Citation: Mei-Chao GAO, Yun-Yun GONG, Zi-Yue LI, Bai-Hui WANG, Xiao-Qing HUANG, Wen-Jiao YU. Fabrication of Bi₁₂O₁₇Br₂ with Efficient Photocatalytic N₂ Fixation Boosted by Photoinduced Oxygen Vacancies[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(3): 542-550. doi: 10.11862/CJIC.2022.043 shu

Fabrication of Bi₁₂O₁₇Br₂ with Efficient Photocatalytic N₂ Fixation Boosted by Photoinduced Oxygen Vacancies

School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong 273165, China

Corresponding author: Mei-Chao GAO, meichaogao@hotmail.com
Received Date: 14 September 2021
Revised Date: 29 December 2021

Figures(8)

Bi₁₂O₁₇Br₂ photocatalyst was prepared through a one-pot hydrothermal method. An average microsheets size of 1.2 μm and a high specific surface area of ca. 29 m²·g^-1 were observed for Bi₁₂O₁₇Br₂ photocatalyst. Bi₁₂O₁₇Br₂ has a bandgap of 2.42 eV, which can be excited under visible light illumination. The photoinduced oxygen vacancies are easily generated on the surface of Bi₁₂O₁₇Br₂. The N₂ molecules could be captured and activated by oxygen vacancies. An NH₃ generation rate of 337.6 μmol·g^-1·h^-1 was detected on Bi₁₂O₁₇Br₂ under visible light irradiation. It demonstrates that the accomplishment of the visible-light-driven photocatalytic for the N₂ photo fixation with H₂O over a Bi₁₂O₁₇Br₂ photocatalyst.
- Bi₁₂O₁₇Br₂,
- photocatalysis,
- oxygen vacancy,
- N₂ photo fixation
1. [1]
  Bao D, Zhang Q, Meng F L, Zhong H X, Shi M M, Zhang Y, Yan J M, Jiang Q, Zhang X B. Electrochemical Reduction of N₂ under Ambient Conditions for Artificial N₂ Fixation and Renewable Energy Storage Using N₂/NH₃ Cycle[J]. Adv. Mater., 2017,29(3)1604799. doi: 10.1002/adma.201604799
2. [2]
  Wang K Y, Gu G Z, Hu S Z, Zhang J, Sun X L, Wang F, Li P, Zhao Y F, Fan Z P, Zou X. Molten Salt Assistant Synthesis of Three-Dimensional Cobalt Doped Graphitic Carbon Nitride for Photocatalytic N₂ Fixation: Experiment and DFT Simulation Analysis[J]. Chem. Eng. J., 2019,368:896-904. doi: 10.1016/j.cej.2019.03.037
3. [3]
  Bai Y J, Bai H Y, Qu K G, Wang F G, Guan P, Xu D B, Fan W Q, Shi W D. In-Situ Approach to Fabricate BiOI Photocathode with Oxygen Vacancies: Understanding the N₂ Reduced Behavior in Photoelectro-chemical System[J]. Chem. Eng. J., 2019,362:349-356. doi: 10.1016/j.cej.2019.01.051
4. [4]
  GAO X M, SHANG Y Y, LIU L B. Preparation and Photocatalytic Nitrogen Fixation Performance of Cd Doping δ-Bi₂O₃ Nanosheets[J]. Chinese J. Inorg. Chem., 2019,35(4):580-588.
5. [5]
  Tanaka H, Nishibayashi Y, Yoshizawa K. Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes[J]. Acc. Chem. Res., 2016,49(5):987-995. doi: 10.1021/acs.accounts.6b00033
6. [6]
  Schrauzer G N, Guth T D. Photolysis of Water and Photoreduction of Nitrogen on Titanium Dioxide[J]. J. Am. Chem. Soc., 1977,99(22):7189-7193. doi: 10.1021/ja00464a015
7. [7]
  Liao Y, Lin J N, Cui B H, Xie G, Hu S. Well-Dispersed Ultrasmall Ruthenium on TiO₂ (P25) for Effective Photocatalytic N₂ Fixation in Ambient Condition[J]. J. Photochem. Photobiol. A, 2020,387112100. doi: 10.1016/j.jphotochem.2019.112100
8. [8]
  Wu G, Yu L H, Liu Y F, Zhao J M, Han Z, Geng G. One Step Synthesis of N Vacancy-Doped g-C₃N₄/Ag₂CO₃ Heterojunction Catalyst with Outstanding"Two-Path"Photocatalytic N₂ Fixation Ability via In-Situ Self-Sacrificial Method[J]. Appl. Surf. Sci., 2019,481:649-660. doi: 10.1016/j.apsusc.2019.03.112
9. [9]
  Zhang C M, Chen G, Lv C D, Yao Y, Xu Y L, Jin X L, Meng Q Q. Enabling Nitrogen Fixation on Bi₂WO₆ Photocatalyst by c-PAN Surface Decoration[J]. ACS Sustainable Chem. Eng., 2018,6(9):11190-11195. doi: 10.1021/acssuschemeng.8b02236
10. [10]
  Cao S H, Zhou N, Gao F H, Chen H, Jiang F. All-Solid-State Z-Scheme 3, 4-Dihydroxybenzaldehyde-Functionalized Ga₂O₃/Graphitic Carbon Nitride Photocatalyst with Aromatic Rings as Electron Mediators for Visible-Light Photocatalytic Nitrogen Fixation[J]. Appl. Catal. B, 2017,218:600-610. doi: 10.1016/j.apcatb.2017.07.013
11. [11]
  Wang S Y, Hai X, Ding X, Chang K, Xiang Y G, Meng X G, Yang Z X, Chen H, Ye J H. Light-Switchable Oxygen Vacancies in Ultrafine Bi₅O₇Br Nanotubes for Boosting Solar-Driven Nitrogen Fixation in Pure Water[J]. Adv. Mater., 2017,29(31)1701774. doi: 10.1002/adma.201701774
12. [12]
  Li H, Shang J, Ai Z H, Zhang L Z. Efficient Visible Light Nitrogen Fixation with BiOBr Nanosheets of Oxygen Vacancies on the Exposed {001} Facets[J]. J. Am. Chem. Soc., 2015,137(19):6393-6399. doi: 10.1021/jacs.5b03105
13. [13]
  Li J, Sun S Y, Qian C X, He L, Chen K K, Zhang T Q, Chen Z L, Ye M M. The Role of Adsorption in Photocatalytic Degradation of Ibuprofen under Visible Light Irradiation by BiOBr Microspheres[J]. Chem. Eng. J., 2016,297:139-147. doi: 10.1016/j.cej.2016.03.145
14. [14]
  Gao X Y, Tang G B, Peng W, Guo Q, Luo Y M. Surprise in the Phosphate Modification of BiOCl with Oxygen Vacancy: In Situ Construction of Hierarchical Z-Scheme BiOCl-OV-BiPO₄ Photocatalyst for the Degradation of Carbamazepine[J]. Chem. Eng. J., 2019,360:1320-1329. doi: 10.1016/j.cej.2018.10.216
15. [15]
  Gao M C, Yang J X, Sun T, Zhang Z Z, Zhang D F, Huang H J, Lin H X, Fang Y, Wang X X. Persian Buttercup-like BiOBr_xCl_1-x Solid Solution for Photocatalytic Overall CO₂ Reduction to CO and O₂[J]. Appl. Catal. B, 2019,243:734-740. doi: 10.1016/j.apcatb.2018.11.020
16. [16]
  Gao M C, Zhang D F, Pu X P, Li H, Lv D D, Zhang B B, Shao X. Facile Hydrothermal Synthesis of Bi/BiOBr Composites with Enhanced Visible-Light Photocatalytic Activities for the Degradation of Rhodamine B[J]. Sep. Purif. Technol., 2015,154:211-216. doi: 10.1016/j.seppur.2015.09.063
17. [17]
  Zhang L, Wang W Z, Jiang D, Gao E P, Sun S M. Photoreduction of CO₂ on BiOCl Nanoplates with the Assistance of Photoinduced Oxygen Vacancies[J]. Nano Res., 2015,8(3):821-831. doi: 10.1007/s12274-014-0564-2
18. [18]
  Wang J L, Yu Y, Zhang L Z. Highly Efficient Photocatalytic Removal of Sodium Pentachlorophenate with Bi₃O₄Br under Visible Light[J]. Appl. Catal. B, 2013,136-137:112-121. doi: 10.1016/j.apcatb.2013.02.009
19. [19]
  Di J, Song P, Zhu C, Chen C, Xiong J, Duan M, Long R, Zhou W Q, Xu M Z, Kang L X, Lin B, Liu D B, Chen S M, Liu C T, Li H M, Zhao Y L, Li S Z, Yan Q Y, Song L, Liu Z. Strain-Engineering of Bi₁₂O₁₇Br₂ Nanotubes for Boosting Photocatalytic CO₂ Reduction[J]. ACS Mater. Lett., 2020,2(8):1025-1032. doi: 10.1021/acsmaterialslett.0c00306
20. [20]
  Meng C X, Wang B, Ji M X, Jiang Q, Chen R, Ji S N, Chen Z G, Li H M, Xia J X. One-Step Mechanical Synthesis of Oxygen-Defect Modified Ultrathin Bi₁₂O₁₇Br₂ Nanosheets for Boosting Photocatalytic Activity[J]. ChemistrySelect, 2020,5(36):11177-11184. doi: 10.1002/slct.202003267
21. [21]
  Li R, Liu J X, Duo F F, Zhang C M, Wang Y W, Wang Y F, Zhang X C, Fan C M. Facile Hydrolysis Synthesis of Novel Bi₁₂O₁₇Br₂ Photocatalyst with Superior Reduction Ability and Photocatalytic Activity[J]. Mater. Lett., 2018,224:5-8. doi: 10.1016/j.matlet.2018.04.057
22. [22]
  Li K L, Lee W W, Lu C S, Dai Y M, Chou S Y, Chen H L, Lin H P, Chen C C. Synthesis of BiOBr, Bi₃O₄Br, and Bi₁₂O₁₇Br₂ by Controlled Hydrothermal Method and Their Photocatalytic Properties[J]. J. Taiwan Inst. Chem. Eng., 2014,45(5):2688-2697. doi: 10.1016/j.jtice.2014.04.001
23. [23]
  Zeng L, Zhe F, Wang Y, Zhang Q L, Zhao X Y, Hu X, Wu Y, He Y M. Preparation of Interstitial Carbon Doped BiOI for Enhanced Performance in Photocatalytic Nitrogen Fixation and Methyl Orange Degradation[J]. J. Colloid Interface Sci., 2019,539:563-574. doi: 10.1016/j.jcis.2018.12.101
24. [24]
  Dai Y T, Ren P J, Li Y R, Lv D D, Shen Y B, Li Y W, Niemants-verdriet H, Besenbacher F, Xiang H W, Hao W C, Lock N, Wen X D, Lewis J P, Su R. Solid Base Bi₂₄O₃₁Br₁₀(OH)_δ with Active Lattice Oxygen for the Efficient Photo-Oxidation of Primary Alcohols to Aldehydes[J]. Angew. Chem. Int. Ed., 2019,539:563-574.
25. [25]
  Kong X Y, Ng B J, Tan K H, Chen X F, Wang H T, Mohamed A R, Chai S P. Simultaneous Generation of Oxygen Vacancies on Ultrathin BiOBr Nanosheets during Visible-Light-Driven CO₂ Photoreduction Evoked Superior Activity and Long-Term Stability[J]. Catal. Today, 2018,314:20-27. doi: 10.1016/j.cattod.2018.04.018
26. [26]
  Li H, Shang J, Zhu H J, Yang Z P, Ai Z H, Zhang L Z. Oxygen Vacancy Structure Associated Photocatalytic Water Oxidation of BiOCl[J]. ACS Catal., 2016,6(12):8276-8285. doi: 10.1021/acscatal.6b02613
27. [27]
  Ning S B, Lin H X, Tong Y C, Zhang X Y, Lin Q Y, Zhang Y Q, Long J L, Wang X X. Dual Couples Bi Metal Depositing and Ag@AgI Islanding on BiOI 3D Architectures for Synergistic Bactericidal Mechanism of E. coli under Visible Light[J]. Appl. Catal. B, 2017,204:1-10. doi: 10.1016/j.apcatb.2016.11.006
1. [1]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
2. [2]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
3. [3]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
4. [4]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
5. [5]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
6. [6]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
7. [7]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
8. [8]
  Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi₂Sn₂O₇ quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131
9. [9]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
10. [10]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
11. [11]
  Tianbo Jia , Lili Wang , Zhouhao Zhu , Baikang Zhu , Yingtang Zhou , Guoxing Zhu , Mingshan Zhu , Hengcong Tao . Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO₂ reduction products. Chinese Chemical Letters, 2024, 35(5): 108692-. doi: 10.1016/j.cclet.2023.108692
12. [12]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
13. [13]
  Luyan Shi , Ke Zhu , Yuting Yang , Qinrui Liang , Qimin Peng , Shuqing Zhou , Tayirjan Taylor Isimjan , Xiulin Yang . Phytic acid-derivative Co₂B-CoPO_x coralloidal structure with delicate boron vacancy for enhanced hydrogen generation from sodium borohydride. Chinese Chemical Letters, 2024, 35(4): 109222-. doi: 10.1016/j.cclet.2023.109222
14. [14]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
15. [15]
  Ying Hou , Zhen Liu , Xiaoyan Liu , Zhiwei Sun , Zenan Wang , Hong Liu , Weijia Zhou . Laser constructed vacancy-rich TiO_2-x/Ti microfiber via enhanced interfacial charge transfer for operando extraction-SERS sensing. Chinese Chemical Letters, 2024, 35(9): 109634-. doi: 10.1016/j.cclet.2024.109634
16. [16]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
17. [17]
  Ting-Ting Huang , Jin-Fa Chen , Juan Liu , Tai-Bao Wei , Hong Yao , Bingbing Shi , Qi Lin . A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect. Chinese Chemical Letters, 2024, 35(7): 109281-. doi: 10.1016/j.cclet.2023.109281
18. [18]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
19. [19]
  Jing Wang , Zenghui Li , Xiaoyang Liu , Bochao Su , Honghong Gong , Chao Feng , Guoping Li , Gang He , Bin Rao . Fine-tuning redox ability of arylene-bridged bis(benzimidazolium) for electrochromism and visible-light photocatalysis. Chinese Chemical Letters, 2024, 35(9): 109473-. doi: 10.1016/j.cclet.2023.109473
20. [20]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(759)
HTML views(223)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication of Bi12O17Br2 with Efficient Photocatalytic N2 Fixation Boosted by Photoinduced Oxygen Vacancies

Metrics

通讯作者: 陈斌, bchen63@163.com

Fabrication of Bi₁₂O₁₇Br₂ with Efficient Photocatalytic N₂ Fixation Boosted by Photoinduced Oxygen Vacancies