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Citation: Xiao-Lan YANG, Zhong-Hui WU, Ya-Jun ZHANG, Xin-Jian HE, Jin-Zhu JIA, Xiong-Zhi YANG, Jun-Li ZHOU. Application of Needle-like NiCo2O4@Carbon Cloth Composites in Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(11): 1943-1949. doi: 10.11862/CJIC.2021.222 shu

Application of Needle-like NiCo2O4@Carbon Cloth Composites in Lithium-Sulfur Batteries

  • School of Chemical Engineering and Light Industry, Key Laboratory of Clean Chemistry Technology of Guangdong Regular Higher Education, Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong University of Technology, Guangzhou 510006, China

  • Corresponding author: Jun-Li ZHOU, zhoujlees@gdut.edu.cn
  • Received Date: 8 February 2021
    Revised Date: 6 September 2021

Figures(6)

  • Using carbon cloth (CC) as a flexible substrate, needle-like network structure NiCo2O4 was grown on the surface of CC by hydrothermal method, and then NiCo2O4@CC composites were prepared and used for lithium-sulfur battery. NiCo2O4 grows vertically on the surface of carbon fiber to form a three-dimensional network of nano-needle clusters, which provides more space for sulfur storage and effectively alleviates the volume expansion of sulfur electrode. Through adsorption experiments, it is proved that NiCo2O4@CC can effectively adsorb polysulfide, thus inhibiting the shuttle effect of polysulfide. Compared with CC/S (933 mAh·g-1), NiCo2O4@CC/S composite had better battery performance. The initial discharge specific capacity was as high as 1 467 mAh·g-1 at 0.1C, and the initial discharge specific capacity was 1 098 mAh·g-1 at 0.2C, the discharge specific capacity can remain 879 mAh·g-1 even after 200 cycles, and the average decay rate of each cycle was 0.09%, showing good cycle performance.
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