Citation: Peng-Fei HAO, Xing LIU, Yun-Long FU. Metal-Modulated Photochromic Properties of 2, 4, 6-Tri(2-pyridyl)-1, 3, 5-triazine Based Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(2): 198-210. doi: 10.11862/CJIC.2022.033 shu

Metal-Modulated Photochromic Properties of 2, 4, 6-Tri(2-pyridyl)-1, 3, 5-triazine Based Complexes

Key Laboratory of Magnetic Molecules & Magnetic Information, Materials Ministry of Education, School of Chemical and Material Science, Shanxi Normal University, Taiyuan 030006, China

Corresponding author: Peng-Fei HAO, haopengfei_2015@126.com Yun-Long FU, yunlongfu@sxnu.edu.cn
Received Date: 17 August 2021
Revised Date: 1 December 2021

Figures(12)

Three 2-TPT-based complexes composed of donor-acceptor units, [Zn(2-TPT)(2, 5-FCA)] (1), [Cd(2-TPT) (2, 5-FCA)]·1.5H₂O (2), and[Mn(2-TPT)(2, 5-FCA)] (3), have been synthesized by the combination of 2, 4, 6-tri(2-pyridyl)-1, 3, 5-triazine (2-TPT) and 2, 5-furandicarboxylic acid (2, 5-H₂FCA) with different types of metallic nitrates (Zn, Cd, and Mn), respectively. The structures and photochromic properties of 1-3 have been characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR, UV-Vis, thermogravimetry-differential thermal analysis, electron paramagnetic resonance and X-ray photoelectron spectroscopy. The usage of different metals leads to a 1D single-strand chain for 1 and a double-strand chain for 2 and 3, which are further aggregated into distinct supramolecular frameworks (three-dimensional supramolecular network for 1, two-dimensional supramolecular layer for 2, and discrete chain for 3) through weak interactions. Complexes 1-3 exhibited significantly different photoinduced intermolecular electron transfer (PIET) and photochromic properties, which were mainly reflect in photoresponsive rate and coloration contrast. Thereinto, the photochromic performance of 1 was obviously better than that of 2, while 3 was non-photochromic. These obviously discriminative photochromic behaviors are largely attributed to the different packing modes of crystal structures and the discriminative relative position of electron donors/acceptors caused by different types and coordination patterns of the metal centers, which exhibit the modulating effect of metal centers on the photochromic properties.
- 2, 4, 6-tri(2-pyridyl)-1, 3, 5-triazine,
- complexes,
- photochromism,
- electron transfer
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