Citation: Wen-Jing HOU, Yu-Ting MA, Gao-Yi HAN. Secondary Crystallization and Passivation of Perovskite Film Induced by Dithizone Post-treatment[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1414-1420. doi: 10.11862/CJIC.2021.182 shu

Secondary Crystallization and Passivation of Perovskite Film Induced by Dithizone Post-treatment

Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

Corresponding author: Wen-Jing HOU, houwenjing@sxu.edu.cn Gao-Yi HAN, han_gaoyis@sxu.edu.cn
Received Date: 5 April 2021
Revised Date: 24 June 2021

Figures(8)

The low defect formation energy and surface dangling bonds of organic-inorganic hybrid perovskite can cause the formation of Pb defects in the film. Pb defects belong to the deep level defects, which can reduce the device performances by acting as the charge trap sites to accelerate the non-radiative recombination of carriers, and resulting in poor interface contact and carrier transmission performance. Therefore, passivating the Pb defects in perovskite film is necessary. In this study, dithizone was used as the secondary crystallization inducer and Pb defect passivator of the organic-inorganic hybrid perovskite film. After post-treating the perovskite film with dithizone, the size of the perovskite grains and the film morphology were regulated. Further research results show that dithizone can passivate the Pb defects effectively by coordinating with lead ions, induce secondary crystallization of perovskite crystals, improve the quality of the film, and thus enhancing the device efficiency and stability.
- dithizone,
- post-treatment,
- passivate,
- Pb defects,
- perovskite solar cells
1. [1]
  Alsalloum A Y, Turedi B, Zheng X P, Mitra S, Zhumekenov A A, Lee K J, Maity P, Gereige I, AlSaggaf A, Roqan I S, Mohammed O F, Bakr O M. ACS Energy Lett. , 2020, 5(2): 657-662 doi: 10.1021/acsenergylett.9b02787
2. [2]
  Kojima A, Teshima K, Shirai Y, Miyasaka T. J. Am. Chem. Soc. , 2009, 131(17): 6050-6051 doi: 10.1021/ja809598r
3. [3]
  Kim S G, Le T H, Monfreid T, Goubard F, Bui T T, Park N G. Adv. Mater. , 2021, 33(12): 2007431 doi: 10.1002/adma.202007431
4. [4]
  TIAN H, XIONG Q, LIU P, ZHANG J, HAN L, ZHANG Y H, ZHENG Y J, WU L S, ZHU Y J. Chinese J. Inorg. Chem. , 2018, 34(9): 1710-1718
5. [5]
  Salim T, Sun S Y, Abe Y, Krishna A, Grimsdale A C, Lam Y M. J. Mater. Chem. A, 2015, 3(17): 8943-8969 doi: 10.1039/C4TA05226A
6. [6]
  Chu Z D, Yang M J, Schulz P, Wu D, Ma X, Seifert E, Sun L Y, Li X Q, Zhu K, Lai K J. Nat. Commun. , 2017, 8: 2230 doi: 10.1038/s41467-017-02331-4
7. [7]
  Zhao J J, Deng Y H, Wei H T, Zheng X P, Yu Z H, Shao Y C, Shield J E, Huang J S. Sci. Adv. , 2017, 3(11): eaao5616 doi: 10.1126/sciadv.aao5616
8. [8]
  Chen B, Rudd P N, Yang S, Yuan Y B, Huang J S. Chem. Soc. Rev. , 2019, 48(14): 3842-3867 doi: 10.1039/C8CS00853A
9. [9]
  Han T H, Tan S, Xue J J, Meng L, Lee J W, Yang Y. Adv. Mater. , 2019, 31(47): 1803515 doi: 10.1002/adma.201803515
10. [10]
  Wang L G, Zhou H P, Hu J N, Huang B L, Sun M Z, Dong B W, Zheng G H J, Huang Y, Chen Y H, Li L, Xu Z Q, Li N X, Liu Z, Chen Q, Sun L D, Yan C H. Science, 2019, 363(6424): 265-270 doi: 10.1126/science.aau5701
11. [11]
  Zhang F, Zhu K. Adv. Energy Mater. , 2020, 10: 1902579 doi: 10.1002/aenm.201902579
12. [12]
  Zhang M Y, Chen Q, Xue R M, Zhan Y, Wang C, Lai J Q, Yang J, Lin H Z, Yao J L, Li Y W, Chen L W, Li Y F. Nat. Commun. , 2019, 10: 4593 doi: 10.1038/s41467-019-12613-8
13. [13]
  Yang S, Dai J, Yu Z H, Shao Y C, Zhou Y, Xiao X, Zeng X C, Huang J S. J. Am. Chem. Soc. , 2019, 141(14): 5781-5787 doi: 10.1021/jacs.8b13091
14. [14]
  Chen Q, Zhou H P, Fang Y H, Stieg A Z, Song T B, Wang H H, Xu X B, Liu Y S, Lu S R, You J B, Sun P Y, Mckay J, Goorsky M S, Yang Y. Nat. Commun. , 2015, 6: 7269 doi: 10.1038/ncomms8269
15. [15]
  Ye F H, Ma J J, Chen C, Wang H B, Xu Y H, Zhang S P, Wang T, Tao C, Fang G J. Adv. Mater. , 2021, 33(3): 2007126 doi: 10.1002/adma.202007126
16. [16]
  Pool V L, Gold-parker A, Mcgeehee M D, Toney M F. Chem. Mater. , 2015, 27(21): 7240-7243 doi: 10.1021/acs.chemmater.5b03581
17. [17]
  Wen T Y, Yang S, Liu P F, Tang L J, Qiao H W, Chen X, Yang X H, Hou Y, Yang H G. Adv. Energy Mater. , 2018, 8(13): 1703143 doi: 10.1002/aenm.201703143
18. [18]
  Zeng Q S, Zhang X Y, Feng X L, Lu S Y, Chen Z L, Yong X, Redfern S A T, Wei H T, Wang H Y, Shen H Z, Zhang W, Zheng W T, Zhang H, Tse J S, Yang B. Adv. Mater. , 2018, 30(9): 1705393 doi: 10.1002/adma.201705393
19. [19]
  Wang F, Geng W, Zhou Y, Fang H H, Tong C J, Loi M A, Liu L M, Zhao N. Adv. Mater. , 2016, 28(45): 9986-9992 doi: 10.1002/adma.201603062
20. [20]
  Lin Y Z, Shen L, Dai J, Deng Y H, Wu Y, Bai Y, Zheng X P, Wang J Y, Fang Y J, Wei H T, Ma W, Zeng X C, Zhan X W, Huang J S. Adv. Mater. , 2017, 29(7): 1604545 doi: 10.1002/adma.201604545
21. [21]
  Li N X, Tao S X, Chen Y H, Niu X X, Onwudinanti C K, Hu C, Qiu Z W, Xu Z Q, Zheng G H J, Wang L G, Zhang Y, Li L, Liu H F, Lun Y Z, Hong J W, Wang X Y, Liu Y Q, Xie H P, Gao Y L, Bai Y, Yang S H, Brocks G, Zhou H P. Nat. Energy, 2019, 4(5): 408-415 doi: 10.1038/s41560-019-0382-6
22. [22]
  Wang H H, Wang Z W, Yang Z, Xu Y Z, Ding Y, Tan L G, Yi C Y, Zhang Z, Meng K, Chen G, Zhao Y, Luo Y S, Zhang X D, Hagfeldt A, Luo J S. Adv. Mater. , 2020, 32(21): 2000865 doi: 10.1002/adma.202000865
23. [23]
  Li S N, Ma R X, Zhao X, Guo J H, Zhang Y C, Wang C C, Ren H, Yan Y. Sol. Energy Mater. Sol. Cells, 2020, 206: 110290 doi: 10.1016/j.solmat.2019.110290
24. [24]
  Zhang J K, Yu H Z. J. Energy Chem. , 2021, 54: 291-300 doi: 10.1016/j.jechem.2020.05.061
25. [25]
  Chen J Z, Park N G. Adv. Mater. , 2019, 31(47): 803019
1. [1]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
2. [2]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
3. [3]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
4. [4]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
5. [5]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
6. [6]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
7. [7]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
8. [8]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
9. [9]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
10. [10]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
12. [12]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
13. [13]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
14. [14]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
15. [15]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
16. [16]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
17. [17]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374

Get Citation

PDF

XML

Metrics

PDF Downloads(17)
Abstract views(1520)
HTML views(456)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142