Citation: Xue ZHANG, Yuan-Yuan SUN, Si-Si FENG, Cai-Xia YUAN. Synthesis, Structures, Luminescence and Magnetic Properties of Co(Ⅱ) and Ni(Ⅱ) Coordination Compounds Based on Dibenzoyl-Tartaric Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2279-2288. doi: 10.11862/CJIC.2021.253 shu

Synthesis, Structures, Luminescence and Magnetic Properties of Co(Ⅱ) and Ni(Ⅱ) Coordination Compounds Based on Dibenzoyl-Tartaric Acid

1.
Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education, Shanxi University, Taiyuan 030006, China
2.
Xi'an Manareco New Material Co., Ltd., Xi'an 710000, China

Corresponding author: Si-Si FENG, ssfeng@sxu.edu.cn Cai-Xia YUAN, cxyuan@sxu.edu.cn
Received Date: 25 March 2021
Revised Date: 24 September 2021

Figures(9)

Two coordination compounds[Ni(DBTA)(DMF)(H₂O)₄] (1) and[Co(DBTA)(DMF)(H₂O)₄] (2) (D-H₂DBTA=(+)-2, 3-dibenzoyl-D-tartaric acid, DMF=N, N-dimethylformamide) have been synthesized at room temperature, and characterized by elemental analyses (EA), FT-IR, X-ray single-crystal and powder diffraction analyses. The structural analysis shows that complexes 1 and 2 are isomorphic. They belong to the monoclinic system with P2₁ space group and display a zero-dimensional structure constructed from coordination bonds, which is further interlinked to form a three-dimensional network via hydrogen-bonding interactions. Fluorescence measurements indicate that 1 and 2 can exhibit strong fluorescence using 280 nm as the excitation wavelength. Though 1 and 2 are isomorphic, they displayed different magnetic properties. Complex 1 dominates weak antiferromagnetic couplings between Ni²⁺ cations, while complex 2 exhibits the magnetic anisotropy of the Co²⁺ center and antiferromagnetic interactions between the Co²⁺ cations.
- coordination compounds,
- dibenzoyl-tartaric acid,
- crystal structure,
- luminescence,
- magnetism
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