Citation: Ping TANG, Yang LUO, Hong-Ying XUE, Jing-He BAI, Xiao-Fei ZHU, De-Feng ZHOU. Effects of BiVO₄ Doping on Microstructure and Performance of Nd_0.2Ce_0.8O_1.9 Electrolytes[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2141-2148. doi: 10.11862/CJIC.2021.245 shu

Effects of BiVO₄ Doping on Microstructure and Performance of Nd_0.2Ce_0.8O_1.9 Electrolytes

School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China

Corresponding author: Xiao-Fei ZHU, defengzhou65@126.com De-Feng ZHOU, zhuxiaofei@ccut.edu.cn
Received Date: 24 April 2021
Revised Date: 10 October 2021

Figures(7)

Sol-gel method was applied to prepare BiVO₄ (BV) and Nd_0.2Ce_0.8O_1.9 (NDC) powders. The effects of BV doping on microstructure, morphology and electrical properties of NDC electrolyte were studied. The results of experiments revealed that Nd_0.2Ce_0.8O_1.9 electrolyte showed a highly dense microstructure. At 700℃, the total conductivity (σ_t) of NDC-5BV electrolyte was 3.35×10^-2 S·cm^-1. The polarization resistance (R_p) was reduced by more than 34% at 700℃. The maximum power density (MPD) of the single cell reached up to 514 mW·cm^-2 at 700℃. During the operation time for 70 h, the open circuit voltage (OCV) can be maintained good stability.
- solid oxide fell cell,
- sintering aid,
- doped-ceria electrolyte,
- bismuth vanadate,
- electrochemical performance
1. [1]
  Rashid N L R M, Samat A A, Jais A A, Somalu M R, Muchta A, Isahak W N R W. Review on Zirconate-Cerate-Based Electrolytes for Proton-Conducting Solid Oxide Fuel Cell[J]. Ceram. Int., 2019,45(6):6605-6615. doi: 10.1016/j.ceramint.2019.01.045
2. [2]
  LIU H, YU J, QIAO C, WANG B, LI D X. Research Progress of Electrolyte Materials for Solid Oxide Fuel Cells[J]. Chinese Journal of Power Sources, 2020,44(10):1549-1551. doi: 10.3969/j.issn.1002-087X.2020.10.037
3. [3]
  Kuang X J, Payne J L, Johnson M R, Evans I R. Remarkably High Oxide Ion Conductivity at Low Temperature in an Ordered Fluorite-Type Superstructure[J]. Angew. Chem. Int. Ed., 2012,51(3):690-694. doi: 10.1002/anie.201106111
4. [4]
  ZHAO G C, ZHOU D F, YANG M, XIA Y J, MENG J. Effect of MoO₃ and SiO 2 Doping on the Structure and Conductivity of Ce_0.8Nd_0.2O_1.9 Solid Electrolyte[J]. Chinese J. Inorg. Chem., 2011,27(5):860-864.
5. [5]
  Le S, Zhu S C, Zhu X D, Sun K N. Densification of Sm_0.2Ce_0.8O_1.9 with the Addition of Lithium Oxide as Sintering Aid[J]. J. Power Sources, 2013,222:367-372. doi: 10.1016/j.jpowsour.2012.08.020
6. [6]
  Zhang C, Sunarso J, Zhu Z H, Wang S B, Liu S M. Enhanced Oxygen Permeability and Electronic Conductivity of Ce_0.8Gd_0.2O_2-δ Membrane via the Addition of Sintering Aids[J]. Solid State Ionics, 2017,310(1):121-128.
7. [7]
  Lima C G M, Santos T H, Grilo J P F, Dutra R P S, Nascimento R M, Rajesh S, Fonseca F C, Macedo D A. Synthesis and Properties of CuO-Doped Ce_0.9Gd_0.1O_2-δ Electrolytes for SOFCs[J]. Ceram. Int., 2015,41(3):4161-4168. doi: 10.1016/j.ceramint.2014.12.093
8. [8]
  Ge L, Li S J, Zheng Y F, Zhou M, Chen H, Guo L C. Effect of Zinc Oxide Doping on the Grain Boundary Conductivity of Ce_0.8Ln_0.2O_1.9 Ceramics (Ln=Y, Sm, Gd)[J]. J. Power Sources, 2011,196(15):6131-6137. doi: 10.1016/j.jpowsour.2011.03.032
9. [9]
  Accardo G, Frattini D, Ham H C, Han J H, Yoon S P. Improved Microstructure and Sintering Temperature of Bismuth Nano-Doped GDC Powders Synthesized by Direct Sol-Gel Combustion[J]. Ceram. Int., 2018,44(4):3800-3809. doi: 10.1016/j.ceramint.2017.11.165
10. [10]
  Gil V, Tartaj J, Moure C, Duran P. Rapid Densification by Using Bi₂O₃ as an Aid for Sintering of Gadolinia-Doped Ceria Ceramics[J]. Ceram. Int., 2007,33(3):471-475. doi: 10.1016/j.ceramint.2005.10.012
11. [11]
  Gil V, Tartaj J, Moure C, Duran P. Effect of Bi₂O₃ Addition on the Sintering and Microstructural Development of Gadolinia-Doped Ceria Ceramics[J]. J. Eur. Ceram. Soc., 2007,27(2):801-805.
12. [12]
  Han J X, Zhang J D, Li F, Luan J P, Jia B X. Low-Temperature Sintering and Microstructure Evolution of Bi₂O₃-Doped YSZ[J]. Ceram. Int., 2018,44(1):1026-1033. doi: 10.1016/j.ceramint.2017.10.039
13. [13]
  Guo H H, Zhou D, Du C, Wang P J, Liu W F, Pang L X, Wang Q P, Su J Z, Singh C, Trukhanov S. Temperature Stable Li₂Ti_0.75(Mg_1/3Nb_2/3)_0.25O₃-Based Microwave Dielectric Ceramics with Low Sintering Temperature and Ultra-Low Dielectric Loss for Dielectric Resonator Antenna Applications[J]. J. Mater. Chem. C, 2020,8(14):4690-4700. doi: 10.1039/D0TC00326C
14. [14]
  Fisher J G, Le P G, Han H S, Jeong S M. Use of Vanadium Oxide as a Liquid Phase Sintering Aid for Barium Hexaferrite[J]. J. Magn., 2018,23(3):409-415. doi: 10.4283/JMAG.2018.23.3.409
15. [15]
  Tzou W C, Yang C F, Chen Y C, Cheng P S. Improvements in the Sintering and Microwave Properties of BiNbO₄ Microwave Ceramics by V₂O₅ Addition[J]. J. Eur. Ceram. Soc., 2000,20(7):991-996. doi: 10.1016/S0955-2219(99)00228-9
16. [16]
  Chen X, Sun X, Zhou J, Zhou D F, Zhu X F, Meng J. Effects of CoO and Bi₂O₃ Single/Dual Sintering Aids Doping on Structure and Properties of Ce_0.8Nd_0.2O_1.9[J]. Ceram. Int., 2020,46(14):22727-22732. doi: 10.1016/j.ceramint.2020.06.038
17. [17]
  Wang J Q, Chen X, Xie S K, Chen L, Wang Y, Meng J, Zhou D F. Bismuth Tungstate/Neodymium-Doped Ceria Composite Electrolyte for Intermediate-Temperature Solid Oxide Fuel Cell: Sintering Aid and Composite Effect[J]. J. Power Sources, 2019,428:105-114. doi: 10.1016/j.jpowsour.2019.04.105
18. [18]
  Chen M M, Zhang H J, Fan L D, Wang C Y, Zhu B. Ceria-Carbonate Composite for Low Temperature Solid Oxide Fuel Cell: Sintering Aid and Composite Effect[J]. Int. J. Hydrogen Energy, 2014,39(23):12309-12316. doi: 10.1016/j.ijhydene.2014.04.004
19. [19]
  Hoffart L, Heider U, Jörissen L, Huggins R A, Witschel W. Transport Properties of Materials with the Scheelite Structure and Their Modification by Doping[J]. Solid State Ionics, 1995,72(2):195-198. doi: 10.1007/BF02388670
20. [20]
  Yao D, Dong C W, Bing Q M, Liu Y, Qu F D, Yang M H, Liu B B, Yang B, Zhang H. Oxygen-Defective Ultrathin BiVO₄ nanosheets for Enhanced Gas Sensing[J]. ACS Appl. Mater. Interfaces, 2019,11(26):23495-23502. doi: 10.1021/acsami.9b05626
21. [21]
  Peet J R, Fuller C A, Frick B, Koza M M, Johnson M R, Piovano A, Evans I R. Insight into Design of Improved Oxide Ion Conductors: Dynamics and Conduction Mechanisms in the Bi_0.913V_0.087O_1.587 Solid Electrolyte[J]. J. Am. Chem. Soc., 2019,141(25):9989-9997. doi: 10.1021/jacs.9b03743
22. [22]
  Nagao M, Kobayashi K, Hibino T. Low-Temperature Sintering of Yttria-Stabilized Zirconia Using Bismuth-Vanadium Oxide as a Sintering Aid at 800℃[J]. Chem. Lett., 2014,43(12):1887-1889. doi: 10.1246/cl.140712
23. [23]
  Dong C W, Lu Y S, Yao S Y, Ge R, Wang Z D, Wang Z, An P F, Liu Y, Yang B, Zhang H. Colloidal Synthesis of Ultrathin Monoclinic BiVO₄ Nanosheets for Z-Scheme Overall Water Splitting under Visible Light[J]. ACS Catal., 2018,8(9):8649-8658. doi: 10.1021/acscatal.8b01645
24. [24]
  WANG M, ZHU T, LÜ C M. Bismuth Vanadate Photocatalyst and Its Application. Beijing: Chemical Industry Press, 2016.
25. [25]
  Dolić S D, Jovanović D J, Smits K, Babić B, Marinović-Cincović M, Porobić S, Dramićanin M D. Improved Coloristic Properties and High NIR Reflectance of Environment-Friendly Yellow Pigments Based on Bismuth Vanadate[J]. Ceram. Int., 2018,44(15):17953-17961. doi: 10.1016/j.ceramint.2018.06.272
26. [26]
  Zhang T S, Ma J, Chan S H, Kilner J A. Improvements in Sintering Behavior and Grain-Boundary Conductivity of Ceria-Based Electrolytes by a Small Addition of Fe₂O₃[J]. J. Electrochem. Soc., 2004,151(10):84-90. doi: 10.1149/1.1795257
27. [27]
  Santos T H, Grilo J, Loureiro F, Fagg D P, Fábio C. Structure, Densification and Electrical Properties of Gd³⁺ and Cu²⁺ Co-doped Ceria Solid Electrolytes for SOFC Applications: Effects of Gd₂O₃ Content[J]. Ceram. Int., 2018,44(3):2745-2751. doi: 10.1016/j.ceramint.2017.11.009
28. [28]
  Huang W, Shuk P, Greenblatt M. Hydrothermal Synthesis and Properties of Ce_1-xSm_xO_2-x/2 and Ce_1-xCa_xO_2-x Solid Solutions[J]. Chem. Mater., 1997,9(10):2240-2245. doi: 10.1021/cm970425t
29. [29]
  Guo T, Zhang L, Song X, Dong X L, Shirolkar M M, Wang M, Li M, Wang H Q. Influences of Gd₂Ti₂O₇ Sintering Aid on the Densification, Ionic Conductivity and Thermal Expansion of Gd_0.1Ce_0.9O_1.95 Electrolyte for Solid Oxide Fuel Cells. J[J]. Power Sources, 2014,262:239-244. doi: 10.1016/j.jpowsour.2014.03.077
30. [30]
  Ding H, Qu D L, Sun H B, Guo X, Li J, Li Q S, Li G C, Wang P, Zhang X Y. Improved Sintering Behavior and Electrical Performance of Ce_0.8Sm_0.2O_2-δ BaZr_0.1Ce_0.7Y_0.2O_3-δ (SDC-BZCY) Composite Electrolytes with the Addition of Iron(Ⅲ) Oxide for IT-SOFCs[J]. Ceram. Int., 2019,45(18):24702-24706. doi: 10.1016/j.ceramint.2019.08.209
31. [31]
  Song X B, Liao D L, Lian Z X, Chen F, Peng K P. Effects of Monovalent Alkali Metals on Grain Boundary Conductivity and Electrochemical Properties of Gadolinia-Doped Ceria Electrolyte[J]. Ceram. Int., 2021,47(13):18773-18782. doi: 10.1016/j.ceramint.2021.03.212
32. [32]
  Zhu J X, Zhou D F, Guo S R, Ye J F, Hao X F, Cao X Q, Meng J. Grain Boundary Conductivity of High purity Neodymium-Doped Ceria Nano System with and without the Doping of Molybdenum Oxide[J]. J. Power Sources, 2007,174(1):114-123. doi: 10.1016/j.jpowsour.2007.08.093
33. [33]
  Huang K Q, Tichy R, Goodenough J B. Superior Perovskite Oxide-Ion Conductor; Strontium-and Magnesium-Doped LaGaO₃: I, Phase Relationships and Electrical Properties[J]. J. Am. Ceram. Soc., 1998,81(10):2565-2575.
34. [34]
  Strickler D W, Carlson W G. Electrical Conductivity in the ZrO₂-Rich Region of Several M₂O₃-ZrO₂ Systems[J]. Geochim. Cosmochim. Acta, 1952,48(6):155-169.
35. [35]
  Steele B C H. Appraisal of Ce_1-yGd_yO_2-y/2 Electrolytes for IT-SOFC Operation at 500℃[J]. Solid State Ionics, 2000,129(1/2/3/4):95-110.
36. [36]
  Leah R T, Brandon N P, Aguiar P. Modelling of Cells, Stacks and systems Based around Metal-Supported Planar IT-SOFC Cells with CGO Electrolytes Operating at 500-600℃[J]. J. Power Sources, 2005,145(2):336-352. doi: 10.1016/j.jpowsour.2004.12.067
37. [37]
  Wang H T, Hu T H, Xi G C. A novel Gd³⁺ and Yb³⁺ Co-doped Ceria-Sulphate Composite Electrolyte for Intermediate-Temperature Fuel Cells[J]. Ceram. Int., 2020,46(7):8695-8699. doi: 10.1016/j.ceramint.2019.12.104
1. [1]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
2. [2]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
3. [3]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
4. [4]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
5. [5]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
6. [6]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
7. [7]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
8. [8]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
9. [9]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
10. [10]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
11. [11]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
12. [12]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
13. [13]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
14. [14]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
15. [15]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
16. [16]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
17. [17]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
18. [18]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
19. [19]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
20. [20]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1507)
HTML views(128)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effects of BiVO4 Doping on Microstructure and Performance of Nd0.2Ce0.8O1.9 Electrolytes

Metrics

通讯作者: 陈斌, bchen63@163.com

Effects of BiVO₄ Doping on Microstructure and Performance of Nd_0.2Ce_0.8O_1.9 Electrolytes