Citation: Hai-Zhi LIU, Zhi-Hao KONG, Xiao-Yan LIN, Peng-Dong LIU, Fa-Hai DONG, Zhen WANG, Guang-Wu WEN. Effect of La, Ce, Yb Doping on Properties of LiNi_0.5Mn_1.5O₄ High Voltage Cathode Materials[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1782-1792. doi: 10.11862/CJIC.2021.210 shu

Effect of La, Ce, Yb Doping on Properties of LiNi_0.5Mn_1.5O₄ High Voltage Cathode Materials

Hai-Zhi LIU ¹ ,
Zhi-Hao KONG ¹ ,
Xiao-Yan LIN ¹ ,
Peng-Dong LIU ¹ ,
Fa-Hai DONG ¹ ,
Zhen WANG ^{2, 3} ,
Guang-Wu WEN ^{1, 2, 3,,}

1.
School of Materials Science and Engineering, Shandong University of Technology, Zibo, Shandong 255000, China
2.
Shandong Si-Nano Materials Technology Co. Ltd., Zibo, Shandong 255000, China
3.
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China

Corresponding author: Guang-Wu WEN, g_wen2016@163.com
Received Date: 1 April 2021
Revised Date: 28 July 2021

Figures(8)

High-voltage LiNi_0.5Mn_1.5O₄ cathode materials doped with different rare earth elements were prepared by low temperature combustion method. The effects of different doping ratios (molar ratios of 0.5%, 1%, 2%) and different kinds of rare earth elements (La, Ce, Yb) on the material performance were investigated, and the influence mechanism was explored by X-ray diffraction, Raman spectrum, electron paramagnetic resonance and galvanostatic intermittent titration technique. X-ray diffraction pattern illustrates that rare earth doping can inhibit the generation of Li_xNi_1-xO phase. The inductively coupled plasma spectroscopy illustrates that the doped rare earth elements are basically in accordance with the design proportion. Raman spectrum illustrates that rare earth elements can increase the ordered phase of the material and Ce doped sample has the most ordered phase. In combination with electron paramagnetic resonance oxygen vacancy test, it is found that Ce doped sample induces the increase of the proportion of ordered phase in the material, thus improving the stability of the material. Galvanostatic intermittent titration technique test showed that the diffusion coefficient of Ce-doped LiNi_0.5Mn_1.5O₄ material was about 15 times higher than the undoped sample. In different doping proportion, the material with 1% doping amount had the best performance. Among the samples doping with the best amount of three rare earth elements, Ce doped samples had the best doping performance, and the specific discharge capacity of the first discharge can reach 133.3 mAh·g^-1, which was higher than the undoped group and the first discharge efficiency was increased by 18%. After 200 cycles at 1C, the capacity retention rate was 102%, which was 8% higher than the undoped group.
- LiNi_0.5Mn_1.5O₄,
- low temperature combustion method,
- ordered/disordered regulation,
- oxygen vacancy
1. [1]
  Masias A, Marcicki J, Paxton W A. ACS Energy Lett. , 2021, 6: 621-630 doi: 10.1021/acsenergylett.0c02584
2. [2]
  Zhu X B, Schulli T, Wang L Z. Chem. Res. Chin. Univ. , 2020, 36(1): 24-32 doi: 10.1007/s40242-020-9103-8
3. [3]
  Liang G, Peterson V K, See K W, Guo Z, Pang W K. J. Mater. Chem. , 2020, 8(31): 15373-15398 doi: 10.1039/D0TA02812F
4. [4]
  Li W D, Song B H, Manthiram A. Chem. Soc. Rev. , 2017, 46(10): 3006-3059 doi: 10.1039/C6CS00875E
5. [5]
  WANG H, BEN L B, LIN M X, CHEN Y Y, HUANG X J. Energy Storage Science and Technology, 2017, 6(5): 841-854
6. [6]
  LI W, ZHOU L, LIU J L. Inorganic Chemicals Industry, 2019, 51(6): 5-10
7. [7]
  Cui X L, Geng T T, Zhang F L, Zhang N S, Zhao D N, Li C L, Li S Y. J. Alloys Compd. , 2020, 820: 153443-153443 doi: 10.1016/j.jallcom.2019.153443
8. [8]
  Wang L P, Hong L, Huang X J, Baudrin E. Solid State Ionics, 2011, 193(1): 32-38 doi: 10.1016/j.ssi.2011.04.007
9. [9]
  Gu Y J, Li Y, Chen Y B, Liu H Q. Electrochim. Acta, 2016, 213: 368-374 doi: 10.1016/j.electacta.2016.06.124
10. [10]
  Hu E, Bak S M, Liu J, Yu X, Zhou Y, Ehrlich S N, Yang X Q, Nam K W. Chem. Mater. , 2013, 26(2): 1108-1118
11. [11]
  Lee B Y, Chu C T, Krajewski M, Michalska M, Lin J Y. Ceram. Int. , 2020, 46(13): 20856-20864 doi: 10.1016/j.ceramint.2020.05.124
12. [12]
  Rana J, Glatthaar S, Gesswein H, Sharma N, Binder J R, Chernikov R, Schumacher G, Banhart J. J. Power Sources, 2014, 255: 439-449 doi: 10.1016/j.jpowsour.2014.01.037
13. [13]
  Amin R, Belharouk I. J. Power Sources, 2017, 348(30): 311-317
14. [14]
  Lee J, Kim C, Kang B. NPG Asia Mater. , 2015, 7(8): 211-211 doi: 10.1038/am.2015.94
15. [15]
  Xiao J, Chen X, Sushko P V, Sushko M L, Kovarik L, Feng J, Deng Z, Zheng J, Graff G L, Nie Z, Choi D, Liu J, Zhang J G, Whittingham M S. Adv. Mater. , 2012, 24(16): 2109-2116 doi: 10.1002/adma.201104767
16. [16]
  Xu X L, Deng S X, Wang H, Liu J B, Yan H. Nano-micro. Lett. , 2017, 9(2): 97-115
17. [17]
  Wang J F, Chen D, Wu W, Wang L, Liang G C. Trans. Nonferrous Met. Soc. China, 2017, 27(10): 2239-2248 doi: 10.1016/S1003-6326(17)60250-4
18. [18]
  Wei A J, Li W, Chang Q, Bai X, He R, Zhang L H, Liu Z F, Wang Y. Electrochim. Acta, 2019, 323: 134692 doi: 10.1016/j.electacta.2019.134692
19. [19]
  Sun P, Ma Y, Zhai T Y, Li H Q. Electrochim. Acta, 2016, 191: 237-246 doi: 10.1016/j.electacta.2016.01.087
20. [20]
  Bhuvaneswari S, Varadaraju U V, Gopalan R, Prakash R. Electrochim. Acta, 2019, 327: 135008 doi: 10.1016/j.electacta.2019.135008
21. [21]
  Zong B, Lang Y Q, Yan C H, Deng Z Y, Gong J J, Guo J L, Wang L, Liang G C, Glab C. Mater. Today Commun. , 2020, 24: 101003 doi: 10.1016/j.mtcomm.2020.101003
22. [22]
  Kocak T F, Wu L Y, Wang J, Savaci U, Turan S, Zhang X G. J. Electroanal. Chem. , 2021, 881(47): 114926
23. [23]
  Gong J J, Yan S P, Lang Y Q, Zhang Y, Fu S X, Guo J L, Wang L, Liang G C. J. Alloys Compd. , 2021, 859: 157885 doi: 10.1016/j.jallcom.2020.157885
24. [24]
  Garhi G, Aklalouch M, Favotto C, Mansori M, Saadoune I. J. Electroanal. Chem. , 2020, 873: 114413 doi: 10.1016/j.jelechem.2020.114413
25. [25]
  Deng M M, Zou B K, Shao Y, Tang Z F, Chen C H. J. Solid State Electrochem. , 2017, 21(6): 1733-1742 doi: 10.1007/s10008-017-3545-z
26. [26]
  Zhang J N, Sun G, Han Y, Yu F D, Qin X J, Shao G J, Wang Z B. Electrochim. Acta, 2020, 343: 136105 doi: 10.1016/j.electacta.2020.136105
27. [27]
  Wang H, Tan T A, Yang P, Lai M O, Lu L. J. Phys. Chem. C, 2011, 115(13): 6102-6110 doi: 10.1021/jp110746w
28. [28]
  Liang G M, Wu Z B, Didier C, Zhang W C, Cuan J, Li B H, Ko K Y, Hung P Y, Lu C Z, Chen Y Z, Leniec G, Kaczmarek S M, Johannessen B, Thomsen L, Peterson V K, Pang W K, Guo Z P. Angew. Chem. Int. Ed. , 2020, 59(26): 10594-10602 doi: 10.1002/anie.202001454
29. [29]
  Yi T F, Chen B, Zhu Y R, Li X Y, Zhu R S. J. Power Sources, 2014, 247(1): 778-785
30. [30]
  Yi T F, Xie Y, Zhu Y R, Zhu R S, Ye M F. J. Power Sources, 2012, 211: 59-65 doi: 10.1016/j.jpowsour.2012.03.095
31. [31]
  Sun H B, Chen Y G, Xu C H, Zhu D, Huang L H. J. Solid State Electrochem. , 2012, 16(3): 1247-1254 doi: 10.1007/s10008-011-1514-5
32. [32]
  Yang S T, Jia J H, Ding L, Zhang M C. Electrochim. Acta, 2003, 48(5): 569-573 doi: 10.1016/S0013-4686(02)00726-0
33. [33]
  Liu H W, Zhang K L. Mater. Lett. , 2004, 58(24): 3049-3051 doi: 10.1016/j.matlet.2004.05.040
34. [34]
  Xu C Q, Tian Y W, Zhai Y C, Liu L Y. Mater. Chem. Phys. , 2006, 98: 532-538 doi: 10.1016/j.matchemphys.2005.09.089
35. [35]
  Mo M Y, Hui K S, Hong X T, Guo J S, Ye C C, Li A J, Hu N Q, Huang Z Z, Jiang J H, Liang J, Chen H Y. Appl. Surf. Sci. , 2014, 290 (6): 412-418
36. [36]
  Arumugam D, Kalaignan G P. J. Electroanal. Chem. , 2010, 648(1): 54 -59 doi: 10.1016/j.jelechem.2010.06.021
37. [37]
  Chen J, Zou G Q, Deng W T, Huang Z D, Gao X, Liu C, Yin S Y, Liu H Q, Deng X L, Tian Y, Li J Y, Wang C W, Wang D, Wu H W, Yang L, Hou H S, Ji X B. Adv. Funct. Mater. , 2020, 30(46): 4360
38. [38]
  HE G L, HE Y W, ZHAO Z G, LIU M. Acta Phys. Sin. , 2006, 55(2): 839-843 doi: 10.3321/j.issn:1000-3290.2006.02.065
39. [39]
  Chen Y Y, Sun Y, Huang X J. Comput. Mater. Sci. , 2016, 115: 109-116 doi: 10.1016/j.commatsci.2016.01.005
40. [40]
  Wu W, Qin X, Guo J L, Wang J F, Yang H S, Wang L. J. Rare Earths, 2017, 35(9): 887-895 doi: 10.1016/S1002-0721(17)60991-8
41. [41]
  ZHANG Q M, QIAO Y Q, ZHAO M S, WANG L M. Chinese J. Inorg. Chem. , 2012, 28(1): 67-73
42. [42]
  Keppeler M, Nageswaran S, Kim S J, Srinivasan M. Electrochim. Acta, 2016, 213: 904-910 doi: 10.1016/j.electacta.2016.08.014
43. [43]
  Niemoller A, Jakes P, Eurich S, Paulus A, Kungl H, Rüdiger A E, Granwehr J. J. Chem. Phys., 2018, 148(1): 014705 doi: 10.1063/1.5008251
44. [44]
  Wang H L, Shi Z Q, Li J W, Yang S, Ren R B, Cui J Y, Xiao J L, Zhang B. J. Chem. Phys. , 2015, 288: 206-213
45. [45]
  Chudzik K, Witosawski M, Bakierska M, Kubicka M, Natkański P, Kawako J, Molenda M J E A. Electrochim. Acta, 2021, 373: 137901 doi: 10.1016/j.electacta.2021.137901
1. [1]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
2. [2]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
3. [3]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
4. [4]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
5. [5]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
6. [6]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
7. [7]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
10. [10]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
11. [11]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
12. [12]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
15. [15]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
16. [16]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
17. [17]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
18. [18]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
19. [19]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
20. [20]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(966)
HTML views(287)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of La, Ce, Yb Doping on Properties of LiNi0.5Mn1.5O4 High Voltage Cathode Materials

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of La, Ce, Yb Doping on Properties of LiNi_0.5Mn_1.5O₄ High Voltage Cathode Materials