Citation: Cong-Ling LI, Xiao-Yu LU. Cyanide-Bridged Bimetallic Active Site in Porous Carbon-Matrix for Oxygen Reduction Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 930-940. doi: 10.11862/CJIC.2022.098 shu

Cyanide-Bridged Bimetallic Active Site in Porous Carbon-Matrix for Oxygen Reduction Reaction

Cong-Ling LI ^, ,
Xiao-Yu LU

College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

Corresponding author: Cong-Ling LI, conglingli@sues.edu.cn
Received Date: 22 October 2021
Revised Date: 24 February 2022

Figures(8)

Using special compound {[Co(bpy)₂]₃[Fe(CN) ₆]₂}[Fe(CN)₆]_1/3 as a precursor, an ordered mesoporous Fe-Co- N-doped graphite - based catalyst (Fe-Co-N-GC) with the embedding Fe—N, Co— N, and Fe—C≡N —Co active sites was prepared by a nano-casting technique. Together with the high surface area and graphitization degree, the catalytic performance of Fe-Co-N-GC for oxygen reduction reaction (ORR) was remarkably enhanced. This Fe-Co-based bimetallic catalyst also exhibited superior durability and good tolerance to methanol in ORR.
- mesoporous material,
- bimetallic catalyst,
- synergistic effect,
- oxygen reduction reaction,
- fuel cells
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