Citation: Zhen-Yu CAO, Yun WU, Jian-Hua GAO. Bi₉P₂O₁₈Cl: Phase Transition and Hydrogen Production by Photocatalytic Water-Splitting[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 969-976. doi: 10.11862/CJIC.2022.099 shu

Bi₉P₂O₁₈Cl: Phase Transition and Hydrogen Production by Photocatalytic Water-Splitting

School of Physics, Northwest University, Xi′an 710069, China

Corresponding author: Jian-Hua GAO, gaojh@nwu.edu.cn
Received Date: 20 December 2021
Revised Date: 18 March 2022

Figures(5)

Bi₉P₂O₁₈Cl crystals were prepared by the high-temperature molten salt method. Single-crystal X-ray diffraction data analyses demonstrated that Bi₉P ₂O₁₈Cl can undergo a crystal-to-crystal phase transition from room temperature to low temperature. At room temperature, this compound (α-phase) crystallizes in monoclinic space group P2₁/m (11) with unit cell parameters a=1.149 10(7) nm, b =0.540 64(4) nm, c=1.463 69(9) nm, β =93.741(6)°, V= 0.907 38(10) nm³. And at 100 K, it (β-phase) crystallizes in monoclinic space group P2₁/n (14) with unit cell parameters a=1.790 56(4) nm, b=0.538 870(10) nm, c=1.915 57(4) nm, β=103.693(2)°, V=1.795 76(6) nm³. Additionally, high pure powder samples of Bi₉P₂ O₁₈Cl were synthesized using solid -state reaction method, which exhibited promising performance in photocatalytic water splitting to produce H₂, the H₂ evolution rates reached 33.69 µmol·g^-1·h^-1. CCDC: 2128785, α-phase Bi₉P₂O₁₈Cl; 2145491, β-phase Bi₉P₂O₁₈Cl.
- Aurivillius,
- crystal structure,
- phase transition,
- photocatalytic hydrogen production
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Bi₉P₂O₁₈Cl: Phase Transition and Hydrogen Production by Photocatalytic Water-Splitting