Citation: Bei-Bei YANG, Yan-Yan DU, Yu-Lin ZHANG, Ting-Ting CHEN, Duan BIN, Hong-Bin LU, Yong-Yao XIA. Electrochemical Performance of Ti₃C₂T_x/MnO₂ Cathode in Aqueous Zinc Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(4): 578-588. doi: 10.11862/CJIC.2022.075 shu

Electrochemical Performance of Ti₃C₂T_x/MnO₂ Cathode in Aqueous Zinc Ion Batteries

Bei-Bei YANG ¹ ,
Yan-Yan DU ¹ ,
Yu-Lin ZHANG ¹ ,
Ting-Ting CHEN ¹ ,
Duan BIN ^1,, ,
Hong-Bin LU ^{1, 2,,} ,
Yong-Yao XIA ³

1.
Department of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China
2.
Haian Institute of High-Tech Research, Nanjing University, Nantong, Jiangsu 226634, China
3.
Department of Chemistry, Fudan University, Shanghai 200433, China

Corresponding author: Duan BIN, dbin17@fudan.edu.cn Hong-Bin LU, luhb@ntu.edu.cn
Received Date: 27 September 2021
Revised Date: 18 February 2022

Figures(7)

Owing to the advantages of large specific capacity, high work potential, rich reserves, and low price, manganese dioxide (MnO₂) material has become the most potential material for the cathode in aqueous zinc batteries (AZBs). However, it still has problems with poor structural stability and complex electrochemical storage mechanism. Herein, a kind of Ti₃C₂T_x/MnO₂ composite material based on bract - liked structural of MnO₂ deposited on Ti₃C₂T_x was prepared by a two-step method, and the structure, composition, and morphology of the composite were characterized by X - ray powder diffraction (XRD), X - ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM). The zinc storage performance of Ti₃C₂T_x/MnO₂ cathode were evaluated in different aqueous electrolyte (2 mol·L^-1 ZnSO₄, 2 mol·L^-1 ZnSO₄+0.1 mol·L^-1 MnSO₄, 30 mol·L^-1 tetraethylammonium triflate (TEAOTf)+1 mol·L^-1 ZnCF₃SO₃ (ZnOTf), 3 mol·L^-1 ZnOTf), respectively. As a result, Ti₃C₂T_x/MnO₂ cathode displayed two obvious discharge platforms in 2 mol·L^-1 ZnSO₄ and 2 mol·L^-1 ZnSO₄+0.1 mol·L^-1 MnSO₄ solution, which is attributed to the co-insertion of H⁺ and Zn²⁺ due to the weak acidic electrolyte. The initial platform region at 1.0 V occurred in the first step is the insertion of H⁺, and the subsequent reaction is the insertion of Zn²⁺ into Ti₃C₂T_x/MnO₂ electrode. However, in the neutral of 3 mol·L^-1 ZnOTf and 30 mol·L^-1 TEAOTf+1 mol·L^-1 ZnOTf electrolyte, the insertion of H⁺ into the Ti₃C₂T_x/MnO₂ cathode hardly appears, and the obtained discharge capacity may mainly come from the intercalation of Zn²⁺. Moreover, the utilization of ultra -high concentration electrolyte could not only improve the reversibility of Ti₃C₂T_x/MnO₂ electrode material but also effectively inhibit the dissolution of electrode material in the cycling process (78.2% capacity retention after 100 cycles at 0.2 A·g^-1).
- aqueous zinc battery,
- Ti₃C₂T_x/MnO₂,
- electrochemical performance,
- tetraethylammonium triflate,
- ZnCF₃SO₃
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Electrochemical Performance of Ti₃C₂T_x/MnO₂ Cathode in Aqueous Zinc Ion Batteries