Citation: Xue CUI, Yu-Ping ZHANG, Tian GUI, Ming-Liang HE, Fei ZHANG, Na HU, Yu-Qin LI, Xiang-Shu CHEN. Difunctional Effects of Organo-Modified T-Type Zeolite Membranes for Dewatering from Organic Solution[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 2068-2078. doi: 10.11862/CJIC.2021.228 shu

Difunctional Effects of Organo-Modified T-Type Zeolite Membranes for Dewatering from Organic Solution

Institute of Advanced Materials (IAM), State-Province Joint Engineering Laboratory of Zeolite Membrane Materials, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: Fei ZHANG, fzhang@jxnu.edu.cn Xiang-Shu CHEN, cxs66cn@jxnu.edu.cn
Received Date: 27 March 2021
Revised Date: 31 August 2021

Figures(10)

3-aminopropyltriethoxysilane (APTES) was introduced to modify the surface of T-type zeolite membranes. Characterizations, such as X-ray diffraction, field-emission scanning electron microscopy, X-ray photoelectron spectroscopy and FT-IR, demonstrated that APTES was successfully modified on the membrane surface by chemical bonding. The modified APTES plays two roles: one is to improve the membrane hydrophilicity and the other is to reduce the defects of membrane layer. The modified membranes showed a high separation factor and water flux for the dewatering of a 90% isopropyl alcohol solution at 348 K. This method showed good reproducibility, and five modified membranes demonstrated an increased separation factor by about 8 times (from 359±23 to 2 934±183), and a slightly decreased total flux from (3.52±0.10) kg·m^-2·h^-1 to (3.06±0.14) kg·m^-2·h^-1 (a decrease of 13.07%). At 363 K, during 100 h of continuous testing, the modified membrane was very stable, and the permeation side retained a high-water content above 99.50% with a feed solution of 90% isopropyl alcohol.
- T-type zeolite membrane,
- 3-aminopropyltriethoxysilane,
- hydrophilic,
- defects
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