Citation: Xiang XIA, Sheng WANG, Xing-Qian YANG, Rong FAN, Run-Zhi WEI, Zheng LIU, Qun TANG. Synthesis, Crystal Structure and Properties of Zinc Complex Based on 2, 5-Bis(trifluoromethyl)terephthalic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2133-2140. doi: 10.11862/CJIC.2021.254 shu

Synthesis, Crystal Structure and Properties of Zinc Complex Based on 2, 5-Bis(trifluoromethyl)terephthalic Acid Ligand

Xiang XIA ^{1, #} ,
Sheng WANG ^{2, #} ,
Xing-Qian YANG ¹ ,
Rong FAN ¹ ,
Run-Zhi WEI ² ,
Zheng LIU ^2,, ,
Qun TANG ^2,,

1.
Guizhou Wujiang Hydropower Development Limited Liability Company Silin Power Plant, Tongren, Guizhou 565109, China
2.
College of Chemical and Biological Engineering, Guilin University of Technology, Guangxi Key Laboratory of Electrochemical and Magneto-Chemical Functional Materials, Guilin, Guangxi 541004, China

Corresponding author: Zheng LIU, lisa4.6@163.com Qun TANG, tangq@glut.edu.cn
Received Date: 15 April 2021
Revised Date: 1 September 2021

Figures(5)

Complexes[Zn(L)₂(4, 4'-bipy)(H₂O)]_n (1) and[Zn(L)(2, 2'-bipy)]_n (2) were synthesized by solvothermal reaction of 2, 5-bis(trifluoromethyl) terephthalic acid (H₂L) as main ligand and zinc chloride as metal salt with auxiliary ligands 4, 4'-bipyridine (4, 4'-bipy) and 2, 2'-bipyridine (2, 2'-bipy), respectively. Their structure and properties were characterized by X-ray single crystal diffraction, FT-IR, elemental analysis, thermogravimetric analysis, etc. The results show that complex 1 forms an infinitely extending two-dimensional network structure by the bridging effect of L^2- and 4, 4'-bipy ligands, and the layers are stacked in an orderly manner under the action of O5-H5B…O1 hydrogen bond developing three-dimensional structure. The Zn²⁺ acts as the metal node in complex 2, and each carboxyl group on L^2- bridges zinc ions through bidentate chelation and connects infinitely to form a 3D network structure.
- zinc complexes,
- 2, 5-bis(trifluoromethyl)terephthalic acid,
- bipyridine,
- crystal structure
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