Citation: Zi-Wei WANG, Hao-Dong WU, Yaseen Muhammad, Ai-Lin LIANG, He LIU, Zi-Ang NING, Shuai WANG, Gang WANG, Wei QUAN, Hao WANG. Two-Dimensional Coordination Polymer [Tb(1, 4-bdc)_1.5(phen)(H₂O)]_n: Synthesis, Crystal Structure and Luminescent Detection of Fe³⁺[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(3): 551-558. doi: 10.11862/CJIC.2022.056 shu

Two-Dimensional Coordination Polymer [Tb(1, 4-bdc)_1.5(phen)(H₂O)]_n: Synthesis, Crystal Structure and Luminescent Detection of Fe³⁺

Zi-Wei WANG ¹ ,
Hao-Dong WU ¹ ,
Yaseen Muhammad ² ,
Ai-Lin LIANG ¹ ,
He LIU ¹ ,
Zi-Ang NING ¹ ,
Shuai WANG ¹ ,
Gang WANG ¹ ,
Wei QUAN ¹ ,
Hao WANG ^1,,

1.
Beijing Key Lab of Special Elastomer Composite Materials, College of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
2.
Institute of Chemical Sciences, University of Peshawar, Peshawar 25120, Pakistan

Corresponding author: Hao WANG, wangh@bipt.edu.cn
Received Date: 14 September 2021
Revised Date: 20 November 2021

Figures(8)

Two-dimensional coordination polymer of [Tb(1, 4-bdc)_1.5(phen)(H₂O)]_n (1) (1, 4-H₂bdc=terephthalic acid, phen=1, 10-phenanthroline) was synthesized by solvothermal approach. Complex 1 was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy, elemental analysis, and fluorescence spectra. X-ray diffraction crystallographic analyses show that complex 1 crystallizes in the triclinic crystal system P1 space group; two adjacent Tb(Ⅲ) ions are bridged by —O—C—O— from four 1, 4-bdc^2- into a binuclear unit, and further bridged by 1, 4-bdc^2- into an infinite 2D layered structure. The fluorescence experiment proved that the complex 1 can detect Fe³⁺ through the fluorescence quenching mechanism with K_sv=8.39×10³ L·mol^-1 and limit of detection of 0.017 μmol·L^-1.
- coordination polymer,
- crystal structure,
- luminescence sensing
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Two-Dimensional Coordination Polymer [Tb(1, 4-bdc)1.5(phen)(H2O)]n: Synthesis, Crystal Structure and Luminescent Detection of Fe3+

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通讯作者: 陈斌, bchen63@163.com

Two-Dimensional Coordination Polymer [Tb(1, 4-bdc)_1.5(phen)(H₂O)]_n: Synthesis, Crystal Structure and Luminescent Detection of Fe³⁺