Citation: Jian-Fei GAO, Rong-Rong NIE, Zhe FENG, Dun-Ru ZHU. Coexistence of Two Unique Cu(Ⅱ) Ions in Mononuclear Cu(Ⅱ) Complexes with Furanyl Substituted Triaryltriazoles[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1707-1712. doi: 10.11862/CJIC.2021.190 shu

Coexistence of Two Unique Cu(Ⅱ) Ions in Mononuclear Cu(Ⅱ) Complexes with Furanyl Substituted Triaryltriazoles

Jian-Fei GAO ¹ ,
Rong-Rong NIE ¹ ,
Zhe FENG ¹ ,
Dun-Ru ZHU ^{1, 2,,}

1.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: Dun-Ru ZHU, zhudr@njtech.edu.cn
Received Date: 10 May 2021
Revised Date: 2 June 2021

Figures(4)

Two new mononuclear Cu(Ⅱ) complexes, trans-[Cu(L¹)₂(NO₃)₂]_0.5[Cu(L¹)₂(H₂O)₂]_0.5(NO₃) (1) and trans-[Cu(L²)₂(NO₃)₂]_0.5[Cu(L²)₂(H₂O)₂]_0.5(NO₃)·₂CH₃OH (2) (L¹=3-(2-pyridyl)-4-phenyl-5-(2-furanyl)-1, 2, 4-triazole, L²=3-(2-pyridyl) -4-(p-fluorophenyl)-5-(2-furanyl)-1, 2, 4-triazole), were synthesized and characterized by FT-IR, elemental analyses, thermogravimetric analyses, single-crystal X-ray crystallography and powder X-ray diffraction. Both complexes 1 and 2 crystallize in triclinic system with space group P1. The crystal structure analysis shows that there are two crys-tallographically different Cu(Ⅱ) ions in 1 and 2 and each Cu(Ⅱ) ion lies in a distorted octahedral[CuN₄O₂] environment. However, in the axial position one Cu(Ⅱ) ion is coordinated with two water molecules, while another Cu(Ⅱ) ion with two nitrate ions. The L1 or L2 ligand coordinates with Cu(Ⅱ) via one pyridine N atom and one triazole N atom, while the furanyl group does not participate in coordination. In 1 and 2 there are some intermolecular C-H…N, C-H…O, O-H…O hydrogen bonding and C-H…π interactions, linking the mononuclear complex (1 or 2) to form a two-dimensional network.
- furan,
- Cu(Ⅱ) complex,
- crystal structure,
- triaryltriazole
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