Citation: Gui-Hong MAO, Fang-Ming XIAO, Ren-Heng TANG, Ling HUANG, Jian LI, Ying WANG. Effect of Water Washing and Re-sintering Treatment on Microstructure and Electrochemical Properties of High Nickel Ternary Material LiNi_0.88Co_0.07Al_0.05O₂[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1649-1658. doi: 10.11862/CJIC.2021.196 shu

Effect of Water Washing and Re-sintering Treatment on Microstructure and Electrochemical Properties of High Nickel Ternary Material LiNi_0.88Co_0.07Al_0.05O₂

Gui-Hong MAO ^{1, 2} ,
Fang-Ming XIAO ² ,
Ren-Heng TANG ² ,
Ling HUANG ² ,
Jian LI ^1,, ,
Ying WANG ^2,,

1.
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Guangdong Province Key Laboratory of Rare Earth Development and Application, Institute of Rare Metals, Guangdong Academy of Sciences, Guangzhou 510650, China

Corresponding author: Jian LI, kglj1010@163.com Ying WANG, wangying@irmgdas.gd.cn
Received Date: 5 April 2021
Revised Date: 15 July 2021

Figures(10)

Here, nickel cobalt hydroxide (Ni_0.928Co_0.072(OH)₂) and aluminum isopropanol (C₉H₂₁AlO₃) were used as raw material. The ternary precursor was synthesized by aluminum isopropanol hydrolysis. Then, the cathode material LiNi_0.88Co_0.07Al_0.05O₂ was obtained by mixing Ni_0.928Co_0.072(OH)₂ with lithium salt and subsequent sintering. After washing and re-sintering, the crystal structure, microstructure and electrochemical properties of the target products were characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectronic spectroscopy (XPS), energy dispersive X-ray spectroscopy (EDS), transmission electron microscope (TEM) and electrochemical tests. The results showed that synthesized LiNi_0.88Co_0.07Al_0.05O₂ had better comprehensive electrochemical performance when the ratio of solid to liquid was 1:25, washed with deionized water for three times and calcined at 600℃ for 2 h. The specific discharge capacity of 0.2C was up to 207.6 mAh·g^-1, the first charge and discharge efficiency was 84.8%, and the specific discharge capacity of 1C was 192.0 mAh·g^-1. After 100 cycles, the specific discharge capacity of the material was still 148.0 mAh·g^-1, and the capacity retention rate reached 77.1%.
- lithium ion battery,
- high nickel ternary cathode material,
- hydrolysis of aluminum isopropoxide,
- water washing,
- re-sintering
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Effect of Water Washing and Re-sintering Treatment on Microstructure and Electrochemical Properties of High Nickel Ternary Material LiNi0.88Co0.07Al0.05O2

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通讯作者: 陈斌, bchen63@163.com

Effect of Water Washing and Re-sintering Treatment on Microstructure and Electrochemical Properties of High Nickel Ternary Material LiNi_0.88Co_0.07Al_0.05O₂