Citation: Mei-Yin WANG, Yuan-Hang REN, Chun-Bo JIA, Xiang LI, Lin YE, Bin YUE, He-Yong HE. Preparation and Characterization of Mesoporous Cs₃PMo₁₂O₄₀ Employed for Catalytic Epimerization Reaction of Aldoses[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 304-312. doi: 10.11862/CJIC.2022.037 shu

Preparation and Characterization of Mesoporous Cs₃PMo₁₂O₄₀ Employed for Catalytic Epimerization Reaction of Aldoses

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200438, China

Corresponding author: Bin YUE, yuebin@fudan.edu.cn He-Yong HE, heyonghe@fudan.edu.cn
Received Date: 24 August 2021
Revised Date: 20 December 2021

Figures(11)

Keggin-type mesoporous Cs₃PMo₁₂O₄₀ (m-Cs₃PMo) has been prepared by using H₃PMo₁₂O₄₀ and CsCl as starting materials and amphiphilic triblock copolymer F127 as a template. The composition, structure, and morphology were characterized by powder X-ray diffraction (XRD), FT-IR, field emission scanning electron microscopy (FESEM), transmission electron microscope (TEM), N₂ adsorption-desorption test, and small-angle X-ray scattering (SAXS). The results show that m-Cs₃ PMo belongs to the cubic lattice system and owns 2.5 and 6.0 nm wormlike mesoporous pores. The catalytic activity of m-Cs₃PMo in aqueous epimerization of D-glucose, D-xylose, and L-arabinose was investigated. The effects of temperature, time, and catalyst amount on the D-glucose epimerization reaction and the recycling performance of the catalyst were also studied. During the recycling process, the catalyst activity and product selectivity did not decrease significantly, which showed good stability of m-Cs₃PMo.
- mesoporous materials,
- polyoxometalates,
- heterogeneous catalysis,
- aldose epimerization
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Preparation and Characterization of Mesoporous Cs3PMo12O40 Employed for Catalytic Epimerization Reaction of Aldoses

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Preparation and Characterization of Mesoporous Cs₃PMo₁₂O₄₀ Employed for Catalytic Epimerization Reaction of Aldoses