Citation: Yong-Lan FENG, Ying WANG, Wu-Jiu JIANG, Jiang-Xi YU, Fu-Xing ZHANG, Dai-Zhi KUANG. Synthesis, Structure and Fluorescence Properties of Bis(3-ethoxysalicylaldehyde) 1, 3-Benzyldiacyl Hydrazone Tetrabutyl(phenyl)ditin[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(1): 103-110. doi: 10.11862/CJIC.2022.026 shu

Synthesis, Structure and Fluorescence Properties of Bis(3-ethoxysalicylaldehyde) 1, 3-Benzyldiacyl Hydrazone Tetrabutyl(phenyl)ditin

Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Key Laboratory of Functional Organometallic Materials, University of Hunan Province, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: Dai-Zhi KUANG, hnkcq@qq.com
Received Date: 15 July 2021
Revised Date: 21 October 2021

Figures(4)

The bis(3-ethoxysalicylaldehyde) 1, 3-benzyldiacyl hydrazone (H₄L) ligand was prepared by the reaction of 3-ethoxysalicylaldehyde with benzene-1, 3-dicarbohydrazide in ethanol solution. Bis(3-ethoxysalicylaldehyde) 1, 3benzyldiacyl hydrazone tetrabutyl(phenyl)ditin, Bu₄Sn₂L (T1) and Ph₄Sn₂L (T2), were synthesized by solvothermal reaction of H₄L with dibutyltin oxide and triphenyltin hydroxide in methanol, respectively. The structures of ligand and complexes were characterized by elemental analysis, IR, UV-Vis spectroscopy, NMR, and single-crystal X-ray diffraction. The molecular formula of H₄L is C₂₆H₂₆N₄O₆. The crystal of H₄L belongs to the monoclinic system and space group C2/c. Two formylhydrazide (3-ethoxy)salicylaldehydes are cis-symmetric configuration. The molecular formula of T1 is C₄₂H₅₈N₄O₆Sn₂. The crystal of T1 belongs to the orthorhombic system and space group Pbcn. The two formylhydrazide (3-ethoxy)salicylaldehyde chains of H₄L turn inward 180°, and a distorted trigonal bipyramid is formed by the coordination of coordinating atoms with tin. The molecular structure is axis-symmetric about C2…C4. The molecular formula of T2 is C₅₀H₄₂N₄O₆Sn₂. The crystal of T2 belongs to the triclinic system, space group P1. One formylhydrazide (3-ethoxy)salicylaldehyde of H₄L keeps the original configuration, and the other formylhydrazide (3-ethoxy)salicylaldehyde turns inward 180°. Two coordination chains with different configuration orientations were formed, which coordinated with diphenyltin to form a binuclear trans-asymmetric distorted trigonal bipyramid complexes. The fluorescence properties of trichloromethane solutions of H₄L, T1, T2 (50 μmol·L^-1) were tested. The results showed that H₄L had weak fluorescence at 520 nm, and T1 and T2 had 14-15 times stronger fluorescence emission peaks than the ligand at 518 nm.
- bis(3-ethoxysalicylaldehyde) 1, 3-benzyldiacyl hydrazone,
- organotin complex,
- solvothermal synthesis,
- crystal structure,
- fluorescence properties
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