Cycloruthenated Complex Based on 3-Ethyl-1-(thiophen-2-yl)imidazolium: Synthesis and Recognizing Hg2+
- Corresponding author: Xiang-Hong LI, lixhchem@mail.scuec.edu.cn
Citation: Ce XU, Kang DU, Lin TAN, Xiang-Hong LI, Bing-Guang ZHANG, Ding-Guo TANG. Cycloruthenated Complex Based on 3-Ethyl-1-(thiophen-2-yl)imidazolium: Synthesis and Recognizing Hg2+[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 220-226. doi: 10.11862/CJIC.2022.036
Constable E C. Cyclometallated Complexes Incorporating a Heterocyclic Donor Atom; The Interface of Coordination Chemistry and Organometallic Chemistry[J]. Polyhedron, 1984,3(9/10):1037-1057.
Djukic J P, Sortais J B, Barloy L, Pfeffer M. Cycloruthenated Compounds-Synthesis and Applications[J]. Eur. J. Inorg. Chem., 2009(7):817-853.
Muro-Small M L, Yarnell J E, McCusker C E, Castellano F N. Spectroscopy and Photophysics in Cyclometalated RuⅡ-Bis(bipyridyl) Complexes[J]. Eur. J. Inorg. Chem., 2012,2012(25):4004-4011. doi: 10.1002/ejic.201200460
Reveco P, Cherry W R, Medley J, Garber A, Gale R J, Selbin J. Cyclometalated Complexes of Ruthenium. 3. Spectral, Electrochemical and Two-Dimensional Proton NMR of[Ru(bpy)2(cyclometalating ligand)]+[J]. Inorg. Chem., 1986,25(11):1842-1845. doi: 10.1021/ic00231a025
Bessho T, Yoneda E, Yum J H, Guglielmi M, Tavernelli I, Imai H, Rothlisberger U, Nazeeruddin M K, Grätzel M. New Paradigm in Molecular Engineering of Sensitizers for Solar Cell Applications[J]. J. Am. Chem. Soc., 2009,131(16):5930-5934. doi: 10.1021/ja9002684
Bomben P G, Robson K C D, Koivisto B D, Berlinguette C P. Cyclometalated Ruthenium Chromophores for the Dye-Sensitized Solar Cell[J]. Coord. Chem. Rev., 2012,256(15/16):1438-1450.
Huang J F, Liu J M, Su P Y, Chen Y F, Shen Y, Xiao L M, Kuang D B, Su C Y. Highly Efficient and Stable Cyclometalated Ruthenium Complexes as Sensitizers for Dye-Sensitized Solar Cells[J]. Electrochim. Acta, 2015,174:494-501. doi: 10.1016/j.electacta.2015.06.023
Nguyen T D, Lan Y P, Wu C G. High-Efficiency Cycloruthenated Sensitizers for Dye-Sensitized Solar Cells[J]. Inorg. Chem., 2018,57(3):1527-1534. doi: 10.1021/acs.inorgchem.7b02862
Li Z J, Yao C J, Zhong Y W. Near-Infrared Electrochromism of Multilayer Films of a Cyclometalated Diruthenium Complex Prepared by Layer-by-Layer Deposition on Metal Oxide Substrates[J]. Sci. China: Chem., 2019,62(12):1675-1685. doi: 10.1007/s11426-019-9640-1
YAO C J, ZHONG Y W. Near Infrared Electrical Discoloration Based on Mixed Price Double Ruthenium Complex[J]. Chin. Sci. Bull., 2014,59(17):1591-1602.
Lv Z, Wei H J, Li Q, Su X L, Liu S J, Zhang K Y, Huang , Lv W, Zhao Q, Li X H, Huang W. Achieving Efficient Photodynamic Therapy under both Normoxia and Hypoxia Using Cyclometalated Ru Photosensitizer through Type Ⅰ Photochemical Process[J]. Chem. Sci., 2018,9(2):502-512. doi: 10.1039/C7SC03765A
Huang H Y, Zhang P Y, Yu B L, Chen Y, Wang J Q, Ji L N, Chao H. Targeting Nucleus DNA with a Cyclometalated Dipyridophenazineruthenium Complex[J]. J. Med. Chem., 2014,57(21):8971-8983. doi: 10.1021/jm501095r
Wade C R, Gabbaï F P. Cyanide Anion Binding by a Triarylborane at the Outer Rim of a Cyclometalated Ruthenium Cationic Complex[J]. Inorg. Chem., 2010,49(2):714-720. doi: 10.1021/ic9020349
Cheng X J, Li J P, Li X H, Zhang D H, Zhang H J, Zhang A Q, Huang H, Lian J S. A Highly Sensitive Sensor Based on Hollow Particles for the Detection, Adsorption and Removal of Hg2+ Ions[J]. J. Mater. Chem., 2012,22(45):24102-24108. doi: 10.1039/c2jm35427f
Lo H S, Lo K W, Yeung C F, Wong C Y. Rapid Visual and Spectrophotometric Nitrite Detection by Cyclometalated Ruthenium Complex[J]. Anal. Chim. Acta, 2017,990:135-140. doi: 10.1016/j.aca.2017.07.018
Xie X K, Huynh H V. Cyclometallated Ruthenium Complexes with Ditopic Thienyl-NHC Ligands: Syntheses and Alkyne Annulations[J]. Org. Chem. Front., 2015,2(12):1598-1603. doi: 10.1039/C5QO00292C
Reveco P, Schmehl R H, Cherry W R, Fronczek F R, Selbin J. Cyclometalated Complexes of Ruthenium. 2. Spectral and Electrochemical Properties and X-ray Structure of Bis(2, 2'-bipyridine)(4-nitro-2-(2-pyridyl)phenyl)ruthenium[J]. Inorg. Chem., 1985,24(24):4078-4082. doi: 10.1021/ic00218a023
Su X L, Zeng R Q, Li X H, Dang W J, Yao K Y, Tang D G. Cycloruthenated Complexes: pH-Dependent Reversible Cyclometallation and Reactions with Nitrite at Octahedral Ruthenium Centers[J]. Dalton Trans., 2016,45(17):7450-7459. doi: 10.1039/C6DT00576D
Zhao Q, Cao T Y, Li F Y, Li X H, Jing H, Yi T, Huang C H. A Highly Selective and Multisignaling Optical-Electrochemical Sensor for Hg2+ Based on a Phosphorescent Iridium Complex[J]. Organometallics, 2007,26(8):2077-2081. doi: 10.1021/om061031r
Wu Y Q, Jing H, Dong Z S, Zhao Q, Wu H Z, Li F Y. Ratiometric Phosphorescence Imaging of Hg in Living Cells Based on a Neu-tral Iridium Complex[J]. Inorg. Chem., 2011,50(16):7412-7420. doi: 10.1021/ic102082k
Constable E C, Dunne S J, Rees D G F, Schmitt C X. Reversible Cyclometallation at a Ruthenium Centre[J]. Chem. Commun., 1996,10:1169-1170.
Moorlag C, Clot O, Wolf M O, Patrick B O. Switchable Thiophene Coordination in Ru Bipyridyl Phosphinoterthiophene Complexes[J]. Chem. Commun., 2002,24:3028-3029.
Moorlag C, Wolf M O, Bohne C, Patrick B O. Reversible Molecular Switching of Ruthenium Bis(bipyridyl) Groups Bonded to Oligothiophenes: Effect on Electrochemical and Spectroscopic Properties[J]. J. Am. Chem. Soc., 2005,127(17):6382-6393. doi: 10.1021/ja043573a
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO4 photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
VCH3CN∶VHEPES=2∶1, c1=20 µmol·L-1
VCH3CN∶VHEPES=2∶1, c1=20 µmol·L-1
VCH3CN∶VHEPES=2∶1, pH=6.98, c1=20 µmol·L-1; Each UV-Vis spectrum was measured after adding Hg2+ for 3 min; Inset: linear correlation curve of ΔA546 nm of complex 1 with Hg2+ concentration
VCH3CN∶VHEPES=2∶1, pH=7.00, c1=20 µmol·L-1
c1+cHg2+=40 µmol·L-1
VCH3CN∶VHEPES=2∶1, c1=20 µmol·L-1; Inset: MS spectrum of complex 1 at pH 6.98 in the presence of Hg2+