Citation: Huan ZHENG, Yan-Xiao CHU, Si-Si FENG, Cai-Xia YUAN. Structure, Thermostability, Fluorescence, and Dye Adsorption Properties of a Copper(Ⅱ) Coordination Polymer Based on (+)-Di-p-toluoyl-D-tartaric Acid[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(6): 1112-1120. doi: 10.11862/CJIC.2022.109 shu

Structure, Thermostability, Fluorescence, and Dye Adsorption Properties of a Copper(Ⅱ) Coordination Polymer Based on (+)-Di-p-toluoyl-D-tartaric Acid

Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education, Shanxi University, Taiyuan 030006, China

Corresponding author: Si-Si FENG, ssfeng@sxu.edu.cn Cai-Xia YUAN, cxyuan@sxu.edu.cn
Received Date: 1 December 2021
Revised Date: 13 March 2022

Figures(12)

A coordination polymer, formulated as {[Cu(HDTTA)₂(DMF)(H₂O)]·DMF·H₂O}_n (1) (D-H₂DTTA=(+) -di-p-toluoyl-D-tartaric acid, DMF=N, N-dimethylformamide), has been synthesized. Its structure was characterized by IR spectrum, elemental analysis, X-ray single-crystal diffraction, and powder X-ray diffraction. Complex 1 features a 1D chain structure along the a-axis and forms a 2D layered structure in the ab plane through weak intermolecular interactions. The thermal decomposition process of 1 included the loss of solvent molecules below 197 ℃ and follow-up decomposition of the main structure. Under the excitation of 300 nm, the fluorescence of the ligand was quenched by the coordinated Cu²⁺ cation. In addition, complex 1 exhibited a good and specific adsorption effect on methylene blue dye in an aqueous solution with an adsorption rate of 81% after 49 min.
- copper(Ⅱ) complex,
- (+)-di-p-toluoyl-D-tartaric acid,
- crystal structure,
- fluorescence,
- dye adsorption
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