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Citation: Yi-En DU, Xian-Jun NIU, Wan-Xi LI, Shu-Ya GAO, Yu-Mei LI. Solvothermal Synthesis of High-Reactive Faceted Anatase TiO2 Nanomaterials with Improved Photocatalytic Performance[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1753-1763. doi: 10.11862/CJIC.2021.211 shu

Solvothermal Synthesis of High-Reactive Faceted Anatase TiO2 Nanomaterials with Improved Photocatalytic Performance

  • 1.

    School of Chemistry & Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030619, China

  • 2.

    College of Chemistry and Environmental Engineering, Xinjiang Institute of Technology, Urumqi 830023, China

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  • Herein, anatase TiO2 nanoparticles with co-exposed {101}/[111]-facets (ethanoic acid-TiO2 and no control agent-TiO2, namely HAc-TiO2 and NO-TiO2) and co-exposed {101}/{010}/[111]-facets (formic acid-TiO2 and hydrofluoric acid-TiO2, namely FA-TiO2 and HF-TiO2) were prepared by a mild solvothermal method using tetrabutyl titanate as titanium source. The crystal structure, morphology, specific surface area, pore size distribution, optical properties, transformation and recombination of charge carriers (electron and hole) of the samples were characterized. The photocatalytic performance and cycling performance of the samples were also evaluated. The results showed that as-prepared HF-TiO2 with co-exposed {101}/{010}/[111]-facets exhibited the highest photocatalytic activity in the process of photocatalytic degradation of rhodamine B solution (or p-nitrophenol solution), and its degradation efficiency was 97.35% (or 68.57%), which was 1.06 times (or 1.09 times), 1.18 times (or 1.14 times), 1.35 times (or 2.33 times) and 4.88 times (or 5.80 times) of FA-TiO2, HAc-TiO2, BD-TiO2 and NO-TiO2, respectively. The highest photocatalytic activity of HF-TiO2 could be attributed to the synergistic effect of the maximum crystallinity, larger surface energy, superior surface atomic structure and surface electronic structure, lowest photoluminescence intensity, fastest charge transfer rate and minimum carrier recombination rate.
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    1. [1]

      He K, Wen Q K, Wang C W, Wang B X, Yu S S, Hao C C, Chen K Z. Soft Matter, 2017, 13: 7879-7889  doi: 10.1039/C7SM01422H

    2. [2]

      Wang W G, Zhang H Y, Wang R, Feng M, Chen Y M. Nanoscale, 2014, 6: 2390-2396  doi: 10.1039/C3NR05967G

    3. [3]

      Carlucci C, Xu H, Scremin B F, Giannini C, Altamura D, Carlino E, Videtta V, Conciauro F, Gigli G, Ciccarella G. CrystEngComm, 2014, 16: 1817-1824  doi: 10.1039/c3ce41477a

    4. [4]

      Ma Z L, Shi L Y, Qu W W, Hu Q, Chen R F, Wang Y J, Chen Z. RSC Adv., 2020, 10: 43447-43458  doi: 10.1039/D0RA08597A

    5. [5]

      Du Y E, Feng Q, Chen C D, Tanaka Y, Yang X J. ACS Appl. Mater. Interfaces, 2014, 6: 16007-16019  doi: 10.1021/am503914q

    6. [6]

      Nong S Y, Dong C L, Wang Y X, Huang F Q. Nanoscale, 2020, 12: 18429-18436  doi: 10.1039/D0NR04861E

    7. [7]

      Amri F, Septiani N L W, Rezki M, Iqbal M, Yamauchi Y, Golberg D, Kaneti Y V, Yuliarto B. J. Mater. Chem. B, 2021, 9: 1189-1207  doi: 10.1039/D0TB02292F

    8. [8]

      Kubacka A, Fernández-García M, Colón G. Chem. Rev., 2012, 112: 1555-1614

    9. [9]

      Ye L Q, Liu J Y, Jiang Z, Peng T Y, Zan L. Nanoscale, 2013, 5: 9391-9396  doi: 10.1039/c3nr02273k

    10. [10]

      Lazzeri M, Vittadini A, Selloni A. Phys. Rev. B, 2001, 63: 155409  doi: 10.1103/PhysRevB.63.155409

    11. [11]

      Xu H, Reunchan P, Ouyang S X, Tong H, Umezawa N, Kako T. Chem. Mater., 2013, 25(3): 405-411  doi: 10.1021/cm303502b

    12. [12]

      Yang H G, Sun C H, Qiao S Z, Zou J, Liu G, Smith S C, Cheng H M, Lu G Q. Nature, 2008, 453: 638-641  doi: 10.1038/nature06964

    13. [13]

      Wen P H, Itoh H, Tang W P, Feng Q. Langmuir, 2007, 23: 11782-11790  doi: 10.1021/la701632t

    14. [14]

      Yang H G, Liu G, Qiao S Z, Sun C H, Jin Y G, Smith S C, Zou J, Cheng H M, Lu G Q. J. Am. Chem. Soc., 2009, 131: 4078-4083  doi: 10.1021/ja808790p

    15. [15]

      Sun W, Liu H, Hu J C, Li J L. RSC Adv., 2015, 5: 513-520  doi: 10.1039/C4RA13596B

    16. [16]

      Liu M, Li H M, Zeng Y S, Huang T C. Appl. Surf. Sci., 2013, 274: 117-123  doi: 10.1016/j.apsusc.2013.02.125

    17. [17]

      Zhao J, Zou X X, Su J, Wang P P, Zhou L J, Li G D. Dalton Trans., 2013, 42: 4365-4368  doi: 10.1039/c3dt33053b

    18. [18]

      Chen C D, Sewvandi G A, Kusunose T, Tanaka Y, Nakanishi S, Feng Q. CrystEngComm, 2014, 16: 8885-8895  doi: 10.1039/C4CE01250J

    19. [19]

      Du Y E, Niu X J, Li W X, An J, Liu Y F, Chen C D, Wang P F, Yang X J, Feng Q. Materials, 2019, 12: 3614  doi: 10.3390/ma12213614

    20. [20]

      Du Y E, Niu X J, Bai Y, Qi H X, Guo Y Q, Wang P F, Yang X J, Feng Q. ChemistrySelect, 2019, 4: 4443-4457  doi: 10.1002/slct.201900257

    21. [21]

      Du Y E, Niu X J, He J, Liu L, Liu Y F, Chen C D, Yang X J, Feng Q. ACS Omega, 2020, 5: 14147-14156  doi: 10.1021/acsomega.0c01827

    22. [22]

      DU Y E, NIU X J, AN J. Journal of Yunnan University (Natural Sciences Edition), 2020, 42(6): 1147-1158
       

    23. [23]

      He Z Q, Jiang L X, Wang D, Qiu J P, Chen J M, Song S. Ind. Eng. Chem. Res., 2015, 54(3): 808-818  doi: 10.1021/ie503997m

    24. [24]

      Chen D M, Du G X, Zhu Q, Zhou F S. J. Colloid Interface Sci., 2013, 409: 151-157  doi: 10.1016/j.jcis.2013.07.049

    25. [25]

      Ong W J, Tan L L, Chai S P, Yong S T, Mohamed A R. Nanoscale, 2014, 6: 1946-2008  doi: 10.1039/c3nr04655a

    26. [26]

      Yu F, Wang L C, Xing Q J, Wang D K, Jiang X H, Li G C, Zheng A M, Ai F R, Zou J P. Chin. Chem. Lett., 2020, 31: 1648-1653  doi: 10.1016/j.cclet.2019.08.020

    27. [27]

      Sambaza S S, Maity A, Pillay K. ACS Omega, 2020, 5: 29642-29656  doi: 10.1021/acsomega.0c00628

    28. [28]

      Liu X G, Du G R, Li M. ACS Omega, 2019, 4: 14902-14912  doi: 10.1021/acsomega.9b01648

    29. [29]

      Yang L B, Gao P, Lu J H, Guo W, Zhuang Z, Wang Q Q, Li W J, Feng Z Y. RSC Adv., 2020, 10: 20654-20664  doi: 10.1039/D0RA01996H

    30. [30]

      Tu W G, Zhou Y, Liu Q, Tian Z P, Gao J, Chen X Y, Zhang H T, Liu J G, Zou Z G. Adv. Funct. Mater., 2012, 22: 1215-1221  doi: 10.1002/adfm.201102566

    31. [31]

      Jiang Z L, Tang Y X, Tay Q L, Zhang Y Y, Malyi O I, Wang D P, Deng J Y, Lai Y K, Zhou H F, Chen X D, Dong Z L, Chen Z. Adv. Energy Mater., 2013, 3: 1368-1380  doi: 10.1002/aenm.201300380

    32. [32]

      Zhang G Y, Wei X M, Bai X, Liu C M, Wang B Y, Liu J W. Inorg. Chem. Front., 2018, 5: 951-961  doi: 10.1039/C8QI00105G

    33. [33]

      Jiang X H, Zhang L S, Liu H Y, Wu D S, Wu F Y, Tian L, Liu L L, Zou J P, Luo S L, Chen B B. Angew. Chem. Int. Ed., 2020, 59: 23112-23116  doi: 10.1002/anie.202011495

    34. [34]

      Zhu M, Zhang L S, Liu S S, Wang D K, Qin Y C, Chen Y, Dai W L, Wang Y H, Xing Q J, Zou J P. Chin. Chem. Lett., 2020, 31: 1961-1965  doi: 10.1016/j.cclet.2020.01.017

    35. [35]

      Wei X X, Cui B Y, Wang X X, Cao Y Z, Gao L B, Guo S Q, Chen C M. CrystEngComm, 2019, 21: 1750-1757  doi: 10.1039/C8CE02072H

    36. [36]

      Zheng L L, Wang D K, Wu S L, Jiang X H, Zhang J, Xing Q J, Zou J P, Luo S L. J. Mater. Chem. A, 2020, 8: 25425-25430  doi: 10.1039/D0TA10165F

    37. [37]

      Kiatkittipong K, Scott J, Amal R. ACS Appl. Mater. Interfaces, 2011, 3(10): 3988-3996  doi: 10.1021/am2008568

    38. [38]

      Hu D W, Zhang W X, Tanaka Y, Kusunose N, Peng Y G, Feng Q. Cryst. Growth Des., 2015, 15(3): 1214-1225  doi: 10.1021/cg501616k

    39. [39]

      Pan J, Liu G, Lu G Q, Cheng H M. Angew. Chem. Int. Ed., 2011, 50: 2133-2137  doi: 10.1002/anie.201006057

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