Citation: Bai-Tong NIU, Yan-Hui FENG, Hui-Ling LIAO, Hong-Xu GUO, Shao-Ming YING. Mixed Metal-Organic Frameworks with Supercapacitor Performance Constructed by Succinic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 951-958. doi: 10.11862/CJIC.2022.104 shu

Mixed Metal-Organic Frameworks with Supercapacitor Performance Constructed by Succinic Acid

1.
College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, Fujian 363000, China
2.
Fujian Provincial Key Laboratory of Featured Materials in Biochemical Industry, Ningde Normal University, Ningde, Fujian 352100, China

Corresponding author: Hong-Xu GUO, guohx@mnnu.edu.cn
Received Date: 27 October 2021
Revised Date: 9 March 2022

Figures(8)

A mixed metal-organic framework (MOF(Ni, Co)) was synthesized through a simple one-pot solvothermal method, and was characterized through X-ray diffraction, FT-IR, scanning electron microscope, X-ray photoelectron spectroscopy, and N₂ adsorption-desorption. The performance of the samples as supercapacitor electrode materials was further studied for the first time. The unique nano-flower -like structure of MOF(Ni_1.2Co_0.8) provides more electroactive sites and a shorter pathway for electron transfer and electrolyte diffusion, resulting in an excellent electrochemical performance with a high specific capacitance of 850 F·g^-1 at 1 A·g^-1. At the same time, this work shows that the MOF(Ni) electrode material doped with an appropriate amount of Co can facilitate the electron/ion transportation of the electrode, reduce the contact resistance between active material and electrolyte, increase the electrical conductivity, and enhance the electrochemical performance.
- supercapacitor,
- solvothermal method,
- metal-organic frameworks,
- nano-flower
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沈阳化工大学材料科学与工程学院沈阳 110142