Citation: Yu-Ting MAO, Si-Da OUYANG, Zhi-Sheng KE, Yan HU, Shu-Qi YU, Ming-Xue XIANG, Zhong-Bang ZHU, Ping ZHANG. Magnesium-Doped Tricalcium Aluminate: Preparation and Simultaneous Removal Performance of Nitrogen and Phosphorus[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1745-1752. doi: 10.11862/CJIC.2021.202 shu

Magnesium-Doped Tricalcium Aluminate: Preparation and Simultaneous Removal Performance of Nitrogen and Phosphorus

Yu-Ting MAO ^{1, 2} ,
Si-Da OUYANG ¹ ,
Zhi-Sheng KE ¹ ,
Yan HU ³ ,
Shu-Qi YU ¹ ,
Ming-Xue XIANG ¹ ,
Zhong-Bang ZHU ¹ ,
Ping ZHANG ^1,,

1.
Key Laboratory of Poyang Lake Environment and Resource Utilization, Ministry of Education, School of Environmental and Chemical Engineering, Nanchang University, Nanchang 330031, China
2.
Office of MRL Development Committee of Jiangxi Province, Nanchang 330046, China
3.
Ganzhou Institute of Animal Science, Ganzhou, Jiangxi 341401, China

Corresponding author: Ping ZHANG, zhangping@ncu.edu.cn
Received Date: 9 February 2021
Revised Date: 22 July 2021

Figures(7)

Magnesium-doped tricalcium aluminate (Mg-C₃A) was successfully prepared through solid reaction method. The crystal structure and morphology of Mg-C₃A with various Mg contents were analyzed via X-ray diffraction, Raman spectra, scanning electron microscope and high-resolution transmission electron microscope to explore the preparation mechanism. The results showed that Mg-C₃A was composed of C₃A isomorphism formed by the replacement of Ca with Mg and the surface MgO, in which the Mg doping did not change the cubic symmetric structure and morphology of C₃A. The simultaneous removal behavior of nitrogen (NH₄⁺) and phosphorus (PO₄^3-) by Mg-C₃A were investigated by batch experiments (e. g., Mg-C₃A dosage, reaction time and real wastewater treatment), which revealed the maximum capacity was 65.2 and 20.2 mg·g^-1 at 12 h, respectively, conforming to the pseudo-secondorder kinetic model. Besides, the removal mechanisms were comprehensively explored by microscopic characterizations. The released ions (i.e., Mg²⁺ and Al³⁺) of Mg-C₃A play a major role in the removal of NH₄⁺ and PO₄^3- via the formation of struvite and AlPO₄; the OH^- benefits for the removal of excessive NH₄⁺ via neutralization.
- magnesium-doped tricalcium aluminate,
- preparation,
- ammonium,
- phosphate,
- simultaneous removal
1. [1]
  Myers R J, Geng G, Li J, Rodriguez E D, Ha J, Kidkhunthod P, Sposito G, Lammers L N, Kirchheim A P, Monteiro P J. Langmuir, 2017, 33(1): 45-55 doi: 10.1021/acs.langmuir.6b03474
2. [2]
  Zhang P, Zeng X, Wen X, Yang C, Ouyang S, Li P, Gu Z, Wu D, Frost R L. Chem. Eng. J. , 2019, 366: 11-20 doi: 10.1016/j.cej.2019.02.010
3. [3]
  DAI Y C, ZHANG G F, LIU F, QIAN G R. Acta Sci. Circumstantiae, 2012, 32(10): 2450-2454
4. [4]
  Kumar R, Pal P. Environ. Sci. Pollut. Res. , 2015, 22(22): 17453-17464 doi: 10.1007/s11356-015-5450-2
5. [5]
  Xu K, Li J, Zheng M, Zhang C, Xie T, Wang C. Water Res. , 2015, 80: 71-79 doi: 10.1016/j.watres.2015.05.026
6. [6]
  Hovelmann J, Putnis C V. Environ. Sci. Technol. , 2016, 50(23): 13032-13041 doi: 10.1021/acs.est.6b04623
7. [7]
  Stephan D, Wistuba S. Cem. Concr. Res. , 2006, 36(11): 2011-2020 doi: 10.1016/j.cemconres.2006.06.001
8. [8]
  Mishra R K, Fernandez-Carrasco L, Flatt R J, Heinz H. Dalton Trans. , 2014, 43(27): 10602-10616 doi: 10.1039/C4DT00438H
9. [9]
  Torréns-Martín D, Fernandez-Carrasco L, Martínez-Ramírez S, Ibáñez J, Artús L, Matschei T. J. Am. Ceram. Soc. , 2013, 96: 3589-3595 doi: 10.1111/jace.12535
10. [10]
  De La Pierre M, Carteret C, Maschio L, André E, Orlando R, Dovesi R. J. Chem. Phys. , 2014, 140: 164509 doi: 10.1063/1.4871900
11. [11]
  Böckelmann H, Schlecht R. Phys. Rev. B, 1973, 31(15): 5225-5231
12. [12]
  Liu H, Lu X C, Li M, Zhang L J, Pan C, Zhang R, Li J, Xiang W L. Environ. Sci. Technol. , 2018, 52(8): 4719-4727 doi: 10.1021/acs.est.7b05612
13. [13]
  Steele F A, Davey W P. J. Am. Chem. Soc. , 1929, 51(8): 2283-2293 doi: 10.1021/ja01383a001
14. [14]
  Mondal P, Jeffery J W. Acta Crystallogr. Sect. B, 1975, B31(3): 689-697
15. [15]
  Voicu G, Ghiţulică C D, Andronescu E. Mater. Charact. , 2012, 73: 89-95 doi: 10.1016/j.matchar.2012.08.002
16. [16]
  Wu Y, Wan J, Xiong J, Wang S, Gu P. Adv. Mater. Res. , 2010, 113-116: 655-661 doi: 10.4028/www.scientific.net/AMR.113-116.655
17. [17]
  WAN J B, HE H Y, DENG X P, WU Y M. Chinese Journal of Environmental Engineering, 2011, 5(5): 1047-1050
18. [18]
  ZHANG X Y, WU Z C, WANG Z W, ZHOU Q, YANG D H. China Environmental Science, 2010, 30(5): 609-614
19. [19]
  JIANG X T, CHI J. Journal of Agro-Environment Science, 2014, 33(9): 1817-1822
20. [20]
  WANG X B, WANG Y, LU S C, XIN N, ZHANG S H. Journal of Agro-Environment Science, 2010, 29(9): 1784-1788
21. [21]
  Schambeck C M, Costa R, Derlon N. Bioresour. Technol. , 2021, 333: 125167 doi: 10.1016/j.biortech.2021.125167
22. [22]
  Zheng Y, Wang A. Ind. Eng. Chem. Res. , 2010, 49(13): 6034-6041 doi: 10.1021/ie9016336
23. [23]
  Xu X, Wang B, Tang H, Jin Z, Mao Y, Huang T. J. Environ. Manage. , 2020, 260: 110130 doi: 10.1016/j.jenvman.2020.110130
24. [24]
  Genethliou C, Triantaphyllidou I E, Tekerlekopoulou A, Koutsoukos P, Vayenas D. J. Hazard. Mater. , 2020, 406: 124679
25. [25]
  HUANG J C, LING G S, WU Y N, ZHAI J, ZONG J. Chinese J. Inorg. Chem. , 2020, 36(11): 2031-2040 doi: 10.11862/CJIC.2020.238
26. [26]
  WANG J H, CHEN Y, LIU N, SUN T T, Atif S. Chinese J. Inorg. Chem. , 2020, 36(7): 1249-1258
27. [27]
  Yan L, Song J, Chan T, Jing C. Environ. Sci. Technol. , 2017, 51(11): 6335-6341 doi: 10.1021/acs.est.7b00807
28. [28]
  Bishop M, Barron A R. Ind. Eng. Chem. Res. , 2006, 45(21): 7042-7049 doi: 10.1021/ie060806t
29. [29]
  Rheinheimer V, Chae S, Rodríguez E, Geng G, Kirchheim A, Monteiro P. Materials, 2016, 9: 745 doi: 10.3390/ma9090745
30. [30]
  Malki A, Mekhalif Z, Detriche S, Fonder G, Boumaza A, Djelloul A. J. Solid State Chem. , 2014, 215: 8-15 doi: 10.1016/j.jssc.2014.03.019
1. [1]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
2. [2]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
3. [3]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
4. [4]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
5. [5]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
6. [6]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
7. [7]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
8. [8]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
9. [9]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
10. [10]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
11. [11]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
12. [12]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
13. [13]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
14. [14]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
15. [15]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
16. [16]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
17. [17]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
18. [18]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
19. [19]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
20. [20]
  Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of ⁶⁸Ga-labeled PM_2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 669-676. doi: 10.11862/CJIC.20230468

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(989)
HTML views(169)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142