Citation: Xiang XIA, Sheng WANG, Xing-Qian YANG, Rong FAN, Run-Zhi WEI, Zheng LIU, Qun TANG. Synthesis, Crystal Structure and Properties of Zinc Complex Based on 2, 5-Bis(trifluoromethyl)terephthalic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2133-2140. doi: 10.11862/CJIC.2021.254 shu

Synthesis, Crystal Structure and Properties of Zinc Complex Based on 2, 5-Bis(trifluoromethyl)terephthalic Acid Ligand

Xiang XIA ^{1, #} ,
Sheng WANG ^{2, #} ,
Xing-Qian YANG ¹ ,
Rong FAN ¹ ,
Run-Zhi WEI ² ,
Zheng LIU ^2,, ,
Qun TANG ^2,,

1.
Guizhou Wujiang Hydropower Development Limited Liability Company Silin Power Plant, Tongren, Guizhou 565109, China
2.
College of Chemical and Biological Engineering, Guilin University of Technology, Guangxi Key Laboratory of Electrochemical and Magneto-Chemical Functional Materials, Guilin, Guangxi 541004, China

Corresponding author: Zheng LIU, lisa4.6@163.com Qun TANG, tangq@glut.edu.cn
Received Date: 15 April 2021
Revised Date: 1 September 2021

Figures(5)

Complexes[Zn(L)₂(4, 4'-bipy)(H₂O)]_n (1) and[Zn(L)(2, 2'-bipy)]_n (2) were synthesized by solvothermal reaction of 2, 5-bis(trifluoromethyl) terephthalic acid (H₂L) as main ligand and zinc chloride as metal salt with auxiliary ligands 4, 4'-bipyridine (4, 4'-bipy) and 2, 2'-bipyridine (2, 2'-bipy), respectively. Their structure and properties were characterized by X-ray single crystal diffraction, FT-IR, elemental analysis, thermogravimetric analysis, etc. The results show that complex 1 forms an infinitely extending two-dimensional network structure by the bridging effect of L^2- and 4, 4'-bipy ligands, and the layers are stacked in an orderly manner under the action of O5-H5B…O1 hydrogen bond developing three-dimensional structure. The Zn²⁺ acts as the metal node in complex 2, and each carboxyl group on L^2- bridges zinc ions through bidentate chelation and connects infinitely to form a 3D network structure.
- zinc complexes,
- 2, 5-bis(trifluoromethyl)terephthalic acid,
- bipyridine,
- crystal structure
1. [1]
  Cao K Y, Yu Z X, Yin D, Chen L G, Jiang Y, Zhu L J. Fabrication of BTA-MOF-TEOS-GO Nanocomposite to Endow Coating Systems with Active Inhibition and Durable Anticorrosion Performances[J]. Prog. Org. Coat., 2020,143105629. doi: 10.1016/j.porgcoat.2020.105629
2. [2]
  Wei W C, Liu Z, Liang C X, Han G C, Li Y K, Li Q W, Han J X, Zhang S F. Corrosion Inhibition Performance of Nitrogen-Containing Metal Organic Framework Compounds on Copper Flakes in Dilute HCl Medium[J]. Prot. Met. Phys. Chem., 2020,56(3):638-650. doi: 10.1134/S2070205120030302
3. [3]
  Wei W C, Liu Z, Wei R Z, Han G C, Liang C X. Synthesis of MOFs/GO Composite for Corrosion Resistance Application on Carbon Steel[J]. RSC Adv., 2020,10(50):29923-29934. doi: 10.1039/D0RA05690A
4. [4]
  Ramezanzadeh M, Ramezanzadeh B, Bahlakeh G, Tati A, Mahdavian M. Development of an Active/Barrier Bi-functional Anti-corrosion System Based on the Epoxy Nanocomposite Loaded with Highlycoordinated Functionalized Zirconium-Based Nanoporous Metal-Organic Framework (Zr-MOF)[J]. Chem. Eng. J., 2021,408127361. doi: 10.1016/j.cej.2020.127361
5. [5]
  Seidi F, Jouyandeh M, Taghizadeh M, Taghizadeh A, Vahabi H, Habibzadeh S, Formela K, Saeb M R. Metal-Organic Framework (MOF)/Epoxy Coatings: A Review[J]. Materials, 2020,13(12)2881. doi: 10.3390/ma13122881
6. [6]
  Santos J A O, Mutti A M G, Bispo A G, Pires A M, Lima S A M. Red-Emitting Hybrid Based on Eu³⁺-dbm Complex Anchored on Silica Nanoparticles Surface by Carboxylic Acid for Biomarker Application[J]. Materials, 2020,13(23)5494. doi: 10.3390/ma13235494
7. [7]
  Li M, Hsu Y P, Liu Y H, Peng S M, Liu S T. Iridium Complexes with Ligands of 1, 8-Naphthyridine-2-carboxylic Acid Derivatives-Preparation and Catalysis[J]. J. Organomet. Chem., 2020,927121537. doi: 10.1016/j.jorganchem.2020.121537
8. [8]
  Świderski G, Łyszczek R, Wojtulewski S, Kalinowska M, Świsłocka R, Lewandowski W. Comparison of Structural, Spectroscopic, Theoretical and Thermal Properties of Metal Complexes (Zn (Ⅱ), Mn (Ⅱ), Cu(Ⅱ), Ni(Ⅱ) and Co(Ⅱ)) of Pyridazine-3-carboxylic Acid and Pyridazine-4-carboxylic Acids[J]. Inorg. Chim. Acta, 2020,512119865. doi: 10.1016/j.ica.2020.119865
9. [9]
  Eremina J A, Lider E V, Sukhikh T S, Klyushova L S, Perepechaeva M L, Sheven D G, Berezin A S, Grishanova A Y, Potkin V I. Water-Soluble Copper (Ⅱ) Complexes with 4, 5-Dichloro-isothiazole-3-carboxylic Acid and Heterocyclic N-Donor Ligands: Synthesis, Crystal Structures, Cytotoxicity, and DNA Binding Study[J]. Inorg. Chim. Acta, 2020,510119778. doi: 10.1016/j.ica.2020.119778
10. [10]
  Kadnikova O Y, Kondratenko Y A, Gurzhiy V V, Ugolkov V L, Kochina T A. Synthesis and Structures of Tris(2-hydroxypropyl) amine Complexes with Ni-Ⅱ, Zn-Ⅱ, Cu-Ⅱ, and Co-Ⅱ Salts of Biologically Active Carboxylic Acids[J]. Russ. Chem. Bull., 2020,69(5):958-964. doi: 10.1007/s11172-020-2855-y
11. [11]
  Rosi N L, Kim J, Eddaoudi M, Chen B L, O'Keeffe M, Yaghi O M. Rod Packings and Metal-Organic Frameworks Constructed from Rod-Shaped Secondary Building Units[J]. J. Am. Chem. Soc., 2005,127(5):1504-1518. doi: 10.1021/ja045123o
12. [12]
  Deng H X, Grunder S, Cordova K E, Valente C, Furukawa H, Hmadeh M, Gandara F, Whalley A C, Liu Z, Asahina S, Kazumori H, O'Keeffe M, Terasaki O, Stoddart J F, Yaghi O M. Large-Pore Apertures in a Series of Metal-Organic Frameworks[J]. Science, 2012,336(6084):1018-1023. doi: 10.1126/science.1220131
13. [13]
  Luan F F, Xiao G X, Zhang Y X, Li S Q, Hu Z Q, Du H L, Guo D C. Synthesis, Fluorescence Properties and F-Detection Performance of Eu(Ⅲ) Complexes Based on the Novel Coumarin Schiff Base Derivatives[J]. J. Mol. Liq., 2020,320114439. doi: 10.1016/j.molliq.2020.114439
14. [14]
  Michida W, Nagai A, Sakuragi M, Okobira T, Kusakabe K. Fluorescence Emission Behaviors of the L-Cysteine/Au (Ⅰ) Complex in a Cyclodextrin-Based Metal-Organic Framework[J]. Processes, 2020,8(12)1555. doi: 10.3390/pr8121555
15. [15]
  Li Y J, Bian R N, Li P, Xie K F, Dong W K. Investigation of Supramolecular Assemblies, Hirshfeld Surfaces and DFT Analyses, and Fluorescence Properties of Three Newly Synthesized Multinuclear Co(Ⅱ), Ni(Ⅱ) and Zn(Ⅱ) Complexes[J]. Polyhedron, 2020,192114867. doi: 10.1016/j.poly.2020.114867
16. [16]
  Răducă M, Ene C D, Ionescu S, Florea M, Mădălan A M. Coordination Polymers and a Dinuclear Complex Constructed from Zinc (Ⅱ) Ions and Fluorescein: Iodine Adsorption and Optical Properties[J]. J. Coord. Chem., 2019,72(8):1222-1237. doi: 10.1080/00958972.2019.1605442
17. [17]
  Wang S, Ye B Y, An C W, Wang J G, Li Q B. Synergistic Effects between Cu Metal-Organic Framework (Cu-MOF) and Carbon Nanomaterials for the Catalyzation of the Thermal Decomposition of Ammonium Perchlorate (AP)[J]. J. Mater. Sci., 2019,54(6):4928-4941. doi: 10.1007/s10853-018-03219-4
18. [18]
  XIA Y, ZENG X H, LUO Y S, DI B S, QIU L, HE L H, LIU S J, WEN H R, CHEN J L. Syntheses and Characterizations of Copper(Ⅰ) Bisphosphine Complexes Based on 6-Methoxycarbonyl-2, 2'-bipyridine[J]. Chinese J. Inorg. Chem., 2016,32(11):2012-2016.
19. [19]
  Umadevi D, Sastry G N. Quantum Mechanical Study of Physisorption of Nucleobases on Carbon Materials: Graphene versus Carbon Nanotubes[J]. J. Phys. Chem. Lett., 2011,2(13):1572-1576. doi: 10.1021/jz200705w
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