Citation: Zhi-Yong MO, Shi-Zhu SONG, Wen-Yu LI, Xue-Long HE, Lu SHEN, Xiao-Hong GAO, Qi LI. Pd Nanoparticles Anchored on Porous Carbon Nanofibers for Enhanced Electrocatalytic Oxygen Reduction Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(6): 1037-1048. doi: 10.11862/CJIC.2022.110 shu

Pd Nanoparticles Anchored on Porous Carbon Nanofibers for Enhanced Electrocatalytic Oxygen Reduction Reaction

School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China

Corresponding author: Xiao-Hong GAO, gao.xh@ntu.edu.cn Qi LI, zhuiqiuzhizhuo@163.com
Received Date: 3 December 2021
Revised Date: 14 April 2022

Figures(10)

Zirconium-based metal-organic frameworks (UiO-66) nanomaterials with 2-amino terephthalic acid as a ligand was synthesized by the solvothermal method. PAN/UiO-66 fibers with free-dispersed UiO-66 nanoparticles were prepared by electrospinning. Porous carbon nanofibers (PCNFs) were prepared by controllable pyrolysis. Pd nanoparticles were deposited on the surface of PCNFs by the wet-chemistry reduction method to obtain PCNFs@Pd composites. The morphologies, compositions, and structures of PCNFs@Pd were characterized by scanning electron microscope, transmission electron microscope, and X -ray diffraction. The performances of oxygen reduction reaction (ORR) of PCNFs@Pd were tested by electrochemical workstations in 0.1 mol·L^-1 KOH and 0.1 mol·L^-1 HClO₄ electrolytes, respectively. It was found that adding UiO-66 into PAN fibers significantly improved the ORR performance of PCNFs@Pd (0.34% of Pd loading) composites. Compared with 40%Pt/C, PCNFs@Pd composites in alkaline electrolytes showed lower Tafel slope, better cycle stability, and methanol toxicity resistance. Moreover, the catalytic activity and cycle stability of PCNFs@Pd were comparable to that of 20%Pt/C in acidic electrolytes.
- UIO-66,
- electrospinning,
- porous carbon nanofibers,
- Pd nanoparticles,
- oxygen reduction reaction
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