Citation: Wen-Juan JI, Dan WANG, Guo-Jiao WANG, Xiu-Ling SUN, Yun-Long FU. High Performance Supercapacitors Constructed with Isomorphic MOFs Doped Graphene Oxide Electrode Materials[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 1931-1942. doi: 10.11862/CJIC.2021.241 shu

High Performance Supercapacitors Constructed with Isomorphic MOFs Doped Graphene Oxide Electrode Materials

Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of Education, School of Chemical and Material Science, Shanxi Normal University, Taiyuan 030006, China

Corresponding author: Wen-Juan JI, jiwj@sxnu.edu.cn Yun-Long FU, yunlongfu@sxnu.edu.cn
Received Date: 14 January 2021
Revised Date: 27 September 2021

Figures(15)

A series of X-MOF@GO composited with X-MOF (X₆O(TATB)₄(H⁺)₂·(H₂O)₈·(DMF)₂, X=Zn, Co, Ni; H₃TATB=4, 4', 4″-s-triazine-2, 4, 6-triyl-tribenzoic acid; DMF=N, N-dimethylformamide) and graphene oxide (GO) as supercapacitor electrode materials were synthesized by one-step self-assembly under hydrothermal conditions. X-ray powder diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy showed that X-MOF@GO composites were successfully synthesized. Ni-MOF@1.5GO electrode with the best performance delivered a specific capacitance of 694.8 F·g^-1 at 0.5 A·g^-1. Moreover, the specific capacitance of Ni-MOF@1.5GO electrode was nearly twice of Ni-MOF, while the capacitance of Ni-MOFs@1.0GO retained about 81.2% after 1 000 cycles indicating that GO doped Ni-MOF can boost the performance of MOFs materials effectively. A symmetrical capacitor based on Ni-MOF@1.5GO//AC (AC=activated carbon) electrode exhibited a high energy density of 754.3 W·kg^-1 at power density of 15.4 Wh·kg^-1, while the capacitance retention reached about 70.0% after 3 000 cycles.
- metal-organic framework,
- graphene oxide,
- composite materials,
- supercapacitors
1. [1]
  Sheberla D, Bachman J C, Elias J S, Sun C J, Shao-Horn Y, Dincă M. Conductive MOF Electrodes for Stable Supercapacitors with High Areal Capacitance[J]. Nat. Mater., 2017,16:220-224. doi: 10.1038/nmat4766
2. [2]
  Bi S, Banda H, Chen M, Niu L, Chen M Y, Wu T Z, Wang J S, Wang R X, Feng J M, Chen T Y, Dincă M, Kornyshev A A, Feng G. Molecular Understanding of Charge Storage and Charging Dynamics in Superca-pacitors with MOF Electrodes and Ionic Liquid Electrolytes[J]. Nat. Mater., 2020,19:552-558. doi: 10.1038/s41563-019-0598-7
3. [3]
  Campagnol N, Romero-Vara R, Deleu W, Stappers L, Binnemans K, De Vos D E, Fransaer J. A Hybrid Supercapacitor based on Porous Carbon and the Metal-Organic Framework MIL-100(Fe)[J]. ChemElectroChem, 2014,1(7):1182-1188. doi: 10.1002/celc.201402022
4. [4]
  Zhu G L, Wen H, Ma M, Wang W Y, Yang L, Wang L C, Shi X F, Cheng X W, Sun X P, Yao Y D. A Self-Supported Hierarchical Co-MOF as a Supercapacitor Electrode with Ultrahigh Areal Capacitance and Excellent Rate Performance[J]. Chem. Commun., 2018,54(74):10499-10502. doi: 10.1039/C8CC03669A
5. [5]
  Xu X Y, Song Y H, Xue R N, Zhou J K, Gao J P, Xing F B. Amorphous CoMoS₄ for a Valuable Energy Storage Material Candidate[J]. Chem. Eng. J., 2016,301:266-275. doi: 10.1016/j.cej.2016.05.033
6. [6]
  Xiao Z Y, Bao Y X, Li Z J, Huai X D, Wang M H, Liu P, Wang L. Construction of Hollow Cobalt-Nickel Phosphate Nanocages through a Controllable Etching Strategy for High Supercapacitor Performances[J]. ACS Appl. Energy Mater., 2019,2(2):1086-1092. doi: 10.1021/acsaem.8b01627
7. [7]
  Qi K, Hou R Z, Zaman S, Qiu Y B, Xia B Y, Duan H W. Construction of Metal-Organic Framework/Conductive Polymer Hybrid for All-Solid-State Fabric Supercapacitor[J]. ACS Appl. Mater. Interfaces, 2018,10(21):18021-18028. doi: 10.1021/acsami.8b05802
8. [8]
  Mei H, Mei Y J, Zhang S Y, Xiao Z Y, Xu B, Zhang H B, Fan L L, Huang Z D, Kang W P, Sun D F. Bimetallic-MOF Derived Accordion-like Ternary Composite for High-Performance Supercapacitors[J]. Inorg. Chem., 2018,57(17):10953-10960. doi: 10.1021/acs.inorgchem.8b01574
9. [9]
  Gupta A K, Saraf M, Bharadwaj P K, Mobin S M. Dual Functionalized Cu MOF-Based Composite for High-Performance Supercapacitors[J]. Inorg. Chem., 2019,58(15):9844-9854. doi: 10.1021/acs.inorgchem.9b00909
10. [10]
  Ajdari F B, Kowsari E, Shahrak M N, Ehsani A, Kiaei Z, Torkzaban H, Ershadi M, Eshkalak S K, Haddadi-Asl V, Chinnappan A, Ramakrishna S. A Review on the Fifield Patents and Recent Developments over the Application of Metal Organic Frameworks (MOFs) in Supercapacitors[J]. Coord Chem. Rev., 2020,422213441. doi: 10.1016/j.ccr.2020.213441
11. [11]
  Kazemi S H, Hosseinzadeh B, Kazemi H, Kiani M A, Hajati S. Facile Synthesis of Mixed Metal-Organic Frameworks: Electrode Materials for Supercapacitors with Excellent Areal Capacitance and Operational Stability[J]. ACS Appl. Mater. Interfaces, 2018,10(27):23063-23073. doi: 10.1021/acsami.8b04502
12. [12]
  Zheng S S, Li X R, Yan B Y, Hu Q, Xu Y X, Xiao X, Xue H G, Pang H. Transition-Metal (Fe, Co, Ni) Based Metal-Organic Frameworks for Electrochemical Energy Storage[J]. Adv. Energy Mater., 2017,7(18)1602733. doi: 10.1002/aenm.201602733
13. [13]
  Cheng Q H, Tao K, Han X, Yang Y J, Yang Z, Ma Q X, Han L. Ultrathin Ni-MOF Nanosheet Arrays Grown on Polyaniline Decorated Ni Foam as an Advanced Electrode for Asymmetric Supercapacitors with High Energy Density[J]. Dalton Trans., 2019,48(13):4119-4123. doi: 10.1039/C9DT00386J
14. [14]
  Deng T, Zhang W, Arcelus O, Wang D, Shi X Y, Zhang X Y, Carrasco J, Rojo T, Zheng W T. Vertically Co-Oriented Two Dimensional Metal-Organic Frameworks for Packaging Enhanced Supercapacitive Performance[J]. Comm. Chem., 2018,16. doi: 10.1038/s42004-017-0005-8
15. [15]
  Shi H T, Jang S Y, Reza-Ugalde A, Naguib H E. Hierarchically Structured Nitrogen-Doped Multilayer Reduced Graphene Oxide for Flexible Intercalated Supercapacitor Electrodes[J]. ACS Appl. Energy Mater., 2019,3(1):987-997.
16. [16]
  Young C, Kim J, Kaneti Y V, Yamauchi Y. One-Step Synthetic Strategy of Hybrid Materials from Bimetallic Metal-Organic Frameworks for Supercapacitor Applications[J]. ACS Appl. Energy Mater., 2018,1(5):2007-2015. doi: 10.1021/acsaem.8b00103
17. [17]
  Zhang Y D, Lin B P, Sun Y, Zhang X Q, Yang H, Wang J C. Carbon Nanotubes@Metal-Organic Frameworks as Mn-Based Symmetrical Supercapacitor Electrodes for Enhanced Charge Storage[J]. RSC Adv., 2015,5(72):58100-58106. doi: 10.1039/C5RA11597C
18. [18]
  Jiao Y, Qu C, Zhao B T, Liang Z B, Chang H B, Kumar S, Zou R Q, Liu M L, Walton K S. High-Performance Electrodes for a Hybrid Supercapacitor Derived from a Metal-Organic Framework/Graphene Composite[J]. ACS Appl. Energy Mater., 2019,2(7):5029-5038. doi: 10.1021/acsaem.9b00700
19. [19]
  Mallick A, Liang H F, Shekhah O, Jia J T, Mouchaham G, Shkurenko A, Belmabkhout Y, Alshareef H N, Eddaoudi M. Made-to-Order Porous Electrodes for Supercapacitors: MOFs Embedded with Redox-Active Centers as a Ease Study[J]. Chem. Commun., 2020,56:1883-1886. doi: 10.1039/C9CC08860A
20. [20]
  Xue Y Y, Li S N, Jiang Y C, Hu M C, Zhai Q G. Quest for 9-Connected Robust Metal-Organic Framework Platforms on the Base of[J]. J. Mater. Chem. A, 2019,7:4640-4650. doi: 10.1039/C8TA09080G
21. [21]
  Hou X Y, Yan X L, Wang X, Li S N, Jiang Y C, Hu M C, Zhai Q G. Excellent Supercapacitor Performance of Robust Nickel-Organic Framework Materials Achieved by Tunable Porosity, Inner-Cluster Redox, and In Situ Fabrication with Graphene Oxide[J]. Cryst. Growth Des., 2018,18:6035-6045. doi: 10.1021/acs.cgd.8b00881
22. [22]
  Xu H Z, Ye K, Zhu K, Yin J L, Yan J, Wang G L, Cao D X. Efficient Bifunctional Catalysts Synthesized from Three-Dimensional Ni/Fe Bimetallic Organic Frameworks for Overall Urea Electrolysis[J]. Dalton Trans., 2020,49(17):5646-5652. doi: 10.1039/D0DT00605J
23. [23]
  Chen Y W, Lv D F, Wu J L, Xiao J, Xi H X, Xia Q B, Li Z. A New MOF-505@GO Composite with High Selectivity for CO₂/CH₄ and CO₂/N₂ Separation[J]. Chem. Eng. J., 2017,308:1065-1072. doi: 10.1016/j.cej.2016.09.138
24. [24]
  Yan X L, Li X J, Yan Z F, Komarneni S. Porous Carbons Prepared by Direct Carbonization of MOFs for Supercapacitors[J]. Appl. Surf. Sci., 2014,308:306-310. doi: 10.1016/j.apsusc.2014.04.160
25. [25]
  Wang L, Feng X, Ren L T, Piao Q H, Zhong J Q, Wang Y B, Li H W, Chen Y F, Wang B. Flexible Solid-State Supercapacitor Based on a Metal-Organic Framework Interwoven by Electrochemically-Deposited PANI[J]. J. Am. Chem. Soc., 2015,137:4920-4923. doi: 10.1021/jacs.5b01613
26. [26]
  Zhu L L, Hao C, Wang X H, Guo Y N. Fluffy Cotton-like GO/Zn-Co-Ni Layered Double Hydroxides Form from a Sacrificed Template GO/ZIF-8 for High Performance Asymmetric Supercapacitors[J]. ACS Sustainable Chem. Eng., 2020,8(31):11618-11629. doi: 10.1021/acssuschemeng.0c02916
27. [27]
  Al-Naddaf Q, Al-Mansour M, Thakkar H, Rezaei F. MOF-GO Hybrid Nanocomposite Adsorbents for Methane Storage[J]. Ind. Eng. Chem. Res., 2018,57:17470-17479. doi: 10.1021/acs.iecr.8b03638
28. [28]
  Jin H X, Yuan D Q, Zhu S Y, Zhu X H, Zhu J L. Ni-Co Layered Double Hydroxide on Carbon Nanorods and Graphene Nanoribbons Derived from MOFs for Supercapacitors[J]. Dalton Trans., 2018,47(26):8706-8715. doi: 10.1039/C8DT01882K
29. [29]
  Hou Y, Chai D F, Li B N, Pang H J, Ma H Y, Wang X M, Tan L C. Polyoxometalate-Incorporated Metallacalixarene@Graphene Composite Electrodes for High-Performance Supercapacitors[J]. ACS Appl. Mater. Interfaces, 2019,11(23):20845-20853. doi: 10.1021/acsami.9b04649
30. [30]
  Hong J W, Park S J, Kim S. Synthesis and Electrochemical Characterization of Nanostructured Ni-Co -MOF/Graphene Oxide Composites as Capacitor Electrodes[J]. Electrochim. Acta, 2019,311:62-71. doi: 10.1016/j.electacta.2019.04.121
31. [31]
  Salgado S, Pu L, Maheshwari V. Targeting Chemical Morphology of Graphene Oxide for Self-Assembly and Subsequent Templating of Nanoparticles: A Composite Approaching Capacitance Limits in Graphene[J]. J. Phys. Chem. C, 2012,116(22):12124-12130. doi: 10.1021/jp3023875
32. [32]
  Hu X R, Li J F, Wu Q S, Zhang Q W, Wang X. MOF-Derived Ni(OH)₂ Nanocubes/GO For High-Performance Supercapacitor[J]. ChemistrySelect, 2019,4(27):7922-7926. doi: 10.1002/slct.201901616
33. [33]
  Zhou Y J, Mao Z M, Wang W, Yang Z K, Liu X. In-Situ Fabrication of Graphene Oxide Hybrid Ni-Based Metal-Organic Framework (Ni-MOFs@GO) with Ultrahigh Capacitance as Electrochemical Pseudo-capacitor Materials[J]. ACS Appl. Mater. Interfaces, 2016,8(42):28904-28916. doi: 10.1021/acsami.6b10640
34. [34]
  CHU M, LI X, LI N, HOU M J, LI X Z, DONG Y Z, WANG L. Improved Electrocatalytic Hydrogen-Evolution Performance of Metal -Organic-Framework MOF(Ni)-74 by Using Graphene Oxide Decorations[J]. Mater. Rep., 2018,32(5):1417-1422.
35. [35]
  Sun D F, Ma S Q, Ke Y X, Petersen T M, Zhou H C. Synthesis, Characterization, and Photoluminescence of Isostructural Mn, Co, and Zn MOFs Having a Diamondoid Structure with Large Tetrahedral Cages and High Thermal Stability[J]. Chem. Commun., 2005(21):2663-2665. doi: 10.1039/b502007g
36. [36]
  Jiang X B, Li G N, Lu D P, Xiao W, Ruan X H, Li X C, He G H. Hybrid Control Mechanism of Crystal Morphology Modification for Ternary Solution Treatment via Membrane Assisted Crystallization[J]. Cryst. Growth Des., 2018,18:934-943. doi: 10.1021/acs.cgd.7b01424
37. [37]
  Yadav H, Sinha N, Kumar B. New Geometrical Modeling to Study Crystal Morphology[J]. Cryst. Growth Des., 2016,16:4559-4566. doi: 10.1021/acs.cgd.6b00665
38. [38]
  Qu C, Jiao Y, Zhao B T, Chen D C, Zou R Q, Walton K S, Liu M L. Nickel-Based Pillared MOFs for High-Performance Supercapacitors: Design, Synthesis and Stability Study[J]. Nano Energy, 2016,26:66-73. doi: 10.1016/j.nanoen.2016.04.003
39. [39]
  Saraf M, Rajak R, Mobin S M. Solid-Type Supercapacitor of Reduced Graphene Oxide-Metal Organic Framework Composite Coated on Carbon Fiber Paper[J]. J. Mater. Chem. A, 2016,4:16432-6445. doi: 10.1039/C6TA06470A
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