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Citation: Chang-Wei DANG, Yong-Wei ZHANG, Feng HAN, Jiao-E DANG, Zhuo-Lei LIU, Yin-Hao WANG, Ying-Ying DENG, Si-Ning YUN. Chemical Co-precipitation Preparation of ZnMoO4/Aloe-Derived Porous Carbon and Catalytic Performance[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(3): 489-500. doi: 10.11862/CJIC.2022.046 shu

Chemical Co-precipitation Preparation of ZnMoO4/Aloe-Derived Porous Carbon and Catalytic Performance

  • Functional Materials Laboratory (FML), School of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China

  • Corresponding author: Si-Ning YUN, yunsining@xauat.edu.cn
  • Received Date: 29 September 2021
    Revised Date: 10 December 2021

Figures(8)

  • Herein, aloe-derived porous carbon (APC), ZnMoO4, and ZnMoO4/APC catalysts were successfully prepared by two-step activation and chemical co-precipitation, respectively. As counter electrodes (CEs) in dyesensitized solar cells (DSSCs), the electrochemical properties and photovoltaic performance of these three CE catalysts in Cu-mediated DSSCs with D35 and Y123 dyes were explored. The microstructure, chemical composition, specific surface area, and porous textures of APC, ZnMoO4, and ZnMoO4/APC were characterized by field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), and N2 adsorption-desorption isotherms. The results show that APC was a porous network structure with a specific surface area of 1 439 m2·g-1, and ZnMoO4 nanoparticles were evenly embedded or dispersed on the surface of APC. ZnMoO4/APC delivered a power conversion efficiency (PCE) of 3.97% and 3.72% in the Cu2+/Cu+ electrolyte-based DSSCs with D35 and Y123 dyes, respectively, which was higher than that of APC (2.72%, 2.61%), ZnMoO4 (1.24%, 1.08%) and Pt (2.86%, 2.80%) at the same conditions.
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