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Citation: Ao XIA, Yue-Peng HAN, Xiao-Xiong ZENG, Chen-Peng ZHAO, Guo-Qiang TAN. Preparation and Lithium Storage Properties of N Doped MnO2/Carbon Cloth Composites[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(12): 2175-2184. doi: 10.11862/CJIC.2021.234 shu

Preparation and Lithium Storage Properties of N Doped MnO2/Carbon Cloth Composites

  • School of Materials Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science & Technology, Xi'an 710021, China

  • Corresponding author: Ao XIA, xiaao@sust.edu.cn
  • Received Date: 22 May 2021
    Revised Date: 2 September 2021

Figures(9)

  • MnO2/CC and N doped MnO2/CC binderless anode materials were prepared by hydrothermal method with carbon cloth (CC) as a flexible substrate, and the structure characterization and electrochemical performance of the materials were tested by means of X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), specific surface area test and galvanostatic charge and discharge. The results showed that N doped MnO2/CC had good rate performance and cycle stability. The first charge specific capacity of N doped MnO2/CC was 948.8 mAh·g-1 at the current density of 0.1 A·g-1, and the reversible specific capacity remained 907.9 mAh·g-1 when the current density returned to 0.1 A·g-1 after different rate tests, and the capacity retention rate was 95.7%. At the high current density of 1 A·g-1, the initial charging specific capacity of N doped MnO2/CC was 640.3 mAh·g-1, the reversible specific capacity still retained 529.9 mAh·g-1 after 100 cycles, and the capacity retention rate was 82.8%. The reversible specific capacity was much higher than that of commercial MnO2.
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