Citation: Lan YANG, Xin XIA, Dong-Huang WANG, Ai-Jun ZHOU. Co-precipitation Reaction Control of FeFe-Based Prussian Blue Cathode Material for Sodium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(1): 111-118. doi: 10.11862/CJIC.2022.020 shu

Co-precipitation Reaction Control of FeFe-Based Prussian Blue Cathode Material for Sodium-Ion Batteries

Lan YANG ¹ ,
Xin XIA ^1,, ,
Dong-Huang WANG ² ,
Ai-Jun ZHOU ^{2, 3,,}

1.
College of Textile and Clothing, Xinjiang University, Urumqi 830046, China
2.
Yangtze Delta Region Institute(Huzhou), University of Electronic Science and Technology of China, Huzhou, Zhejiang 313001, China
3.
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, China

Corresponding author: Xin XIA, xjxiaxin@163.com Ai-Jun ZHOU, zhouaj@uestc.edu.cn
Received Date: 31 July 2021
Revised Date: 20 November 2021

Figures(5)

FeFe-based Prussian blue (NaFeHCF) is a promising cathode material for sodium-ion batteries (SIBs). However, how to effectively control the synthesis parameters to improve the cycling stability of NaFeHCF in sodiumion batteries remains to be addressed. In this work, NaFeHCF powders were prepared through the co-precipitation method, and the synergetic effects of a complexing agent (with or without sodium citrate) and reaction temperature (0-80 ℃) on the physical and electrochemical properties of NaFeHCF were investigated in detail. The results showed that NaFeHCF powders synthesized with the addition of a complexing agent and at a temperature slightly above room temperature (40 ℃) exhibited the most appropriate properties in terms of morphology, grain size, and crystallinity. Therefore, the SIB cathode using this material showed the highest cycling stability, being able to deliver a discharge capacity of 83.5 mAh·g^-1 after 1 500 cycles at the current density of 120 mA·g^-1 with capacity retention of 79.4%.
- sodium-ion battery,
- cathode material,
- Prussian blue,
- complexing agent,
- reaction temperature
1. [1]
  Cai P, Zou K Y, Deng X L, Wang B W, Zheng M, Li L H, Hou H S, Zou G Q, Ji X B. Comprehensive Understanding of Sodium-Ion Capacitors: Definition, Mechanisms, Configurations, Materials, Key Technologies, and Future Developments[J]. Adv. Energy Mater., 2021,11(16)2003804. doi: 10.1002/aenm.202003804
2. [2]
  Nayak P K, Yang L T, Brehm W, Adelhelm P. From Lithium-Ion to Sodium-Ion Batteries: Advantages, Challenges, and Surprises[J]. Angew. Chem. Int. Ed., 2018,57(1):102-120. doi: 10.1002/anie.201703772
3. [3]
  Wang T Y, Su D W, Shanmukaraj D, Rojo T, Armand M, Wang G X. Electrode Materials for Sodium-Ion Batteries: Considerations on Crystal Structures and Sodium Storage Mechanisms[J]. Electrochem. Energy Rev., 2018,1(2):200-237. doi: 10.1007/s41918-018-0009-9
4. [4]
  Xiao J, Li X, Tang K K, Wang D D, Long M Q, Gao H, Chen W H, Liu C T, Liu H, Wang G X. Recent Progress of Emerging Cathode Materials for Sodium Ion Batteries[J]. Mater. Chem. Front., 2021,5(10):3735-3764. doi: 10.1039/D1QM00179E
5. [5]
  Li S F, Gu Z Y, Guo J Z, Hou X K, Yang X, Zhao B, Wu X L. Enhanced Electrode Kinetics and Electrochemical Properties of Low-Cost NaFe₂PO₄(SO₄)₂ via Ca²⁺ Doping as Cathode Material for Sodium-Ion Batteries[J]. J. Mater. Sci. Technol., 2021,78:176-182. doi: 10.1016/j.jmst.2020.10.047
6. [6]
  Gu Z Y, Guo J Z, Zhao X X, Wang X T, Xie D, Sun Z H, Zhao C D, Liang H J, Li W H, Wu X L. High-Ionicity Fluorophosphate Lattice via Aliovalent Substitution as Advanced Cathode Materials in Sodium- Ion Batteries[J]. InfoMat, 2021,3(6):694-704. doi: 10.1002/inf2.12184
7. [7]
  Wu H Y, Zou X, Wu X L. Nanoconstruction and Nanoeffect of Phos- phate-Based Cathode Materials for Advanced Sodium-Ion Batteries[J]. Nano Futures, 2020,4(4)042001. doi: 10.1088/2399-1984/abc103
8. [8]
  ZHANG H X, LI S F, ZHAO B, HOU X K, WU X L. Research Pro- gresses on Iron-Based Cathode Materials for Sodium-Ion Bat[J]. Chinese J. Inorg. Chem., 2020,36(7):1205-1222.
9. [9]
  Zhou A J, Cheng W J, Wang W, Zhao Q, Xie J, Zhang W X, Gao H C, Xue L G, Li J Z. Hexacyanoferrate-Type Prussian Blue Analogs: Principles and Advances Toward High-Performance Sodium and Potassium Ion Batteries[J]. Adv. Energy Mater., 2021,11(2)2000943. doi: 10.1002/aenm.202000943
10. [10]
  Qian J F, Wu C, Cao Y L, Ma Z F, Huang Y H, Ai X P, Yang H X. Prussian Blue Cathode Materials for Sodium-Ion Batteries and Other Ion Batteries[J]. Adv. Energy Mater., 2018,8(17)1702619. doi: 10.1002/aenm.201702619
11. [11]
  Ma F, Li Q, Wang T Y, Zhang H G, Wu G. Energy storage Materials Derived from Prussian Blue Analogues[J]. Sci. Bull., 2017,62(2095/ 9273)358.
12. [12]
  Chen J S, Wei L, Mahmood A, Pei Z X, Zhou Z, Chen X C, Chen Y. Prussian Blue, Its Analogues and Their Derived Materials for Elec-trochemical Energy Storage and Conversion[J]. Energy Storage Mater., 2020,25:585-612. doi: 10.1016/j.ensm.2019.09.024
13. [13]
  Wu X Y, Luo Y, Sun M Y, Qian J F, Cao Y L, Ai X P, Yang H X. Low-Defect Prussian Blue Nanocubes as High Capacity and Long Life Cathodes for Aqueous Na-Ion Batteries[J]. Nano Energy, 2015,13:117-123. doi: 10.1016/j.nanoen.2015.02.006
14. [14]
  Liu Y, Qiao Y, Zhang W X, Li Z, Ji X, Miao L, Yuan L X, Hu X L, Huang Y H. Sodium Storage in Na-Rich NaxFeFe(CN)(6) Nanocubes[J]. Nano Energy, 2015,12:386-393. doi: 10.1016/j.nanoen.2015.01.012
15. [15]
  You Y, Wu X L, Yin Y X, Guo Y G. High-Quality Prussian Blue Crystals as Superior Cathode Materials for Room-Temperature Sodium-Ion Batteries[J]. Energy Environ. Sci., 2014,7(5):1643-1647. doi: 10.1039/C3EE44004D
16. [16]
  You Y, Yu X Q, Yin Y X, Nam K W, Guo Y G. Sodium Iron Hexacyanoferrate with High Na Content as a Na -Rich Cathode Material for Na-Ion Batteries[J]. Nano Res., 2015,8(1):117-128. doi: 10.1007/s12274-014-0588-7
17. [17]
  Yang Y, Liu E S, Yan X M, Ma C R, Wen W, Liao X Z, Ma Z F. Influence of Structural Imperfection on Electrochemical Behavior of Prussian Blue Cathode Materials for Sodium Ion Batteries[J]. J. Electrochem. Soc., 2016,163(9):A2117-A2123. doi: 10.1149/2.0031610jes
18. [18]
  Yan X M, Yang Y, Liu E S, Sun L Q, Wang H, Liao X Z, He Y S, Ma Z F. Improved Cycling Performance of Prussian Blue Cathode for Sodium Ion Batteries by Controlling Operation Voltage Range[J]. Electrochim. Acta, 2017,225:235-242. doi: 10.1016/j.electacta.2016.12.121
19. [19]
  Chen R J, Huang Y X, Xie M, Zhang Q Y, Zhang X X, Li L, Wu F. Preparation of Prussian Blue Submicron Particles with a Pore Structure by Two-Step Optimization for Na-Ion Battery Cathodes[J]. ACS Appl. Mater. Interfaces, 2016,8(25):16078-16086. doi: 10.1021/acsami.6b04151
20. [20]
  Huang Y X, Xie M, Zhang J T, Wang Z H, Jiang Y, Xiao G H, Li S J, Li L, Wu F, Chen R J. A Novel Border-Rich Prussian Blue Synthe- tized by Inhibitor Control as Cathode For Sodium Ion Batteries[J]. Nano Energy, 2017,39:273-283. doi: 10.1016/j.nanoen.2017.07.005
21. [21]
  Kim D S, Yoo H D, Park M S, Kim H S. Boosting the Sodium Storage Capability of Prussian Blue Nanocubes by Overlaying PEDOT: PSS Layer[J]. J. Alloys Compd., 2019,791:385-390. doi: 10.1016/j.jallcom.2019.03.317
22. [22]
  Wang W L, Gang Y, Hu Z, Yan Z C, Li W J, Li Y C, Gu Q F, Wang Z X, Chou S L, Liu H K, Dou S X. Reversible Structural Evolution of Sodium-Rich Rhombohedral Prussian Blue for Sodium-Ion Batteries[J]. Nat. Commun., 2020,11(1)980. doi: 10.1038/s41467-020-14444-4
23. [23]
  Li W J, Chou S L, Wang J Z, Kang Y M, Wang J L, Liu Y, Gu Q F, Liu H K, Dou S X. Facile Method to Synthesize Na-Enriched Na_1+xFeFe(CN)₆ Frameworks as Cathode with Superior Electrochemical Performance for Sodium-Ion Batteries[J]. Chem. Mater., 2015,27(6):1997-2003. doi: 10.1021/cm504091z
24. [24]
  Shen Z L, Guo S H, Liu C L, Sun Y P, Chen Z, Tu J, Liu S Y, Cheng J P, Xie J, Cao G S, Zhao X B. Na-Rich Prussian White Cathodes for Long-Life Sodium-Ion Batteries[J]. ACS Sustainable Chem. Eng., 2018,6(12):16121-16129. doi: 10.1021/acssuschemeng.8b02758
25. [25]
  Yu S H, Shokouhimehr M, Hyeon T, Sung Y E. Iron Hexacyanoferrate Nanoparticles as Cathode Materials for Lithium and Sodium Rechargeable Batteries[J]. ECS Electrochem. Lett., 2013,2(4):A39-A41. doi: 10.1149/2.008304eel
26. [26]
  Wang L, Song J, Qiao R M, Wray L A, Hossain M A, Chuang Y D, Yang W L, Lu Y H, Evans D, Lee J J, Vail S, Zhao X, Nishijima M, Kakimoto S, Goodenough J B. Rhombohedral Prussian White as Cathode for Rechargeable Sodium-Ion Batteries[J]. J. Am. Chem. Soc., 2015,137(7):2548-2554. doi: 10.1021/ja510347s
27. [27]
  Li C, Zhang C, Xie J, Wang K B, Li J Z, Zhang Q C. Ferrocene-Based Metal-Organic Framework as a Promising Cathode in Lithium-Ion Battery[J]. Chem. Eng. J., 2021,404126463. doi: 10.1016/j.cej.2020.126463
28. [28]
  Shen L, Wang Z X, Chen L Q. Prussian Blues as a Cathode Material for Lithium Ion Batteries[J]. Chem. Eur. J., 2014,20(39):12559-12562. doi: 10.1002/chem.201403061
29. [29]
  Chen R J, Huang Y X, Xie M, Wang Z H, Ye Y S, Li L, Wu F. Chemical Inhibition Method to Synthesize Highly Crystalline Prussian Blue Analogs for Sodium-Ion Battery Cathodes[J]. ACS Appl. Mater. Interfaces, 2016,8(46):31669-31676. doi: 10.1021/acsami.6b10884
30. [30]
  Ling C, Chen J J, Mizuno F. First-Principles Study of Alkali and Alkaline Earth Ion Intercalation in Iron Hexacyanoferrate: The Important Role of Ionic Radius[J]. J. Phys. Chem. C, 2013,117(41):21158-21165. doi: 10.1021/jp4078689
31. [31]
  Yan C X, Zhao A L, Zhong F P, Feng X M, Chen W H, Qian J F, Ai X P, Yang H X, Cao Y L. A Low-Defect and Na-Enriched Prussian Blue Lattice with Ultralong Cycle Life for Sodium-Ion Battery Cathode[J]. Electrochim. Acta, 2020,332135533. doi: 10.1016/j.electacta.2019.135533
32. [32]
  ZHUANG Q C, XU S D, QIU X Y, CUI Y L, FANG L, SUN S G. Diagnosis of Electrochemical Impedance Spectroscopy in Lithium Ion Batteries[J]. Progress in Chemistry, 2010,22(6):1044-1057.
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