Citation: Yong-He REN, Lu-Chao LI, Qi-Hui DING, Yong-Qing HUANG, Yue ZHAO. Structures and Luminescence Property of Two Co(Ⅱ) and Cd(Ⅱ) Supramolecular Coordination Networks Created via Synergistic Effect of Coordination Bonds and Secondary Interactions[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 2047-2058. doi: 10.11862/CJIC.2021.224 shu

Structures and Luminescence Property of Two Co(Ⅱ) and Cd(Ⅱ) Supramolecular Coordination Networks Created via Synergistic Effect of Coordination Bonds and Secondary Interactions

1.
Co1lege of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemical and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: Yong-Qing HUANG, yqhuangskd@163.com
Received Date: 27 December 2020
Revised Date: 7 September 2021

Figures(7)

Two complexes with chemical formulas[Co(L)₂(H₂O)₄]·2H₂O (1) and[Cd(L)₂(H₂O)]·3H₂O (2) were obtained by the reaction of 3-carboxy-1-(4-carboxybenzyl)-pyridinium bromide ((H₂L) Br) with corresponding Co(Ⅱ) and Cd(Ⅱ) metal salts. Crystal structure analysis reveals that 1 is a neutral mononuclear complex, which possesses abundant hydrogen bond and π-π interaction components and can be used as supramolecular synthons. In the case of 1, mononuclear[Co(L)₂(H₂O)₄] coordination entities are first joined via hydrogen bonding to produce channel-structured 2D layers, which are further stacked via π-π stacking effect in an interdigitating fashion, generating a 3D porous supramolecular assembly. 2 features a polymeric 1D zigzag chain structure, which is connected via π-π interactions between pendent L ligands, resulting in the formation of 1D ladder chains. Such 1D ladder chains are further combined into wave-like 2D sheets via another two kinds of π-π stacking between two adjacent side rails of 1D ladder chains. Such 2D sheets are further assembled via eight types of O-H…O hydrogen bonds to form a 3D supramolecular structure. According to topological viewpoint based on 1D chains, the 3D structure of 2 can also be deemed as the plywood-like array. In addition, 2 shows strong ultraviolet fluorescence emission with an average life-time of 2.54 ns.
- Co(Ⅱ) complex,
- Cd(Ⅱ) complex,
- secondary interaction,
- pyridinium,
- luminescence property
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