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Citation: Yan-Qiong SHEN, Yun-Chao GENG, Jian-Bo WANG, Xue FAN, Qi-Peng LI. Preparation of R6G@γ-CD-MOFs Composites with Application in Sensing of Fe3+ Ion[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 800-804. doi: 10.11862/CJIC.2022.100 shu

Preparation of R6G@γ-CD-MOFs Composites with Application in Sensing of Fe3+ Ion

  • School of Chemistry and Chemical Engineering, Zhaotong University, Zhaotong, Yunnan 657000, China

  • Corresponding author: Qi-Peng LI, qpli@ztu.edu.cn
  • Received Date: 2 July 2021
    Revised Date: 9 March 2022

Figures(4)

  • γ-CD-MOFs were synthesized with γ-cyclodextrin (γ-CD), potassium hydroxide, methanol, and water, whose structure, stability, and morphology were characterized by X-ray diffraction, thermogravimetric analysis, and scanning electron microscope. Due to γ- CD- MOFs having a 1D channel, rhodamine 6G (R6G) with yellow light emission was introduced into the channel, to obtain a fluorescent composite R6G@γ-CD-MOFs and its fluorescence response to different metal ions was explored. The experimental results show that R6G@γ-CD-MOFs can selectively sense Fe3+ ions from 12 kinds of metal ions, and its fluorescence quenching constant (Ksv) was 1.03×104 L·mol-1 in a range of 2×10-4-2.0×10-2 mol·L-1.
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