Citation: Ling-Fang QIU, Meng-Fan MA, Zhe-Yuan LIU, Jian CHEN, Ping LI, Xiang-Shu CHEN, Hidetoshi Kita, Shu-Wang DUO. Carbonized MoS 2/S-Doped g-C₃N₄ Heterojunction: Synthesis and Catalytic Degradation Mechanism of Rhodamine B under Visible Light[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1885-1892. doi: 10.11862/CJIC.2021.179 shu

Carbonized MoS 2/S-Doped g-C₃N₄ Heterojunction: Synthesis and Catalytic Degradation Mechanism of Rhodamine B under Visible Light

1.
Jiangxi Key Laboratory of Surface Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, China
2.
江西师范大学化学化工学院, 先进材料研究院, 分子筛膜材料国家地方联合实验室, 南昌 330000
3.
山口大学大学院创成科学研究院, 宇部 755-8611, 日本

Corresponding author: Shu-Wang DUO, dsw@jxstnu.edu.cn
Received Date: 30 March 2021
Revised Date: 20 May 2021

Figures(5)

To further improve the photocatalytic activity of polymeric semiconductor, graphitic carbon nitride (g-C₃N₄), for organic degradation, carbonized MoS₂/S-doped g-C₃N₄ heterojunction (MoSC/S-CN) was prepared simply by hydrothermal method. And it was used to degrade rhodamine B (RhB) under visible-light illumination. Based on the results, it turned out that the visible-light adsorption range of optimized MoSC/S-CN became much broader, and the corresponding RhB degradation efficiency under visible-light illumination within 100 min was 92.5%, which was 68.83% higher than that of pure g-C₃N₄. Based on a series of structural and optical characterizations, it is clear that after S doping and further coupling with carbonized MoS₂, MoSC/S-CN shows a synergistic effect. The band structure of g-C₃N₄ changes, and the photo-induced electron-hole pair separation rate is enhanced, which improves the photocatalytic activity of g-C₃N₄ effectively.
- carbonized MoS₂,
- S-doped g-C₃N₄,
- semiconductor,
- heterojunction,
- visible light
1. [1]
  Ong W J, Tan L L, Ng Y H, Yong S T, Chai S P. Chem. Rev. , 2016, 116: 7159-7329 doi: 10.1021/acs.chemrev.6b00075
2. [2]
  Prasad C, Tang H, Liu Q Q, Bahadur I, Jiang Y J. Int. J. Hydrogen Energy, 2020, 45: 337-379 doi: 10.1016/j.ijhydene.2019.07.070
3. [3]
  Jiang L B, Yuan X Z, Pan Y, Liang J, Zeng G M, Wu Z B, Wang H. Appl. Catal. B, 2017, 217: 388-406 doi: 10.1016/j.apcatb.2017.06.003
4. [4]
  Zeng W X, Bian Y, Cao S, Zhu A Q, Qiao L L, Ma Y J, Tan P F, Ma Q Y, Dong R, Pan J. Appl. Surf. Sci. , 2019, 478: 334-340 doi: 10.1016/j.apsusc.2019.01.238
5. [5]
  Li J, Liu E Z, Ma Y N, Hu X Y, Wan J, Sun L, Fan J. Appl. Surf. Sci. , 2016, 364: 694-702 doi: 10.1016/j.apsusc.2015.12.236
6. [6]
  Li Y F, Zhou M, Cheng B, Shao Y. J. Mater. Sci. Technol. , 2020, 56: 1-17 doi: 10.1016/j.jmst.2020.04.028
7. [7]
  Liang Z Z, Shen R, Ng Y H, Zhang P, Xiang Q J, Li X. J. Mater. Sci. Technol. , 2020, 56: 89-121 doi: 10.1016/j.jmst.2020.04.032
8. [8]
  Bie C B, Cheng B, Fan J J, Ho W K, Yu J G. EnergyChem, 2021, 3: 100051 doi: 10.1016/j.enchem.2021.100051
9. [9]
  Hu K H, Xian G H, Yu F X, Jia D S. J. Mater. Sci. , 2010, 45: 2640-2648 doi: 10.1007/s10853-010-4242-9
10. [10]
  Shao M M, Shao Y F, Ding S J, Tong R, Zhong X W, Yao L M, Ip W F, Xu B M, Shi X Q, Sun Y Y. ACS Sustainable Chem. Eng. , 2019, 7: 4220-4229 doi: 10.1021/acssuschemeng.8b05917
11. [11]
  Zhao Z H, Qin F, Kasiraju S, Xie L X, Alam M K, Chen S, Wang D Z, Ren Z F, Wang Z M, Grabow L, Bao J M. ACS Catal. , 2017, 7: 7312-7318 doi: 10.1021/acscatal.7b02885
12. [12]
  Zhang K, Zhao Y, Zhang S, Yu H, Chen Y J, Gao P, Zhu C L. J. Mater. Chem. A, 2014, 2: 18715-18719 doi: 10.1039/C4TA04564E
13. [13]
  Jeon J, Lee J, Choi S, Lee B H, Song Y J, Cho J H, Yun H J, Lee S. ACS Nano, 2018, 12: 338-346 doi: 10.1021/acsnano.7b06417
14. [14]
  Qiu L F, Qiu X B, Li P, Ma M F, Chen X S, Duo S W. Mater. Lett. , 2020, 268: 127566 doi: 10.1016/j.matlet.2020.127566
15. [15]
  Qiu L F, Zhou Z W, Ma M F, Li P, Duo S W. Materials, 2019, 12: 3948-3964 doi: 10.3390/ma12233948
16. [16]
  Ye L J, Wang D, Chen S J. ACS Appl. Mater. Interfaces, 2016, 8: 5280-5289 doi: 10.1021/acsami.5b11326
17. [17]
  Vinoth S, Mary Rajaitha P, Venkadesh A, Shalini Devi K S, Radhakrishnan S, Pandikumar A. Nanoscale Adv. , 2020, 2: 4242-4250 doi: 10.1039/D0NA00172D
18. [18]
  Zeleke T S, Tsai M C, Weret M A, Huang C J, Hwang B J. ACS Nano, 2019, 13: 6720-6729 doi: 10.1021/acsnano.9b01266
19. [19]
  Ren H, Jia S, Wu Y, Wu S, Zhang T. Ind. Eng. Chem. Res. , 2014, 53: 17645-17653 doi: 10.1021/ie503312x
20. [20]
  Fan G D, Du B H, Zhou J J, Yu W W, Chen Z Y, Yang S W. Appl. Catal. B, 2020, 265: 118610 doi: 10.1016/j.apcatb.2020.118610
1. [1]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
2. [2]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
3. [3]
  Yi Liu , Zhe-Hao Wang , Guan-Hua Xue , Lin Chen , Li-Hua Yuan , Yi-Wen Li , Da-Gang Yu , Jian-Heng Ye . Photocatalytic dicarboxylation of strained C–C bonds with CO₂ via consecutive visible-light-induced electron transfer. Chinese Chemical Letters, 2024, 35(6): 109138-. doi: 10.1016/j.cclet.2023.109138
4. [4]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
5. [5]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
6. [6]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
7. [7]
  Tingting Liu , Pengfei Sun , Wei Zhao , Yingshuang Li , Lujun Cheng , Jiahai Fan , Xiaohui Bi , Xiaoping Dong . Magnesium doping to improve the light to heat conversion of OMS-2 for formaldehyde oxidation under visible light irradiation. Chinese Chemical Letters, 2024, 35(4): 108813-. doi: 10.1016/j.cclet.2023.108813
8. [8]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
9. [9]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
10. [10]
  Tian-Yu Gao , Xiao-Yan Mo , Shu-Rong Zhang , Yuan-Xu Jiang , Shu-Ping Luo , Jian-Heng Ye , Da-Gang Yu . Visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO₂. Chinese Chemical Letters, 2024, 35(7): 109364-. doi: 10.1016/j.cclet.2023.109364
11. [11]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
12. [12]
  Bicheng Zhu , Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327
13. [13]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
14. [14]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
15. [15]
  Qiongqiong Wan , Yanan Xiao , Guifang Feng , Xin Dong , Wenjing Nie , Ming Gao , Qingtao Meng , Suming Chen . Visible-light-activated aziridination reaction enables simultaneous resolving of C=C bond location and the sn-position isomers in lipids. Chinese Chemical Letters, 2024, 35(4): 108775-. doi: 10.1016/j.cclet.2023.108775
16. [16]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
17. [17]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
18. [18]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
19. [19]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
20. [20]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(583)
HTML views(104)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Carbonized MoS 2/S-Doped g-C3N4 Heterojunction: Synthesis and Catalytic Degradation Mechanism of Rhodamine B under Visible Light

Metrics

通讯作者: 陈斌, bchen63@163.com

Carbonized MoS 2/S-Doped g-C₃N₄ Heterojunction: Synthesis and Catalytic Degradation Mechanism of Rhodamine B under Visible Light