modification. Chinese Chemical Letters, 2024, 35(10): 109352-. doi: 10.1016/j.cclet.2023.109352
Zhen Liu , Zhi-Yuan Ren , Chen Yang , Xiangyi Shao , Li Chen , Xin Li . Asymmetric alkenylation reaction of benzoxazinones with diarylethylenes catalyzed by B(C6F5)3/chiral phosphoric acid. Chinese Chemical Letters, 2024, 35(5): 108939-. doi: 10.1016/j.cclet.2023.108939
Xingyan Liu , Chaogang Jia , Guangmei Jiang , Chenghua Zhang , Mingzuo Chen , Xiaofei Zhao , Xiaocheng Zhang , Min Fu , Siqi Li , Jie Wu , Yiming Jia , Youzhou He . Single-atom Pd anchored in the porphyrin-center of ultrathin 2D-MOFs as the active center to enhance photocatalytic hydrogen-evolution and NO-removal. Chinese Chemical Letters, 2024, 35(9): 109455-. doi: 10.1016/j.cclet.2023.109455
Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
Huan Yao , Jian Qin , Yan-Fang Wang , Song-Meng Wang , Liu-Huan Yi , Shi-Yao Li , Fangfang Du , Liu-Pan Yang , Li-Li Wang . Ultra-highly selective recognition of nucleosides over nucleotides by rational modification of tetralactam macrocycle and its application in enzyme assay. Chinese Chemical Letters, 2024, 35(6): 109154-. doi: 10.1016/j.cclet.2023.109154
Xin Zhang , Junyu Chen , Xiang Pei , Linxin Yang , Liang Wang , Luona Chen , Guangmei Yang , Xibo Pei , Qianbing Wan , Jian Wang . Drug-loading ZIF-8 for modification of microporous bone scaffold to promote vascularized bone regeneration. Chinese Chemical Letters, 2024, 35(6): 108889-. doi: 10.1016/j.cclet.2023.108889
Jin Long , Xingqun Zheng , Bin Wang , Chenzhong Wu , Qingmei Wang , Lishan Peng . Improving the electrocatalytic performances of Pt-based catalysts for oxygen reduction reaction via strong interactions with single-CoN4-rich carbon support. Chinese Chemical Letters, 2024, 35(5): 109354-. doi: 10.1016/j.cclet.2023.109354
Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO2 adsorption and conversion: Modification methods, reaction condition, and CO2 hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
Solvent molecules and hydrogen atoms have been omitted for clarity
Solvent molecules and hydrogen atoms have been omitted for clarity
Solvent molecules and hydrogen atoms have been omitted for clarity; Symmetry code: A: 1-x, 1-y, 1-z