Citation: Hong-Hua WU, Feng-Hua ZU, Shan FU, Xiao-Long DONG, Su-Yun LI, Jian-Jun YI, Hai-Jun HAO, Qing-Hong XU. Ag@Silsequioxanes: Synthesis and Its Catalytic Reduction Performance for p-Nitrophenol[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 1961-1969. doi: 10.11862/CJIC.2021.225 shu

Ag@Silsequioxanes: Synthesis and Its Catalytic Reduction Performance for p-Nitrophenol

1.
College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China
2.
Petrochemical Research Institute of PetroChina Company Limited, Beijing 102206, China

Corresponding author: Hai-Jun HAO, hjhao@mail.buct.edu.cn Qing-Hong XU, xuqh@mail.buct.edu.cn
Received Date: 12 March 2021
Revised Date: 28 August 2021

Figures(9)

Aminopropyltriethoxysilane and oxalyl chloride were used as raw materials to synthesize silsesquioxanes containing imino and carbonyl functional groups. A composite with silver nanoparticles (average particle size of about 15 nm) uniformly dispersed on the surface of the siloxane polymer was obtained through coordination adsorption and reduction. The research results showed that the weight percentage of silver loaded in the composite was about 13.66% and p-nitrophenol (4-NP) was completely reduced to 4-aminophenol (4-AP) within 6 min at 25℃ in aqueous solution by the composite catalyst, and the composite catalyst remained 95% activity after used 7 times. Under room temperature and one atmospheric pressure, the highest activity of the composite catalyst was about 33.0 g_4-AP·g_Ag^-1, which showed excellent catalytic reduction performance.
- silsequioxanes,
- silver nanoparticles,
- reduction catalysis,
- 4-nitrophenol,
- 4-aminophenol
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