Citation: Hao-Jie WANG, Rui-Qing WANG, Bing LI, Sheng SUI. Effects of Preformed Pt Nanoparticles on Structure of Platinum Nanowire Cathode for Proton Exchange Membrane Fuel Cells[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 787-799. doi: 10.11862/CJIC.2022.103 shu

Effects of Preformed Pt Nanoparticles on Structure of Platinum Nanowire Cathode for Proton Exchange Membrane Fuel Cells

Hao-Jie WANG ¹ ,
Rui-Qing WANG ² ,
Bing LI ^1,, ,
Sheng SUI ^2,,

1.
School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai 200237, China
2.
Institute of Fuel Cells, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Bing LI, bingli@ecust.edu.cn Sheng SUI, ssui@sjtu.edu.cn
Received Date: 24 October 2021
Revised Date: 31 March 2022

Figures(9)

Pt nanowires (Pt NWs) have been demonstrated to have a higher specific activity of oxygen reduction reaction (ORR) than that of commercial Pt/C due to their unique structural characteristics. In this work, a cathode with a uniform distribution of Pt NWs was obtained by introducing preformed Pt nanoparticles (NPs) into the carbon matrix to induce Pt NW growth. The structure and performance of the as-prepared cathode were investigated by altering Pt NP loadings (0-0.015 mg·cm^-2) and Pt NP sources (Pt/C with different Pt contents). The cathode surface was characterized by scanning electron microscopy (SEM), and the morphology and crystal structure of Pt NW were analyzed by transmission electron microscopy (TEM) and X -ray diffraction (XRD). Polarization and cyclic voltamme-try curves were obtained in single cells. The best single-cell performance, as well as the largest electrochemical surface area (ECSA) value was achieved by the cathode with preformed Pt NP loading of 0.005 mg·cm^-2 originating from 40% Pt/C. Finally, a possible mechanism for the influence of preformed Pt NPs in the Pt NW distribution was proposed.
- Pt nanowire,
- cathode structure,
- preformed Pt nanoparticle,
- induced growth,
- proton exchange membrane fuel cell
1. [1]
  Meng X T, Deng X, Zhou L S, Hu B, Tan W Y, Zhou W, Liu M L, Shao Z P. A Highly Ordered Hydrophilic -Hydrophobic Janus Bi-functional Layer with Ultralow Pt Loading and Fast Gas/Water Trans-port for Fuel Cells. Energy Environ[J]. Mater., 2021,4(1):126-133.
2. [2]
  ZHAO X Y, WU Y E. Synthesis of High-Performance and Low-Loading PtCo/C Proton Exchange Membrane Fuel Cell Catalysts[J]. Chinese J. Inorg. Chem., 2021,37(8):1457-1464.
3. [3]
  Garapati M S, Sundara R.. .Highly Efficient and ORR Active Platinum-Scandium Alloy -Partially Exfoliated Carbon Nanotubes Electrocata-lyst for Proton Exchange Membrane Fuel Cell. Int[J]. J. Hydrogen Energy, 2019,44(21):10951-10963. doi: 10.1016/j.ijhydene.2019.02.161
4. [4]
  Zhang H X, Liang J Y, Xia B W, Du S F. Ionic Liquid Modified Pt/C Electrocatalysts for Cathode Application in Proton Exchange Mem-brane Fuel Cells[J]. Front. Chem. Sci. Eng., 2019,13(4):695-701. doi: 10.1007/s11705-019-1838-8
5. [5]
  Li W B, Lin R, Yang Y. Investigation on the Reaction Area of PEMFC at Different Position in Multiple Catalyst Layer[J]. Electrochim. Acta, 2019,302:241-248. doi: 10.1016/j.electacta.2019.02.003
6. [6]
  Wu Z Y, Iqbal Z, Wang X Q. Metal-Free, Carbon-Based Catalysts for Oxygen Reduction Reactions[J]. Front. Chem. Sci. Eng., 2015,9(3):280-294. doi: 10.1007/s11705-015-1524-4
7. [7]
  Liu Z Y, Zhang J L, Yu P T, Zhang J X, Makharia R, More K L, Stach E A. Transmission Electron Microscopy Observation of Corrosion Behaviors of Platinized Carbon Blacks under Thermal and Electro-chemical Conditions[J]. J. Electrochem. Soc., 2010,157(6):B906-B913. doi: 10.1149/1.3391737
8. [8]
  Lu Y X, Du S F, Steinterger-Wilckens R.. One-Dimensional Nano-structured Electrocatalysts for Polymer Electrolyte Membrane Fuel Cells-A Review.[J]. Appl. Catal. B, 2016,199:292-314. doi: 10.1016/j.apcatb.2016.06.022
9. [9]
  Xia Y N, Yang P D, Sun Y G, Wu Y Y, Mayers B, Gates B, Yin Y D, Kim F, Yan H Q. One-Dimensional Nanostructures: Synthesis, Char-acterization, and Applications[J]. Adv. Mater., 2003,15(5):353-389. doi: 10.1002/adma.200390087
10. [10]
  Cademartiri L, Ozin G A. Ultrathin Nanowires-A Materials Chemistry Perspective[J]. Adv. Mater., 2009,21(9):1013-1020. doi: 10.1002/adma.200801836
11. [11]
  Zhang J T, Li C M. Nanoporous Metals: Fabrication Strategies and Advanced Electrochemical Applications in Catalysis, Sensing and Energy Systems[J]. Chem. Soc. Rev., 2012,41(21):7016-7031. doi: 10.1039/c2cs35210a
12. [12]
  Koenigsmann C, Zhou W P, Adzic R R, Sutter E, Wong S S.. Size-Dependent Enhancement of Electrocatalytic Performance in Rela-tively Defect -Free, Processed Ultrathin Platinum Nanowires.[J]. Nano Lett, 2010,10(8):2806-2811. doi: 10.1021/nl100718k
13. [13]
  Xu L B, Yan Y S, Zhang C W, Chen J F. Controlled Synthesis of Pt Nanowires with Ordered Large Mesopores for Methanol Oxidation Reaction[J]. Sci. Rep., 2016,631440. doi: 10.1038/srep31440
14. [14]
  Wang C Z, Zhang Y, Zhang Y J, Xu P, Feng C M, Chen T, Guo T, Yang F N, Wang Q, Wang J X. Highly Ordered Hierarchical Pt and PtNi Nanowire Arrays for Enhanced Electrocatalytic Activity toward Methanol Oxidation[J]. ACS Appl. Mater. Interfaces, 2018,10(11):9444-9450. doi: 10.1021/acsami.7b19727
15. [15]
  Li C L, Sato T, Yamauchi Y. Electrochemical Synthesis of One-Dimensional Mesoporous Pt Nanorods Using the Assembly of Surfac-tant Micelles in Confined Space[J]. Angew. Chem., 2013,125(31):8208-8211. doi: 10.1002/ange.201303035
16. [16]
  Sun S H, Yang D Q, Zhang G X, Sacher E, Dodelet J P. Synthesis and Characterization of Platinum Nanowire-Carbon Nanotube Heter-ostructures[J]. Chem. Mater., 2007,19(26):6376-6378. doi: 10.1021/cm7022949
17. [17]
  Sun S H, Yang D, Villers D, Zhang G X, Sacher E, Dodelet J P. Template-and Surfactant-Free Room Temperature Synthesis of Self-Assembled 3D Pt Nanoflowers from Single-Crystal Nanowires[J]. Adv. Mater., 2008,20(3):571-574. doi: 10.1002/adma.200701408
18. [18]
  Sun S H, Jaouen F, Dodelet J P. Controlled Growth of Pt Nanowires on Carbon Nanospheres and Their Enhanced Performance as Elec-trocatalysts in PEM Fuel Cells[J]. Adv. Mater., 2008,20(20):3900-3904. doi: 10.1002/adma.200800491
19. [19]
  Sun S H, Zhang G X, Geng D S, Chen Y Q, Li R Y, Cai M, Sun X L. A Highly Durable Platinum Nanocatalyst for Proton Exchange Membrane Fuel Cells: Multiarmed Starlike Nanowire Single Crystal[J]. Angew. Chem, 2011,123(2):442-446. doi: 10.1002/ange.201004631
20. [20]
  Meng H, Zhan Y, Zeng D, Zhang X X, Zhang G Q, Jaouen F. Factors Influencing the Growth of Pt Nanowires via Chemical Self-Assembly and Their Fuel Cell Performance[J]. Small, 2015,11(27):3377-3386. doi: 10.1002/smll.201402904
21. [21]
  Du C Y, Cheng X Q, Yang T, Yin G P, Shi P F. Numerical Simula-tion of the Ordered Catalyst Layer in Cathode of Proton Exchange Membrane Fuel Cells[J]. Electrochem. Commun., 2005,7(12):1411-1416. doi: 10.1016/j.elecom.2005.09.022
22. [22]
  Bonnefont A, Ruvinskiy P, Rouhet M, Orfanidi A, Neophytides S, Savinova E. Advanced Catalytic Layer Architectures for Polymer Electrolyte Membrane Fuel Cells[J]. WIREs Energy Environ., 2014,3(5):505-521. doi: 10.1002/wene.110
23. [23]
  Tian Z Q, Lim S H, Poh C K, Tang Z, Xia Z T, Luo Z Q, Shen P K, Chua D, Feng Y P, Shen Z X. A. Highly Order -Structured Membrane Electrode Assembly with Vertically Aligned Carbon Nanotubes for Ultra-Low Pt Loading PEM Fuel Cells[J]. Adv. Energy Mater., 2011,1(6):1205-1214. doi: 10.1002/aenm.201100371
24. [24]
  Du S F. A Facile Route for Polymer Electrolyte Membrane Fuel Cell Electrodes with In Situ Grown Pt Nanowires[J]. J. Power Sources, 2010,195(1):289-292. doi: 10.1016/j.jpowsour.2009.06.091
25. [25]
  Su K H, Sui S, Yao X Y, Wei Z X, Zhang J L, Du S F. Controlling Pt Loading and Carbon Matrix Thickness for a High Performance Pt-Nanowire Catalyst Layer in PEMFCs[J]. Int. J. Hydrogen Energy, 2014,39(7):3397-3403. doi: 10.1016/j.ijhydene.2013.12.062
26. [26]
  Wei Z X, He A, Su K H, Sui S.. Carbon Matrix Effects on the Micro-Structure and Performance of Pt Nanowire Cathode Prepared by Decal Transfer Method.[J]. J. Energy Chem, 2015,24(2):213-218. doi: 10.1016/S2095-4956(15)60303-5
27. [27]
  Jana N R, Gearheart L, Murphy C J.. Evidence for Seed-Mediated Nucleation in the Chemical Reduction of Gold Salts to Gold Nanoparticles[J]. Chem. Mater., 2001,13(7):2313-2322. doi: 10.1021/cm000662n
28. [28]
  Zhao X J, Luo X J, Bazuin C G, Masson J F. In Situ Growth of AuNPs on Glass Nanofibers for SERS Sensors[J]. ACS Appl. Mater. Interfaces, 2020,12(49):55349-55361. doi: 10.1021/acsami.0c15311
29. [29]
  Kuttner C, Mayer M, Dulle M, Moscoso A, López-Romero J M, Förster S, Fery A, Pérez-Juste J, Contreras -Cáceres R. Seeded Growth Synthesis of Gold Nanotriangles: Size Control, SAXS Analy-sis, and SERS Performance[J]. ACS Appl. Mater. Interfaces, 2018,10(13):11152-11163. doi: 10.1021/acsami.7b19081
30. [30]
  Tangeysh B, Tibbetts K M, Odhner J H, Wayland B B, Levis R J. Gold Nanotriangle Formation through Strong-Field Laser Processing of Aqueous KAuCl₄ and Postirradiation Reduction by Hydrogen Per-oxide[J]. Langmuir, 2017,33(1):243-252. doi: 10.1021/acs.langmuir.6b03812
31. [31]
  Ooi M J, Aziz A A. Seed -Mediated Grown Platinum Nanocrystal: A Correlation between Seed Volume and Catalytic Performance of For-mic Acid and Ethanol Oxidation[J]. Int. J. Hydrogen Energy, 2017,42(14):9063-9068. doi: 10.1016/j.ijhydene.2016.06.032
32. [32]
  Lu Y X, Du S F, Steinberger-Wilckens R. Three-Dimensional Cata-lyst Electrodes Based on PtPd Nanodendrites for Oxygen Reduction Reaction in PEFC Applications[J]. Appl. Catal. B, 2016,187:108-114. doi: 10.1016/j.apcatb.2016.01.019
33. [33]
  Wang R Q, Cao X L, Sui S, Li B, Li Q F. Study on the Growth of Plat-inum Nanowires as Cathode Catalysts in Proton Exchange Membrane fuel cells[J]. Front. Chem. Sci. Eng., 2022,16:364-375. doi: 10.1007/s11705-021-2052-z
34. [34]
  Berhault G, Bausach M, Bisson L, Becerra L, Thomazeau C, Uzio D.. Seed-Mediated Synthesis of Pd Nanocrystals: Factors Influencing a Kinetic-or Thermodynamic -Controlled Growth Regime[J]. J. Phys. Chem. C, 2007,111(16):5915-5925. doi: 10.1021/jp0702752
35. [35]
  Lee E P, Chen J Y, Yin Y D, Campbell C T, Xia Y N. Pd-Catalyzed Growth of Pt Nanoparticles or Nanowires as Dense Coatings on Poly-meric and Ceramic Particulate Supports[J]. Adv. Mater., 2006,18(24):3271-3274. doi: 10.1002/adma.200601070
36. [36]
  Du S F, Pollet B G.. Catalyst Loading for Pt -Nanowire Thin Film Electrodes in PEFCs[J]. Int. J. Hydrogen Energy, 2012,37(23):17892-17898. doi: 10.1016/j.ijhydene.2012.08.148
37. [37]
  Zheng J, Zhou S Y, Gu S, Xu B J, Yan Y S. Size-Dependent Hydro-gen Oxidation and Evolution Activities on Supported Palladium Nanoparticles in Acid and Base[J]. J. Electrochem. Soc., 2016,163(6):F499-F506. doi: 10.1149/2.0661606jes
38. [38]
  Lee W J, Bera S, Shin H C, Hong W P, Oh S J, Wan Z X, Kwon S H. Uniform and Size-Controlled Synthesis of Pt Nanoparticle Catalyst by Fluidized Bed Reactor Atomic Layer Deposition for PEMFCs[J]. Adv. Mater. Interfaces, 2019,6(21)1901210. doi: 10.1002/admi.201901210
39. [39]
  Lee W J, Bera S, Woo H J, Ahn J W, Bae J S, Oh I K, Kwon S H. Controllable Size and Crystallinity of Ru Nanoparticles on Carbon Support by Fluidized Bed Reactor-Atomic Layer Deposition for Enhanced Hydrogen Oxidation Activity[J]. J. Mater. Chem. A, 2021,9:17223-17230. doi: 10.1039/D1TA03678E
40. [40]
  Hou Y Z, Deng H, Pan F W, Chen W M, Du Q, Jiao K.. Pore-Scale Investigation of Catalyst Layer Ingredient and Structure Effect in Proton Exchange Membrane Fuel Cell[J]. Appl. Energy, 2019,253113561. doi: 10.1016/j.apenergy.2019.113561
41. [41]
  Lu Y X, Du S F, Steinberger -Wilckens R.. Temperature-Controlled Growth of Single -Crystal Pt Nanowire Arrays for High Performance Catalyst Electrodes in Polymer Electrolyte Fuel Cells[J]. Appl. Catal. B, 2015,164:389-395. doi: 10.1016/j.apcatb.2014.09.040
42. [42]
  Baricci A, Bonanomi M, Yu H, Guetaz L, Maric R, Casalegno A. Modelling Analysis of Low Platinum Polymer Fuel Cell Degradation under Voltage Cycling: Gradient Catalyst Layers with Improved Durability[J]. J. Power Sources, 2018,405:89-100. doi: 10.1016/j.jpowsour.2018.09.092
43. [43]
  Thanh N T, Maclean N, Mahiddine S. Mechanisms of Nucleation and Growth of Nanoparticles in Solution[J]. Chem. Rev., 2014,114(15):7610-7630. doi: 10.1021/cr400544s
44. [44]
  Sosso G C, Chen J, Cox S J, Fitzner M, Pedevilla P, Zen A, Michae-lides A. Crystal Nucleation in Liquids: Open Questions and Future Challenges in Molecular Dynamics Simulations[J]. Chem. Rev., 2016,116(12):7078-7116. doi: 10.1021/acs.chemrev.5b00744
45. [45]
  Chayen N E. Methods for Separating Nucleation and Growth in Protein Crystallization[J]. Prog. Biophys. Mol. Biol., 2005,88(3):329-337. doi: 10.1016/j.pbiomolbio.2004.07.007
46. [46]
  Nikoobakht B, El-Sayed M A. Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method[J]. Chem. Mater., 2003,15(10):1957-1962. doi: 10.1021/cm020732l
47. [47]
  Xiong Y, Xiao L, Yang Y, DiSalvo F J, Abruña H D. High-Loading Intermetallic Pt₃ Co/C Core-Shell Nanoparticles as Enhanced Activity Electrocatalysts toward the Oxygen Reduction Reaction (ORR)[J]. Chem. Mater., 2018,30(5):1532-1539. doi: 10.1021/acs.chemmater.7b04201
48. [48]
  Wang L, Wang H J, Nemoto Y, Yamauchi Y. Rapid and Efficient Synthesis of Platinum Nanodendrites with High Surface Area by Chemical Reduction with Formic Acid[J]. Chem. Mater., 2010,22(9):2835-2841. doi: 10.1021/cm9038889
49. [49]
  Su K H, Yao X Y, Sui S, Wei Z X, Zhang J L, Du S F. Matrix Material Study for In Situ Grown Pt Nanowire Electrocatalyst Layer in Proton Exchange Membrane Fuel Cells (PEMFCs)[J]. Fuel Cells, 2015,15(3):449-455. doi: 10.1002/fuce.201400168
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