Citation: Deng-Kui XIE, Ai-Ling FAN, Wei PANG, Ya-Qi GUO, Dian-Chao GAO. Flocculent Ternary Nickel-Cobalt-Iron Hydroxide Electrode Material: Preparation and Performance for Electrochemical Energy Storage[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(1): 31-38. doi: 10.11862/CJIC.2022.024 shu

Flocculent Ternary Nickel-Cobalt-Iron Hydroxide Electrode Material: Preparation and Performance for Electrochemical Energy Storage

Department of Materials and Manufacturing, Beijing University of Technology, Key Laboratory of Advanced Functional Materials, Ministry of Education, Beijing 100124, China

Corresponding author: Ai-Ling FAN, fanailing@bjut.edu.cn
Received Date: 14 May 2021
Revised Date: 28 November 2021

Figures(6)

Three electrode materials of nickel - cobalt hydroxide, nickel - iron hydroxide, and nickel - cobalt - iron hydroxide were synthesized on nickel foam (NF) via a one - step solvothermal method. The electrochemical tests showed that the ternary nickel-cobalt-iron metal electrode with the best energy storage performance outperforms the other two binary metal electrodes, and it could reach an area capacitance of 5.11 F·cm^-2 at a current density of 2 mA·cm^-2. To further investigate the practical application, an asymmetric supercapacitor was assembled with NiCoFeOH/NF as the positive electrode and activated carbon as the negative electrode, respectively, and the device achieved a maximum energy density of 5.994 Wh·m^-2 at a power density of 46.814 W·m^-2. The results show that the excellent performance of NiCoFe - OH/NF can be attributed to loosen flocculent structure, which provides larger specific surface area per unit volume and subsequently store more electric charges, as well as facilitate electron/ion transportation, reduce the contact resistance between active material and electrolyte, and increase the electrical conductivity.
- solvothermal method,
- nickel-cobalt-iron,
- ternary metal electrode,
- supercapacitor,
- energy storage performance
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