Citation: Zhen-Hua LI, LI-Lin LUO, Chong-Qing WAN, Yue-Qi HU, Ruo-Han ZHOU, Xia LI. Cu(Ⅱ)/Zn(Ⅱ) Coordination Polymers Constructed by 3-(4'-Carboxy-phenoxy) benzoic Acid: Synthesis, Crystal Structure and as a Fluorescence Sensor to Acetone and Tb³⁺ Ion[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1381-1389. doi: 10.11862/CJIC.2021.177 shu

Cu(Ⅱ)/Zn(Ⅱ) Coordination Polymers Constructed by 3-(4'-Carboxy-phenoxy) benzoic Acid: Synthesis, Crystal Structure and as a Fluorescence Sensor to Acetone and Tb³⁺ Ion

Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: Xia LI, xiali@cnu.edu.cn
Received Date: 5 January 2021
Revised Date: 23 May 2021

Figures(9)

Taking 3-(4'-carboxyl-phenyloxy) benzoic acid (3, 4'-H₂oba) and phenanthroline (phen) as ligands, two coordination polymers (CPs) [M(3, 4'-oba) (phen) (H₂O)]_n (M=Zn (1), Cu (2)) were synthesized by hydrothermal method and their structures were characterized by X-ray single crystal diffraction. CP 1 features a one-dimensional chain structure. The coordination environment of Zn²⁺ ion is[ZnO₃N₂], forming tetragonal vertebral configuration. The Zn²⁺ ions are linked by 3, 4'-oba ligands through μ₁: η¹η⁰/μ₁: η¹η⁰ coordination modes. CP 2 has a structure with[CuO₄N₂] coordination unit. Ligand 3, 4'-oba uses the pattern of μ₁: η¹η⁰/μ₁: η¹η¹ to connect two Cu²⁺ to form a 1D zigzag chain structure. The 1D chain forms a 2D supramolecular network structure through hydrogen bonds (C—H…O in 1 and O—H…O in 2). Ligand phen coordinates with Zn²⁺/Cu²⁺ by bidentate chelation mode. CP 1 showed strong fluorescence, which is attributed to the π^*-π transition of the ligand. The fluorescence properties of 1 in different solvents and the fluorescence sensitization effect on lanthanide metal ion were studied. The fluorescence of CP 1 was quenched by acetone molecule, and it can sensitize the rare earth metal Tb³⁺ ions to emit strong green fluorescence. Therefore, 1 can be used as a fluorescence sensor for detecting acetone molecule and Tb³⁺ ion.
- transition metal,
- coordination polymer,
- crystal structure,
- fluorescence
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Cu(Ⅱ)/Zn(Ⅱ) Coordination Polymers Constructed by 3-(4'-Carboxy-phenoxy) benzoic Acid: Synthesis, Crystal Structure and as a Fluorescence Sensor to Acetone and Tb3+ Ion

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通讯作者: 陈斌, bchen63@163.com

Cu(Ⅱ)/Zn(Ⅱ) Coordination Polymers Constructed by 3-(4'-Carboxy-phenoxy) benzoic Acid: Synthesis, Crystal Structure and as a Fluorescence Sensor to Acetone and Tb³⁺ Ion