Chiroptical Properties of Mixed-Ligand Ruthenabenzene Complex
- Corresponding author: Li-Xia FENG, lxfeng@tynu.edu.cn Yue-Kui WANG, ykwang@sxu.edu.cn
Citation: Li-Xia FENG, Qiao-Ling LIU, Si-Si FENG, Yu-Cui HOU, Yue-Kui WANG. Chiroptical Properties of Mixed-Ligand Ruthenabenzene Complex[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(4): 665-674. doi: 10.11862/CJIC.2022.079
XU Z X, LI L F, BAI X L, XU S F. Enantiomeric Helical Frameworks with dia Net Based on Rigid Ligands from Spontaneous Resolution[J]. Chinese J. Inorg. Chem., 2021,37(7):1191-1196.
CHENG L, YANG J H, ZHAI Q C, ZHANG Q S. A Chiral Ag(Ⅰ) Coordination Polymer Based on an α, α-L-Diaryl Prolinol-Pyridine Derivative: Circular Dichroism, SHG Response and Luminescent Property[J]. Chinese J. Inorg. Chem., 2020,36(2):361-367.
Zhao X, Nguyen E T, Hong A N, Feng P Y, Bu X H. Chiral Isocamphoric Acid: Founding a Large Family of Homochiral Porous Materials[J]. Angew. Chem. Int. Ed., 2018,57(24):7101-7105. doi: 10.1002/anie.201802911
Santos A R, Escudero D, González L, Orellana G. Unravelling the Quenching Mechanisms of a Luminescent RuⅡ Probe for CuⅡ[J]. Chem. Asian J., 2015,10(3):622-629. doi: 10.1002/asia.201403340
Knoll J D, Turro C. Control and Utilization of Ruthenium and Rhodium Metal Complex Excited States for Photoactivated Cancer Therapy[J]. Coord. Chem. Rev., 2015,282-283:110-126. doi: 10.1016/j.ccr.2014.05.018
Estalayo-Adrián S, Garnir K, Moucheron C. Perspectives of Ruthenium Polyazaaromatic Photo -oxidizing Complexes Photoreactive towards Tryptophan-Containing Peptides and Derivatives[J]. Chem. Commun., 2018,54:322-337. doi: 10.1039/C7CC06542F
Padhi S K, Fukuda R, Ehara M, Tanaka K. Photoisomerization and Proton-Coupled Electron Transfer (PCET) Promoted Water Oxidation by Mononuclear Cyclometalated Ruthenium Catalysts[J]. Inorg. Chem., 2012,51(9):5386-5392. doi: 10.1021/ic3003542
Feng L X, Wang Y K, Jia J. Triplet Ground-State-Bridged Photochemical Process: Understanding the Photoinduced Chiral Inversion at the Metal Center of[Ru(phen)2(L-Ser)] + and Its Bipy Analogues[J]. Inorg. Chem., 2017,56(23):14467-14476. doi: 10.1021/acs.inorgchem.7b02030
Feng L X, Wang Y K. A Key Factor Dominating the Competition between Photolysis and Photoracemization of [Ru(bipy)3]2+ and [Ru(phen)3]2+ Complexes[J]. Inorg. Chem., 2018,57(15):8994-9001. doi: 10.1021/acs.inorgchem.8b00975
Salassa L, Borfecchia E, Ruiu T, Garino C, Gianolio D, Gobetto R, Sadler P J, Cammarata M, Wulff M, Lamberti C. Photo-induced Pyridine Substitution in cis-[Ru(bpy)2(py)2]Cl2: A Snapshot by Time-Resolved X-ray Solution Scattering[J]. Inorg. Chem., 2010,49(23):11240-11248. doi: 10.1021/ic102021k
Wang Y, Wang Y K, Wang J M, Liu Y, Yang Y T. Theoretical Analysis of the Individual Contributions of Chiral Arrays to the Chiroptical Properties of Tris -diamine Ruthenium Chelates[J]. J. Am. Chem. Soc., 2009,131(25):8839-8847. doi: 10.1021/ja9004738
Zhu J, Jia G C, Lin Z Y. Understanding Nonplanarity in Metallabenzene Complexes[J]. Organometallics, 2007,26(8):1986-1995. doi: 10.1021/om0701367
Lin R, Zhao J, Chen H Y, Zhang H, Xia H P. Interconversion of Metallabenzenes and Cyclic η2-Allene-Coordinated Complexes[J]. Chem. Asian J., 2012,7(8):1915-1924. doi: 10.1002/asia.201200231
Wang T D, Li S H, Zhang H, Lin R, Han F F, Lin Y M, Wen T B, Xia H P. Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole[J]. Angew. Chem. Int. Ed., 2009,48(35):6453-6456. doi: 10.1002/anie.200902738
Iron M A, Lucassen A C B, Cohen H, van der Boom M E, Martin J M L. A Computational Foray into the Formation and Reactivity of Metallabenzenes[J]. J. Am. Chem. Soc., 2004,126(37):11699-11710. doi: 10.1021/ja047125e
Yang J, Jones W M, Dixon J K, Allison N T. Detection of a Ruthena-benzene, Ruthenaphenoxide, and Ruthenaphenanthrene Oxide: The First Metalla Aromatics of a Second-Row Transition Metal[J]. J. Am. Chem. Soc., 1995,117(38):9776-9777. doi: 10.1021/ja00143a029
Zhang H, Xia H P, He G M, Wen T B, Gong L, Jia G C. Synthesis and Characterization of Stable Ruthenabenzenes[J]. Angew. Chem. Int. Ed., 2006,45(18):2920-2923. doi: 10.1002/anie.200600055
Lin R, Zhang H, Li S H, Wang J N, Xia H P. New Highly Stable Metallabenzenes via Nucleophilic Aromatic Substitution Reaction[J]. Chem. Eur. J., 2011,17(15):4223-4231. doi: 10.1002/chem.201003566
Zhang H, Lin R, Li J H, Zhu J, Xia H P. Interconversion between Ruthenacyclohexadiene and Ruthenabenzene: A Combined Experimental and Theoretical Study[J]. Organometallics, 2014,33(19):5606-5609. doi: 10.1021/om500550a
Lin R, Zhang H, Li S H, Chen L, Zhang W, Wen T B, Zhang H, Xia H. pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthena-benzene with L-and D-Cysteine[J]. Chem. Eur. J., 2011,17(8):2420-2427. doi: 10.1002/chem.201001867
Andrae D, Häußermann U, Dolg M, Stoll H, Preuß H. Energy-Adjusted Ab Initio Pseudopotentials for the Second and Third Row Transition Elements[J]. Theor. Chim. Acta, 1990,77(2):123-141. doi: 10.1007/BF01114537
Martin J M L, Sundermann A. Correlation Consistent Valence Basis Sets for Use with the Stuttgart-Dresden-Bonn Relativistic Effective Core Potentials: The Atoms Ga-Kr and In-Xe[J]. J. Chem. Phys., 2001,114(8):3408-3420. doi: 10.1063/1.1337864
Kurapkat G, Krüger P, Wollmer A, Fleischhauer J, Kramer B, Zobel E, Koslowski A, Botterweck H, Woody R W. Calculations of the CD Spectrum of Bovine Pancreatic Ribonuclease[J]. Biopolymers, 1997,41(3):267-287. doi: 10.1002/(SICI)1097-0282(199703)41:3<267::AID-BIP3>3.0.CO;2-Q
Berova N, Polavarapu P L, Nakanishi K, Woody R W. Comprehensive Chiroptical Spectroscopy: Instrumentation, Methodologies, and Theoretical Simulations. New Jersey: John Wiley & Sons, 2012: 525-540
Zhang H, Feng L, Gong L, Wu L Q, He G M, Wen T B, Yang F Z, Xia H P. Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC≡CCH(OH)C≡CH[J]. Organometallics, 2007,26(10):2705-2713. doi: 10.1021/om070195k
Bosnich B. The Absolute Configurations of Bis-Bidentate Chelate Compounds. The Case of the cis-Bis(pyridine)bis(o-phenanthroline)-Ruthenium(Ⅱ) Ion[J]. Inorg. Chem., 1968,7(1):178-180. doi: 10.1021/ic50059a044
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO2 by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
Experimental crystal structure is obtained from the reference[25]